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21.
22.
Here, we report on the application of corroles as analytically active compounds in liquid membrane electrodes (ISE) that are sensitive towards salicylic acid and salicylate.The potentiometric signals generated by corrole-incorporated ISEs strongly depend on the pH of the aqueous sample solution and the membrane composition, such as the presence of lipophilic sites. Corrole incorporating ISEs are characterised by a low detection limit (4.0 × 10−5 M) and a wide linear range (4.0 × 10−5 to 5.3 × 10−3 M). Also, they are free from interference versus other organic anions.The mechanism of the generation of the potentiometric signals of corrole incorporating ISEs in the presence of salicylate anion, as well salicylic acid, will be discussed. 相似文献
23.
准噶尔盆地腹部普遍发育深层(大于4000m)超压系统,很多钻井都钻遇超压。通过对超压段钻井、地质、测井、地震特征系统研究发现,超压段泥浆密度大幅增加,具有高声波时差、低电阻率以及地震低速的超压响应特征。利用Dix公式计算地震层速度和利用Fillippone公式计算地层压力,得到超压数据体。准噶尔盆地腹部超压在白垩系及其以下沉积地层中均有分布,超压层的深度范围不同。分1井西凹陷边缘以及昌吉凹陷西南有空层现象。超压顶面分布的层位由北往南、从东到西逐渐变浅,从三叠系顶部到白垩系底部。深部超压对油气分布和富集有着重要的控制作用,准噶尔盆地腹部超压层分布的研究将对本区油气勘探起积极的推动作用。 相似文献
24.
Manual responses can be defined by differing response parameters. Any of them may generate a Simon effect. For all those response parameters, the same implementation of the Simon effect (in terms of subserving mechanism) is assumed. In 3 experiments, subjects had to respond with either fingers or sticks. Temporal properties of the Simon effect changed with response parameters relevant in a task. The Simon effect for manual responses decayed. For stick responses, in which the action goal differed from the anatomical mapping of the acting hand, a sustained Simon effect was observed. However, if the action goal for stick responses was not instrumental for selecting the correct response, the Simon effect decayed. The findings are consistent with the notion of different mechanisms involved in generating a Simon effect. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
25.
Exchanges of total N and C between a river and its floodplain forest have been enhanced by sedimentation processes during flood pulses at a 5‐ha bottomland hardwood forest located at the Olentangy River Wetland Research Park in central Ohio. In the spring of 2000, the forest was hydrologically restored by notching an artificial levee that had separated the Olentangy River and its floodplain forest for 100 years. One‐hundred flat sediment traps (30 cm × 30 cm) were used to collect sediment samples during spring/summer flooding events from 2003 to 2005. Results showed that sediment deposition is determined by the landscape variability during flooding events, Net sediment deposit in the wettest area averaged 134 ± 12 g‐dry wt m?2 in 2003, 127 ± 17 g‐dry wt m?2 in 2004 and 149 ± 23 g‐dry wt m?2 in 2005. Total N and C sedimentation ranged from 0.49 to 0.92 g‐N m?2 and 5.2 to 19.9 g‐C m?2. Fe dominates the sediment chemistry and results show the elemental abundance in the order of Al > Fe > Ca > K > Mg > S > P > Na > Mn > Zn > B > Cu > Mo. A hydrologic pulsing index (HPI) could be used as an indicator for mass changes of energies with hydrologic pulsing events. Restoration of seasonally flooded bottomland forests could stimulate potentially large nutrient and Fe releases, which would eventually lead to an enhanced forest productivity and biodiversity. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
26.
Herbert S. Bennett 《Journal of research of the National Institute of Standards and Technology》2007,112(4):209-221
In this paper, we present the theory for calculating Raman line shapes as functions of the Fermi energy and finite temperatures in zinc blende, n-type GaAs for donor densities between 1016 cm−3 and 1019 cm−3. Compared to other theories, this theory is unique in two respects: 1) the many-body effects are treated self-consistently and 2) the theory is valid at room temperature for arbitrary values of the ratio R = (Q2/α), where Q is the magnitude of the normalized wave vector and α is the normalized frequency used in the Raman measurements. These calculations solve the charge neutrality equation self-consistently for a two-band model of GaAs at 300 K that includes the effects of high carrier concentrations and dopant densities on the perturbed densities of states used to calculate the Fermi energy as a function of temperature. The results are then applied to obtain the carrier concentrations from Fermi energies in the context of line shapes in Raman spectra due to the coupling between longitudinal optical phonons and plasmons. Raman measurements have been proposed as a non-destructive method for wafer acceptance tests of carrier density in semiconductor epilayers. The interpretation of Raman spectra to determine the majority electron density in n-type semiconductors requires an interdisciplinary effort involving experiments, theory, and computer-based simulations and visualizations of the theoretical calculations. 相似文献
27.
The authors used visual search tasks in which components of the classic flanker task (B. A. Eriksen & C. W. Eriksen, 1974) were introduced. In several experiments the authors obtained evidence of parallel search for a target among distractor elements. Therefore, 2-stage models of visual search predict no effect of the identity of those distractors. However, clear compatibility effects of the distractors were obtained: Responses were faster when the distractors were compatible with the response than when they were incompatible. These results show that even in parallel search tasks identity information is extracted from the distractors. In addition, alternative interpretations of the results in terms of the occasional identification of a distractor before or after the target was identified could be ruled out. The results showed that flat search slopes obtained in visual search experiments provide no benchmark for preattentive processing. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
28.
Yoon Carolyn; Feinberg Fred; Hu Ping; Gutchess Angela Hall; Hedden Trey; Chen Hiu-Ying Mary; Jing Qicheng; Cui Yao; Park Denise C. 《Canadian Metallurgical Quarterly》2004,19(3):379
Understanding how aging influences cognition across different cultures has been hindered by a lack of standardized, cross-referenced verbal stimuli. This study introduces a database of such item-level stimuli for both younger and older adults, in China and the United States, and makes 3 distinct contributions. First, the authors specify which item categories generalize across age and/or cultural groups, rigorously quantifying differences among them. Second, they introduce novel, powerful methods to measure between-group differences in freely generated ranked data, the rank-ordered logit model and Hellinger Affinity. Finally, a broad archive of tested, cross-linguistic stimuli is now freely available to researchers: data, similarity measures, and all stimulus materials for 105 categories and 4 culture-by-age groups, comprising over 10,000 fully translated unique item responses. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
29.
A modified rainflow counting method 总被引:1,自引:0,他引:1
Nie Hong 《International Journal of Fatigue》1991,13(6):465-469
The rainflow counting method is commonly recognized to be a good cyclic counting method in fatigue life prediction and for testing engineering components and structures. However, it has some shortcomings, which are pointed out in this paper in connection with the analysis of the stress-strain response. A modified rainflow counting method is presented. Case studies show that all the cycles really existing in the stress-strain response that cannot be counted by the rainflow counting method can be counted by the modified rainflow counting method. So it can be said that the modified rainflow counting method is a more reasonable cycling counting method than the traditional rainflow counting method. 相似文献
30.
正压冲固基础海洋平台冰激振动动力响应 总被引:1,自引:0,他引:1
正压冲固基础海洋平台是一种新型平台桩基结构形式。采用三维有限元的数值分析方法,建立了正压冲固平台的三维有限元模型。基于冰激强迫振动理论提出动冰载荷的计算方法,根据海冰破碎长度和冰速确定冰载周期,冰强度限制的水平冰力作为冰力峰值,得到的动冰载荷用于正压冲固平台的动力响应分析,并依照规范计算了6倍桩径处刚性固定时的动力响应。三维有限元方法计算得到的动力响应大于6倍桩径刚性固定时的计算结果,结构安全性评估偏于安全。 相似文献