A method of estimating the standard gibbs free energy of formation

Standard Gibbs free energy of formation (ΔG_f⁰), an important property needed in design calculations has been estimated using molar refraction, R_M. The linear relationships derived between ΔG_f⁰ and R_M tested with the data on 8 series of hydrocarbons at 228 compounds yielded average deviations comparable to the methods cited in recent literature. The method can be used as an alternative to the existing ones, because of its simplicity combined with reasonable accuracy.     

Fractional composition of partly hydrolysed polyvinyl acetate and its compatibility with hydroxypropyl methylcellulose in aqueous solutions

Fractionation of partly hydrolysed polyvinyl acetate (PVA) was performed by warming of its aqueous solutions. The following properties of the obtained fractions were determined: viscosity, molecular weight and molecular weight distribution, surface tension, and absorbance in the IR range. The blockiness of the polymer molecules, characterized by their behaviour towards iodine-containing systems such as I₂,-H₃BO₃ and I₂,-KI, was estimated. Fractionation of the aqueous solutions of PVA by warming is based mainly on the different internal molecular structure of the separated products, i.e. on the length of the vinyl acetate blocks in the PVA molecules and, to a lesser extent, on the degree of hydrolysis and the degree of polymerization. The more blocklike are the PVA molecules, the less compatible are the polymers in the PVA-hydroxypropyl methylcellulose (HPMC)-water system. At phase separation in this sytem the PVA molecules which are not compatible with HPMC are, in the first place, those of the highest blockiness.     

Finite Element Analysis of a Moving Boundary Value Problem

A finite element formulation and the solution of a set of nonlinear coupled heat and mass transfer equations for a two-phase system with a moving evaporation interface is presented. The interface condition takes into account the moisture transfer balance at the moving boundary. The finite element results were compared with existing results for a single phase system for model validation. In the two-phase system, the movement of evaporation front has an appreciable effect on the temperature and moisture distribution inside the porous medium during drying. The effect of the nondimensional heat of vapourization parameter γ on the evaporation front, temperature and moisture distribution in porous medium was studied. The higher the value of γ, the slower is the movement of the evaporation front. The temperature decreased and the moisture content increased as the nondimensional vapourization parameter γ increased. This model has potential applications in studying the heat and mass transfer characteristics in food and biomaterials.     

中小型变压器供电电机起动方式的选择

通过分析和计算及实例，从允许电压降范围和电动机母线电压校验两方面叙述了电动机起动时如何合理地选择起动的方式。     

高温过热器12Cr2MoWVTib（102）钢管的显微组织和相结构分析

本文对原始状态和在火力发电厂使用不同时间的高这热器１０２钢管进行了显微组织和相结构变化规律的探讨和研究。显微组织研究表明，１０２钢管在高温高压下长期运行过程中，使用温度对显微组织和碳化物相有明显影响，而使用时间对其影响不如温度影响强烈。碳化物颗粒图象分析表明，碳化物随着使用时间缓慢长大，而新的碳化物不沉淀，使颗粒总数不断增加，颗粒，间距逐渐缩小。Ｘ射线衍射数据证明，钢管在高温长期使用过程中，ＭＣ相     

双相位编码在数据通信中的应用

双相位码是数据串行通信和记录中使用的一种编码方法。在集散控制系统中使用的磁带机和飞行数据记录器中得到广泛应用。本文主要介绍双相位码的编码、译码原理及双相位码的特点;重点论述双相位码的编码和译码过程在微机上的实现。工程实践和实验表明,用微机实现双相位码的编码和译码过程是切实可行的。试用在TDC-2000集散控制系统中获得了圆满成功。     

山西塔儿山地区金成矿的构造控制因素

本文通过分析晋南塔儿山地区的构造特征，探讨了该区金成矿作用的构造控制因素。     

恢复地层剥蚀厚度方法综述

恢复地层剥蚀厚度是对盆地进行定量研究的重要基础工作。本文综述、评价了目前常用的恢复剥蚀厚度的方法,并对作者曾提出的天然气平衡浓度法作了进一步的阐述。     

RH-KTB耐材长寿技术研究及应用

介绍了宝钢RH-KTB工艺条件下RH用镁铬砖的应用和提高浸渍管管龄、下部槽槽龄的方法.