Measurement of the Metal Surface Acidity/Electronegativity of Pt(110)

In previous work, it has been found that a hydrogen-covered Pt(110) surface is acidic, but quantification of the acidity has not yet been done. In this paper a spectroscopic method is developed to measure the acidity of a metal surface for the first time. The technique involves measuring the intensity of the N–H stretch from the C₅H₄XNH⁺ that forms when hydrogen coadsorbs with pyridine, 2-fluoropyridine and 3-fluoropyridine. The Bethe approximation is then used to estimate the metal surface acidity/electronegativity (MSAEL). The proton affinity/MSAEL of Pt(110) has been determined to be 907 ± 4 kJ/mol at high coverage. This is the first time the MSAEL has been measured on a metal surface. Implications for fuel cell catalysis are discussed.     

Structural Description of Polyaromatic Nucleus in Residue

The proton nuclear magnetic resonance spectroscopy （1H-NMR）, the synchronous fluorescence spectrometry （SFS） and the ruthenium ions catalyzed oxidation （RICO） method were used to determine the chemical structure of polyaromatic nucleus in Oman residue fractions. The results of 1H-NMR analyses showed that the average numbers of aromatic rings in the aromatics, resins and asphaltenes units were 3.2, 5.6 and 8.2, respectively. SFS was used to investigate the distribution of aromatic rings in residue fractions, the main distribution range of aromatic rings in aromatics, resins and asphaltenes were 3 4 rings, 3--5 rings and more than 5 rings, respectively. The aromatic network in residue fractions was oxidized to produce numerous carboxylic acids. The types and content of benzenepolycarboxylic acids, such as phthalic acid, benzenetricarboxylic acids, benzenetetracarboxylic acids, benzenepentacarboxylic acid and benzenehexacarboxylic acid disclosed the condensed types of aromatic nuclei in the core. The biphenyl fraction （BIPH）, the cata-condensed fraction （CATA）, the peri-condensed fraction （PERI） and the condensed index （BCI） were calculated based on the benzenepolycarboxylic acids formed. The results implied that there was less biphenyl type structures in all residue fractions. The aromatics fraction was almost composed of the cata-condensed type system, and the asphaltenes fraction was wholly composed of the peri-condensed type system, while in the resins fraction co-existed the two types, herein the peri-con- densed type was predominant over the cata-condensed type. Based on the analytical results obtained in the study, the components --aromatics, resins and asphaltenes -- were given the likely structural models.     

锌基合金模具的应用及探讨

本文分析了锌基合金模具制造及使用过程中容易出现热裂、翘曲、收缩的问题，并提出了解决这些问题的措施。     

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对于套管挤毁问题较为严重的油气水井，采用非API标准的特厚壁套管来提高其抗挤强度，是今后预防套管挤毁的重要发展方向。目前，特厚壁套管的抗挤强度计算和尺寸系列尚未形成工业标准，文章提出特厚壁套管的抗挤强度计算方法和尺寸系列，供设计者和厂家参考。API/ISO套管挤毁工作组曾对本文公式进行了测评，结果曼示具有较高的计算精度。大量计算表明，特厚壁套管的抗挤强度大大提高，约为加厚前原套管抗挤强度的1．5～4倍，甚至6倍。最后还介绍了特厚壁套管在中原油田的现场应用情况。     

W-Ni-Cu高比重合金注射成形烧结收缩及性能的研究

研究了W-Ni-Cu高比重合金注射成形工艺过程收缩率和性能。比较了模具尺寸、注射坯尺寸、烧结坯尺寸，及烧结阶段各方向收缩率的关系，发现实际收缩与理论预测收缩率较为一致，但在厚度方向存在与其他方向收缩不一致的情形，这与由重力作用产生的塑料流动有关；还探讨了烧结坯密度与烧结条件的关系，测定了烧结坯的力学性能及断口形貌、金相组织，烧结坯在1400℃，90min烧结达到了99％的相对密度，断裂强度600MPa以上。     

Metal sorption by biomass of melanin‐producing fungi grown in clay‐containing medium

The sorption of toxic metals by fungal mycelia grown in clay‐containing medium is reported in this work. Biomass of melanin‐producing microfungi of the genus Cladosporium (C cladosporioides, C resinae and C herbarum) and Aureobasidium pullulans, clay minerals and fungal mycelia grown in clay‐containing medium were compared for their equilibrium Cu and Cd uptake from pH‐buffered solutions using experimental sorption isotherms. Bentonite (Cherkassy) in the natural form was shown to be the best Cu sorbent compared with the other clays and clay minerals tested. Cu sorption isotherms fitted the Langmuir sorption model for all cases. Comparison of Cu and Cd uptake for biomass and bentonite showed a lower biomass uptake capacity but a considerably higher affinity of the biosorbent for the solute. The presence of kaolinite and palygorskite in the medium generally reduced both Cu and Cd sorption capacity and the metal‐binding ability of the fungal–clay mixtures. In contrast, addition of bentonite into the medium did not appreciably alter the Cd sorption ability but increased the sorption of Cu by A pullulans and C cladosporioides grown in this medium. A common feature for all fungi grown in the presence of bentonite was an increase in the Cu sorption capacity (Q_max) of the biomineral sorbents and a reduction in their affinity (Langmuir parameter b) compared with control biomass. A difference between predicted and experimental data obtained for biomass grown on bentonite medium was also observed. The connection between the sorption capacity of biomass grown in clay‐containing medium, mycelial morphology and the structure of fungal pellets is discussed and a mechanism for the changed sorption capacity of the combined biomineral sorbents is proposed which involves blocking or modification of binding sites on biotic and abiotic components of the ‘biomineral’ association. © 2002 Society of Chemical Industry     

浅谈水闸安全检测

通过对华东沿海地区80年代以前修建的一些在役水闸工程的系统安全检测和分析,发现了水闸工程存在的安全隐患,同时也了解水闸工程尚有的潜在能力。提醒水闸管理部门,在役水闸满足目前社会发展需要的同时,还必须高度重视水闸的安全生产运行和管理。水闸安全检测就是利用先进的检测手段,为业主及时、高效、经济和高质量地解决水闸工程存在的实际问题。     

Influence of the Temperature of a Body on Its Weight

The physical preconditions are considered for the temperature of a body to influence the force of gravity experienced by it. The results are given of experiments on weighing metal rods heated by ultrasound which confirm a dependence of the weight of the rods on their temperature.     

Hydrogen Absorption and Release Behavior in Hydrogen Decrepitation Process of Nd-Fe-B Alloys

The behavior of hydrogen absorption and release in hydrogen decrepitation (HD) process of Nd-Fe-B alloys were investigated. The results reveal that the reactivity and the amount of hydrogen absorption in HD process are related to the surface activity of the alloy so that the fresh and active surface has a higher efficiency. The presence of Nd-rich phase at the grain boundary is an essential factor of the HD activity of the alloy at room temperature. On degassing, hydrogen is released from the HD powder continuously with increasing temperature. And the residual hydrogen is as low as 0.0015% at 1073K, which shows that the hydrogen is almost exhaused. It is feasible to remove the hydrogen from the HD powder by heating treatment at the temperature of 523-723K for 1h prior to the magnetic field forming in order to decrease the harmful effect of hydrogen on the easy axis alignment of HD magnet.