特大型桥梁工程地质勘察区域地壳稳定性研究

重大工程区域地壳稳定性研究，是工程前期工程地质勘察的重要内容之一，并越来越多地为工程建设所重视。大桥工程地质勘察以往对此涉及较少，也无明确的统一规定，以长江上所建特大桥为例，对此项工程作了些探索性的研究，重点研究的问题是：区域构造环境及构造变形，地壳结构和深部构造，新构造活动，断裂活动，地震活动等，为大桥建设宏观决策和抗震设计提供依据。     

钢纤维喷射混凝土作为面板材料的可行性研究

钢纤维混凝土作为一种新型增强材料，以其较好的受力变形特性在水利水电，交通，海岸防护，港口及军事等诸多工程中得到了广泛的应用。针对混凝土面板堆石坝面板的受力变形特点，为改善水布垭面板堆石坝面板的受力条件，提高其防渗能力，同时方便施工，现提出采用钢纤维喷射混凝土作为水布垭面板堆石坝面板材料的新构想，并通过对钢纤维喷射混凝土的物理力学特性及堆石坝面板受力变形进行分析，为钢纤维喷射混凝土在水布垭面板堆石坝面板中的实际应用提出了建议方案。     

Rare earth oxides as carbon oxidation catalysts

The behavior of a number of rare earth oxides as catalysts for the oxidation of graphite in air has been investigated by the methods of thermal analysis. Of the oxides studied, only CeO₂ showed significant activity in accelerating the gasification of graphite by oxygen between 500 and 1000°C. Cerium salts, which decompose to a finely dispersed oxide phase at low temperatures, e.g. Ce (III) nitrate and ammonium Ce (IV) nitrate, were found to be very active catalysts. The catalytic effect may be due to a redox process involving the cyclic conversion of the oxide from the Ce (IV) to the Ce (III) oxidation state, or the oxide particles may provide sites for the dissociative chemisorption of oxygen.     

Modelling the effects of dam removal on migratory walleye (Sander vitreus) early life‐history stages

Many dams in the USA have outlived their intended purpose and an increasing number are being considered for removal. Yet, quantitative studies of the potential physical, biological and ecological responses are needed to assess dam removal decisions. In this paper, the responses of migratory walleye (Sander vitreus) to increased spawning habitat availability as a result of dam removal was studied by comparing scenarios with and without a high‐head dam in the Sandusky River (Ohio), a major tributary to Lake Erie. A conceptual, ecological model was proposed to define the relationship between hydrodynamics and walleye spawning, egg hatching, larval drift and survival. A mathematical, ecological model of the early life‐history stages was then developed and coupled with time series of depth and velocity predictions over the spawning grounds from a 1‐D hydrodynamic model. Model simulations were run for 1984–1993 for both the with‐ and without‐dam scenarios to assess the potential benefit of dam removal. The simulation results demonstrated that velocity, depth and water temperature are major factors influencing adult walleye spawning success. Without the dam, 10 times the amount of spawning habitat would be available for walleye to spawn. This increase in spawning habitat area resulted in up to five times the total egg deposition and seven times the larval output to the nursing grounds, based on the assumption that 5% of the walleye population of Lake Erie migrated up the Sandusky River to spawn. We concluded that the spawning habitat in the current condition (with the dam) is limiting and additional spawning habitat upstream could significantly increase the number of larval walleye drifting to Lake Erie. The model sensitivity analysis showed that the number of walleye migrating up the river in spring is the dominant factor for larval recruitment to the lake. Copyright © 2006 John Wiley & Sons, Ltd.     

Ring‐opening polymerization of D,L‐lactide by rare earth 2,6‐dimethylaryloxide

Ring‐opening polymerization of D,L ‐lactide (LA) has been successfully carried out by using rare earth 2,6‐dimethylaryloxide (Ln(ODMP)₃) as single component catalyst or initiator for the first time. The effects of different rare earth elements, solvents, monomers and catalyst concentration as well as polymerization temperature and time on the polymerization were investigated. The results show that La(ODMP)₃ exhibits higher activity to prepare poly(D,L ‐lactide) (PLA) with a viscosity molecular weight of 4.5 × 10⁴ g mol^?1 and the conversion of 97 % at 100 °C in 45 min. The catalytic activity of Ln(ODMP)₃ has following sequence: La > Nd > Sm > Gd > Er > Y. A kinetic study has indicated that the polymerization is first order with respect to both monomer and catalyst concentration. The apparent activation energy of the polymerization of LA with La(ODMP)₃ is 69.6 kJ mol^?1. The analyses of polymer ends indicate that the LA polymerization proceeds according to ‘coordination–insertion’ mechanism with selective cleavage of the acyl–oxygen bond of the monomer. Copyright © 2004 Society of Chemical Industry     

Preparation and Properties of Rare Earth Modified Carbon Black/Natural Rubber Composites

The oxides Eu, Ho, Er and Dy were used to prepare the hydroxides of rare earth modified carbon black. Then natural rubber latex （NRL） was added into the reactor. The system reacted at 85 ℃ with stirring for 1 h to prepare powdered HAF-Ln（OH）3/NR composites. The effects of the kind and content of Ln on the particle size distribution of P [ NR/HAF-Ln （OH）3 ] and mechanical properties of its vulcanizate were studied respectively. It is found that rare earth can help to get the powder of the composite, the product particle with a diameter less than 0.9mm will be get when the composites containing the compound of Ho, Er and Dy with dosage of 1.0, 1.0, O. 5 percent, respectively. The adding of Ln can improve the tensile strength and tear strength of the vulcanizate effectively, what＇s more, Er and Dy can decrease the permanent set of vulcanizate significantly. The SEM studies shows that P[ NR/HAF-Dy （OH）3 ] vulcanizate shows superior mechanical properties that depend primarily on the absence of free carbon black, the fine dispersion of carbon black in the rubber matrix and better polymer-filler interaction.     

碾压混凝土坝应力场有限元及施工仿真分析

采用三维有限元法对某碾压混凝土坝(RCC)在施工导流期的应力场进行分析,着重校核了顶部未到设计龄期的碾压混凝土和大型导流底孔周边的应力分布;并初步探讨了在多因素影响情况下,从开始施工到蓄水运行的坝体温度场、应力场的全过程仿真分析方法。     

Oxides Catalysts of Rare Earth and Transient Metal for Catalytic Oxidation of Benzene

The catalysts of CeO2 and the mixture of CeO2 and CuO were prepared, and the activities of these catalysts for completely oxidizing benzene were studied.The results show that the optimal proportion of CeO2/CuO is 6: 4.The highest temperature at which benzene was completely oxidized on these catalysts at different airspeed was measured.Compared these catalysts with the noble metal used, our catalysts had superiority in the resources and the industrial cost besides good activities.     

万家寨大坝外部变形控制网综述

结合万家寨水利枢纽大坝外部变形控制网测量项目 ,从控制网的布设、标点建造、观测、数据处理及成果分析等方面进行了介绍。实际观测结果说明 ,该控制网能够准确反映大坝运行状态 ,满足工程安全运行需要     

稀土改善09CuPTiRE耐候钢耐蚀性的作用机理

应用扫描电镜(SEM)、离子探针(IMA)、X射线光电子能谱(XPS)和交流阻抗法研究含不同稀土耐候钢稀土提高耐大气腐蚀作用机理。结果表明,合适的稀土含量可显著提高钢的耐腐蚀性,稀土能促进Si、Cu和P在内锈层中以Si~(4+)、Cu~+和P~(5+)形态富集,并观察到锈层中的稀土。钢中加入稀土形成了致密连续厚而粘附性好的含硅铜稀土的复合铁锈层,从而提高了抗大气腐蚀性能。