乙二醇合成工艺的研究进展

对国内外乙二醇合成的传统工艺:直接水合法、催化水合法和碳酸乙烯酯法进行了介绍;对乙二醇合成的新工艺,包括乙二醇和碳酸二甲酯联产法和C1化学法的工艺流程和发展前景进行了综述,其中,C1化学法主要分为乙烯合成法、合成气合成法和甲醛、甲醇合成法。作为合成气合成法之一的合成气偶联合成法,具有工艺要求不高、反应条件温和等优点,是目前最有希望大规模工业化生产乙二醇的工艺路线。     

Change of characteristics of desulfurization and denitrification by combustion flue gas composition and electrode configuration under pulsed corona discharge

Laboratory-scale and parametric experiments of SO₂ and NO_x removal from the simulated combustion gas by pulsed corona discharge have been performed by changing the combustion gas composition and temperature, the electrode configuration of plasma reactor, and the polarity of high-voltage electrode. The following results are obtained: 1) the higher the concentration of H₂O and O₂, the higher the efficiency of desulfurization and denitrification at the same specific input; 2) the pulsed corona discharge with a voltage pulsewidth as short as 200 ns of negative polarity shows the possibility to attain almost 90 percent deSO_x and deNO_x efficiency at the specific discharge input of 20 J/g, which is almost the same as the specific input in the electron-beam process; 3) the deNO_x characteristics show a little temperature dependence in the range of 70 to 130°C, but the deSO_x efficiency increases rapidly in the temperature region below 100°C suggesting the thermochemical dependence of deSO_x reaction; 4) when desulfurization and denitrification proceed, the white dendritic powder deposits on the plasma reactor whose composition is identified to be 49 mol% (NH₄)₂SO₄ and 47 mol% of 2NH₄NO₃ · (NH₄)₂SO₄, and the ratio of SO₂, NO and NH₃ of the deposit is almost equal to that of supplied gas.     

地下水污染修复的活性渗滤墙技术

活性渗滤墙是一种现场修复受污染地下水的新型技术，具有原理简单，施工方便，运行费用低廉等特点，活性渗滤墙垂直于地下水流动方向设置，当地下水流通过活性渗滤墙时，污染物与墙体材料发生化学反应，从而达到环境修复的目的。文中综述了活性渗滤墙技术的修复机理和实际应用，大量研究表明，应用金属铁作为活性渗滤墙材料，可以去除地下水中的重金属以及有机污染物，目前活性渗滤墙已经在世界各地应用，是一种非常有发展前景的环境污染修复技术。     

山前平原地下水侧向补给潜力空间变异模拟

SWAT模型利用分辨率较高的DEM数据,可以估算山前地下水侧向补给的空间变异,并可以计算不同降水年型下补给量的差别。模拟需要对研究区进行填洼、流向确定、汇流和河网水系的提取四步运算,并对河道临界支撑面积的取值进行分析。分别模拟了平水年和丰水年两种降雨年型下研究区13个出水口的地下水侧向补给潜力。在研究区,由于地形的变化,导致山与平原交接断面上出水口的集水面积变异非常大,因此山前平原所接受的地下水侧向补给量的空间变异也非常大。不同的降雨年型下,降雨量转化为地下水侧向补给量的比例也不同。平水年的转化比例较小,丰水年的转化比例较大。应用SWAT模型时,与ArcView的拓展模块有机结合,可以更方便提取完整的大流域,划分出合理的子流域。     

AP的安全制备（英）

1 IntroductionThe ammonium perchlorate ( AP)-based compositepropellant is currently the most widely used one becausethis propellant has good burning characteristics and me-chanical properties. One of the few serious drawbacks ofthe AP-based propellant is that its products of combus-tion, which include HCl, chlorine, and chlorine oxides,cause atmospheric pollution. Increasing concern for aclean atmosphere in recent years has resulted in a com-pelling need for developing a chlorine-free,enviro…     

Thermokinetics of Liquid-Liquid Reaction of Dy（NO3 ）3 with Histidine

The thermokinetics of liquid-liquid reaction of dysprosium nitrate with histidine were studied using a microcalorimeter. On the basis of experimental and calculated results, threethermodynamic parameters (the activation enthalpy, the activation entropy and the activation free enegy),the rate constant, three kinetic parameters (the activation energy, the pre-exponential constant and the reaction order) wereobtained. On the basis of thermodynamics and kinetics, the for marion reaction of the complex was discussed.     

Synthesis,Characterization and Luminescent Properties of Complexes of Rare Earth Nitrates with Tris{2-[N-(pyridine-methanoyl)amino]ethyl} amine

Duringthelastdecade ,thedesignandsynthesisoftripodalligandsandtheirmetalcomplexeshaveattractedconsiderableattentionduetotheirpotentialusesaslumi nescentprobesinmedicineandbiochemistry[1～ 7] ,ascatalysts[8] andelectrochemicalmaterials[9] .However ,thecomplexesofrareearthmetalwithtripodalligandshavefewreported[10 ] .Asanextensionofourstudiesoncomplexesofmetalwithtripodalligands ,anewtripodalligand (tris { 2 [N (pyridine methanoyl)amino]ethyl}amine ,L)anditscomplexeswithrareearthnitratesweresyn…     

Lifetime and ageing management of nuclear power plants: A brief overview of some light water reactor component ageing degradation problems and ways of mitigation

The susceptibility and tendency for nuclear power plant (NPP) components to undergo changes in their mechanical and physical properties in the course of the NPP lifetime is generally termed as “ageing”. The light water reactor (LWR) nuclear environment is not a begnign one; it is characterized not only by fast neutrons, which can degrade metallic structures, but also relatively high temperatures of coolant water (around 300°C) which may contain impurities (e.g. sulphate, chloride, peroxides) which can cause corrosion. The hydrodynamical conditions of the coolant in steam generators, for example, can cause thermal fatigue, erosion and corrosion; suspended particulate matter can accelerate erosion processes which can lead to wall thinning and lowering of safety margins. Ageing is, therefore, a very complex mixture of factors concerned with materials, temperatures, times of exposure to environments which vary with time and with respect to chemical composition and flow charactertistics.

The paper describes a few ageing phenomena which can be considered important due to their impact on nuclear safety issues; their influence on economic aspects (availability) of NPP is outlined. Mitigation measures for NPP component ageing problems are given together with recommendations for addressing such issues in NPP now and in the future.     

Contamination of the Chalk Aquifer by Chlorinated Solvents: A Case Study of the Luton and Dunstable Area

A detailed investigation of contamination by chlorinated solvents of the Chalk Aquifer underlying the towns of Luton and Dunstable was undertaken to assess the extent, causes and mechanisms of pollution. The research programme incorporated land-use surveys, regional groundwater surveys, monitoring of groundwater abstraction points and aquifer profiling by means of the drilling of observation boreholes, the analysis of the recovered core material and the depth sampling of these and other boreholes.
Low-level solvent contamination of the Chalk Aquifer was found to be widespread with 'hotspots'of higher concentrations. At the drilling sites, both the saturated and unsaturated zones were contaminated with solvents, although free product was not observed. The presence of an additional contaminant, oil, at some sites was noted to influence the distribution of solvents within the aquifer.
Clean-up of the aquifer is not a practical option, and treatment of the groundwater at the abstraction points has been adopted.