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Electro-organic synthesis without supporting electrolyte: Possibilities of solid polymer electrolyte technology 总被引:1,自引:0,他引:1
J. Jörissen 《Journal of Applied Electrochemistry》2003,33(10):969-977
The application of ion exchange membranes as solid polymer electrolytes (SPE) in fuel cells is state-of-the-art. This technology needs no supporting electrolyte; consequently it can be applied for electro-organic syntheses in order to save process steps. In this case the process is not predetermined to a maximized energy efficiency so that the selection of the cell design, of the electrode materials and of the operating conditions can be focused on a high selectivity of the electrode reactions. The electro-osmotic stream, which is caused by the solvation shells of the ions during their migration through the membrane, and hence is a typical property of SPE technology, has a significant effect on the electrode reactions. It generates enhanced mass transfer at the electrodes, which is beneficial for reaction selectivity. It can be influenced by the choice of, and possibly by the preparation of, the membrane. An additional remarkable advantage of SPE technology is the exceptional long durability of oxide coated electrodes. By combination of several process engineering methods stable operation of SPE cells has been realized, even for examples of non-aqueous reaction systems. Experiments up to 6000 h duration and in cells of up to 250 cm2 membrane area show the potential for industrial application. 相似文献
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一种通用型的目标数据仿真 总被引:5,自引:1,他引:4
给出了一种通用型的雷达目标模拟器 ,它能够方便直观的产生各种特征的三维目标轨迹 ,可实时离散出目标点迹 ,为雷达数据处理及精度分析提供数据来源。目标轨迹由一组特征点定义 ,修改方便 ,应用灵活 相似文献
147.
Measurement Method of the Thickness Uniformity for Polymer Films 总被引:1,自引:0,他引:1
YANGHong-liang RENQuan FANYun-zheng 《半导体光子学与技术》2003,9(2):128-132
Several methods for investigating the thickness uniformity of polymer thin films are presented as well their measurement principles.A comparison of these experimental methods is given.The cylindrical lightwave feflection method is found to can obtain the thickness distribution along a certain direction.It is simple and suitable method to evaluate the film thickness uniformity. 相似文献
148.
微带型Wilkinson功分器设计与实现 总被引:2,自引:0,他引:2
小型低功耗器件是射频电路设计的研究热点,而微带技术具有小型化低功耗的优点,为此在介绍微带型Wilkin-son功分器工作原理的基础上,使用基于矩量法的ADS软件设计、仿真和优化计算相关数据参数,并制作了一个微带功分器实例,最后对加工的样品进行实测,获得与仿真值吻合较好的预期结果。 相似文献
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Finite element piezothermoelasticity analysis and the active control of FGM plates with integrated piezoelectric sensors and actuators 总被引:3,自引:0,他引:3
An efficient finite element model is presented for the static and dynamic piezothermoelastic analysis and control of FGM
plates under temperature gradient environments using integrated piezoelectric sensor/actuator layers. The properties of an FGM plate are functionally graded in the thickness
direction according to a volume fraction power law distribution. A constant displacement-cum-velocity feedback control algorithm that couples the direct and inverse piezoelectric effects is applied to provide active feedback
control of the integrated FGM plate in a closed loop system. Numerical results for the static and dynamic control are presented
for the FGM plate, which consists of zirconia and aluminum. The effects of the constituent volume fractions and the influence
of feedback control gain on the static and dynamic responses of the FGM plates are examined.
Received: 13 March 2002 / Accepted: 5 March 2003
The work described in this paper was supported by a grant awarded by the Research Grants Council of the Hong Kong Special
Administrative Region, China (Project No. CityU 1024/01E). 相似文献