Analysis of epoxidized soybean oil by gas chromatography

A fast and cost-effective procedure to quantitate epoxidized soybean oil by means of an external standard method is reported. This procedure is applicable to commercial epoxidized oils, polymer additive packages and polymers—polyvinyl chloride (PVC)—containing epoxidized oils. The epoxidized soybean oil is converted into fatty acid methyl esters with tetramethylammonium hydroxide, and analyzed by capillary gas chromatography with flame-ionization detection. In PVC samples, the epoxidized soybean oil was extracted with toluene and followed by derivatization prior to analysis. The methyl esters of monoepoxyoctadecanoic, diepoxyoctadecanoic and triepoxyoctadecanoic acid were separated with a short capillary column.     

Isolation of erucic acid from rapeseed oil by lipase-catalyzed hydrolysis

Three lipases were compared for their ability to hydrolyze high erucic acid rapeseed oil, with the objective of concentrating the erucic acid in a single glyceride fraction. Lipase fromPseudomonas cepacia released all fatty acids rapidly and did not result in selective distribution of erucic acid.Geotrichum candidum lipase released C20 and C22 fatty acids extremely slowly, resulting in their accumulation in the di- and triglyceride fractions. Less than 2% of the total erucic acid was found in the free fatty acid (FFA) fraction. Lipase fromCandida rugosa released erucic acid more slowly than C20 and C18 fatty acids at 35°C but only resulted in a limited accumulation of the erucic acid in the di- and triglyceride fractions. However, when hydrolysis catalyzed byC. rugosa lipase was carried out below 20°C, the reaction mixture solidified and was composed solely of FFAs and diglycerides. The diglyceride fraction contained approximately 95% erucic acid while about 20% of the total erucic acid was found in the FFA fraction. It is concluded that hydrolysis at low temperature withC. rugosa lipase results in a higher purity of erucic acid in the glyceride fraction than can be obtained withG. candidum lipase, but with considerable loss of erucic acid to the FFA fraction.     

Increase in the γ-linolenic acid content by solvent winterization of fungal oil extracted fromMortierella genus

The fungal oil extracted fromMortierella ramanniana var.angulispora (IFO 8187) was solvent winterized in order to raise the content of γ-linolenic acid (GLA). Effects of winterization conditions (solvent, oil concentration in the solvent and temperature) and changes of glyceride compositions were discussed. The fungal oil was separated into four diglycerides and 17 triglycerides (TG) with high performance liquid chromatography. The predominant species were POO, POP and LOP, whose contents were 24.4, 22.9 and 9.4% of the total TG, respectively. Ethanol at 4°C gave the highest GLA content of 10.5% in spite of lower yield than with acetone at −20°C. The highest separation efficiency for GLA (η_GLA) was 0.27 with acetone at −20°C and 10% oil concentration, resulting in 8.3% of GLA from the fungal oil at 5.7% LGA. In case of lower oil concentration at 5–20%, η_GLA showed higher in the following order: acetone (−20°C)>n-hexane (−20°C)>acetone (4°C)>petroleum ether (−20°C). The winterization process also proved to be effective for the separation of TG type, Sa₂U (Sa; saturated fatty acid; U, unsaturated fatty acid) into the crystallized fraction and SaU₂ into the liquid fraction. Acetone at −20°C showed higher separation efficiency for triunsaturated TG than the other solvents.     

火力发电厂仪用压缩空气带水带油探究

采用系统分析、数学及物理计算的方法,对火电厂仪用压缩空气带水带油的原因进行论证,找出最主要原因,并有针对性地采取了预防和改造措施,对改造效果进行了分析与总结。     

油纸电容型套管缺油的危害及判断方法

通过解析油纸电容型套管的结构,介绍了套管四大组成部分的作用和原理,并重点阐述了套管内部绝缘介质的电气性能．同时指出了套管缺油的原因及危害,并说明了如何准确地判断缺油．通过实例阐述了套管缺油的查找方法,论证了综合利用电容量C、介质损失角tanδ、油中溶解气体色谱分析及红外线成像仪对发现套管缺油的合理性及准确性．     

鄂尔多斯盆地化子坪地区延长组长6沉积特征及其与油藏分布关系探讨

根据岩性、沉积结构与构造、测井相综合分析认为,本区长6油层组为三角洲前缘哑相沉积,可细分为三角洲前缘水下分流河道、分流间湾微相.水下分流河道砂体为其主要的储集层.这些砂体横向上复合连片往往呈带状展布,岩性以细粒长石砂岩为主,残余粒间孔和次生溶蚀也为主要的孔隙类犁.通过沉积相与油藏分布的关系研究,认为油气的聚集受沉积微相的控制,水下分流河道砂体为长6油层组良好的储集层,是有利的油气聚集场所.     

铁碳微电解及Fenton氧化法在染料废水处理中的应用

探讨了铁碳微电解及Fenton氧化法的反应机理、影响因素,总结了微电解和Fenton氧化法的优缺点,概述了微电解与Fenton氧化法联用在废水处理中的应用及其发展前景。     

污水回用技术应用现状与研究进展

污水回用是解决水资源短缺和改善城市水环境的有效途径。介绍了国内外城市污水回用技术的发展与应用现状,并提出了城市污水回用的发展方向。     

凝析气藏生产气油比混沌时间序列预测方法

混沌时间序列预测方法在油气田勘探开发过程中发挥着重要的作用。地下储层通常具有较强的非均质性,流体的流动也受到多种未知因素的影响,这也与各种混沌现象极为相似。根据相空间重构理论,应用遗传算法求取最小嵌入维数m及时间延迟τ,构建了混沌时间序列模型,并对牙哈凝析气藏两口井的生产气油比进行了模拟及预测,拟合误差小于6%。研究结果表明,该预测模型有较高的精度。     

植物油纸绝缘的介电与热稳定性能

植物绝缘油是一种新型高燃点、可再生、环保型的液体电介质,是矿物绝缘油的优良替代品.介绍植物绝缘油的实验室制备方法与植物绝缘油的基本电气及理化性能,分析植物油纸试样的工频击穿电压、介质损耗因数、介电常数等介电性能,并采用热重分析法研究油纸的热稳定性.试验与分析结果表明：植物油纸击穿电压高于矿物油纸击穿电压,植物油纸的介电常数和介质损耗因数与温度呈指数关系,其相对介电常数高于矿物油纸,而介质损耗因数与矿物油纸基本一致,植物油纸热稳定性比矿物油纸更高.