Determination of the total concentration and speciation of Al(III) in tea infusions

The aluminium species in different tea infusions were investigated, by determining their stability constants and concentration. This was done for some particular samples using a simple experimental method based on the sorption of aluminium on the strongly sorbing resin Chelex 100, by a batch procedure. From the thermodynamic information obtained it is possible to calculate the concentration of the different species, and in particular that of the free metal ion, which is very important for evaluating the adsorption of aluminium on biological membranes. It was found that aluminium in the tea infusions here considered is present at high total concentration, approximately 0.1 mM, but mainly linked to strong complexes, for instance with side reaction coefficient higher than 10(5.11) at pH 3.95 in one case (tea 1). This could be the reason for the low toxicity of aluminium in tea. These strong complexes were not dissociated even in the presence of Chelex 100. In this case only a limiting value of the reaction coefficient could be evaluated. The presence of the very strong complexes was found in all the tea sample here considered. In two of the considered samples (one black and one green tea) a part of Al(III) was linked to less strong complexes, for example with a reaction coefficient 10(4.14) (tea 2, pH 4.20). The presence in the considered tea infusions of other substances able to complex aluminium was also detected, by the well known ligand titration procedure, at concentration ranging from 0.65 to 3.37 mM in three tea infusions, and at somewhat higher concentration in the case of the ready drink, which was also considered for comparison.     

Some better practices for measuring racial and ethnic identity constructs.

Racial and ethnic identity (REI) measures are in danger of becoming conceptually meaningless because of evaluators' insistence that they conform to measurement models intended to assess unidimensional constructs, rather than the multidimensional constructs necessary to capture the complexity of internalized racial or cultural socialization. Some aspects of the intersection of REI theoretical constructs with research design and psychometric practices are discussed, and recommendations for more informed use of each are provided. A table that summarizes some psychometric techniques for analyzing multidimensional measures is provided. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

连续箱梁桥中跨合龙段劲性骨架优化设计

结合某连续箱梁桥悬臂施工实践,对中跨合龙段劲性骨架设置和受力进行了分析,推导了劲性骨架设计的理论计算公式,并分析了劲性骨架刚度大小对桥梁整体结构的影响。     

Prediction of the effects on dynamic response due to distributed structural modification with additional degrees of freedom

The aim of this study is to investigate means of efficiently assessing the effects of distributed structural modification on the dynamic properties of a complex structure. The dynamic properties of the modified structure can be determined by experimental testing or numerical simulation, both of which are complex, expensive and time-consuming. Assuming that the original dynamic characteristics are already established and that the modification is a relatively simple attachment, the modified dynamic properties may be determined numerically without solving the equations of motion of the full-modified structure. The frequency response functions (FRFs) of the modified structure can be computed by coupling the original FRFs and a delta dynamic stiffness matrix for the modification introduced. The validity of this approach is investigated by applying it to a cantilever beam to which a smaller beam is attached as modification. The original FRFs were obtained experimentally as well as numerically. The delta dynamic stiffness matrix was determined numerically by modeling the attachment and part of the original structure including the attachment points. The FRFs of the modified beam were then computed. Good agreement is obtained by comparing the results to the FRFs of the modified beam determined experimentally as well as by numerical modeling of the complete modified structure.     

建设领域劳务分包现状分析及对策

从劳务市场的现状入手,分析劳务合同存在的问题,寻找解决办法,有利于对建筑市场进行行政指导、行政监督和建筑业企业的健康发展。     

Development of adolescent reading comprehension in language 1 and language 2: A longitudinal analysis of constituent components.

This study investigated the relationship between reading comprehension development of 389 adolescents in their dominant language (Language 1 [L1], Dutch) and a foreign language (Language 2 [L2], English). In each consecutive year from Grades 8 through 10, a number of measurements were taken. Students' reading comprehension, their linguistic knowledge (vocabulary and grammar knowledge) and processing efficiency (speed of word recognition and sentence comprehension) in both languages, and their metacognitive knowledge about reading were assessed. The relative strengths of the effects of these components of reading were analyzed to distinguish among 3 hypotheses about the relationship between L1 and L2 reading comprehension: the transfer hypothesis, the threshold hypothesis, and the processing efficiency hypothesis. The transfer hypothesis predicts a strong relationship between L1 and L2 reading comprehension and a strong effect of metacognitive knowledge on L2 reading comprehension, whereas the threshold and processing efficiency hypotheses predict a more important role of language-specific knowledge and processing skills. Results support the transfer hypothesis, although language-specific knowledge and fluency also contribute to L2 reading performance. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Linear mixture model applied to Amazonian vegetation classification

Many research projects require accurate delineation of different secondary succession (SS) stages over large regions/subregions of the Amazon basin. However, the complexity of vegetation stand structure, abundant vegetation species, and the smooth transition between different SS stages make vegetation classification difficult when using traditional approaches such as the maximum likelihood classifier (MLC). Most of the time, classification distinguishes only between forest/non-forest. It has been difficult to accurately distinguish stages of SS. In this paper, a linear mixture model (LMM) approach is applied to classify successional and mature forests using Thematic Mapper (TM) imagery in the Rondônia region of the Brazilian Amazon. Three endmembers (i.e., shade, soil, and green vegetation or GV) were identified based on the image itself and a constrained least-squares solution was used to unmix the image. This study indicates that the LMM approach is a promising method for distinguishing successional and mature forests in the Amazon basin using TM data. It improved vegetation classification accuracy over that of the MLC. Initial, intermediate, and advanced successional and mature forests were classified with overall accuracy of 78.2% using a threshold method on the ratio of shade to GV fractions, a 7.4% increase over the MLC. The GV and shade fractions are sensitive to the change of vegetation stand structures and better capture biophysical structure information.     

Upper-bound analysis of the pressure-assisted injection forging of thick-walled tubular components with hollow flanges

An upper-bound analysis of the pressure-assisted injection forging (PAIF) of thick-walled tubular components with hollow flanges was conducted to predict the maximum forming-pressure requirements. The polymeric pressurizing material and the pure aluminium work material employed were assumed to obey the von-Mises’ yield criterion, the two materials being divided into three and six zones, respectively, and described using kinematically admissible velocity fields. An upper-bound solution was derived based on this model. Experiments were conducted to validate the solution. The results suggest that the upper-bound analysis has sufficient accuracy for the prediction of the forming-pressure requirements. Subsequently, a parametric analysis was conducted to study the effects of variation of the principal parameters of the process and the geometry, such as tube thicknesses, flange dimensions and friction, on the forming-force requirements, which showed other useful applications of the upper-bound solutions.     

Generalized null space uncorrelated Fisher discriminant analysis for linear dimensionality reduction

We propose a generalized null space uncorrelated Fisher discriminant analysis (GNUFDA) technique integrating the uncorrelated discriminant analysis and weighted pairwise Fisher criterion. The GNUFDA can effectively deal with the small sample-size problem and perform satisfactorily when the dimensionality of the null space decreases with increase in the number of training samples per class and/or classes, C. The proposed GNUFDA can extract at most C-1 optimal uncorrelated discriminative vectors without being influenced by the null-space dimensionality.