Enantioselective extraction of mandelic acid enantiomers based on chiral ligand exchange

Based on the chiral ligand exchange, the distribution behavior of mandelic acid enantiomers, and the partition of Cu^2 at different pH values were studied in a water/alcohol two-phase system containing Cu^2 and N-ndodecyl-L-proline(A). The influences of the solvent sort, the pH value, the concentrations of Cu^2 and chiral ligand on the partition coefficient(K) and separation factor(α) were discussed. The experimental results show that the A formed has more stable ternary complex with D-mandelic acid enantiomer than with L-mandelic acid enantiomer. There is an important influence of the pH value on K and a. When the pH values are less than 3.5, the formation of binary complexes is thermodynamically unfavourable. K and a become maximum when pH values are above 3.5 and the molar ratio of the chiral ligand to Cu^2 is 2:1.     

在玻璃衬底上制作K~+离子交换掩埋波导的新工艺

本文报道用不同离子两步交换技术,在玻璃衬底上制作K~+离子交换掩埋波导的新工艺,它不要求施加外电场。用X射线能谱(XES)分析技术测试了K~+离子的浓度分布,证明所制出的样品是掩埋波导。     

离子注入对铁及其低合金、铝及其合金耐腐蚀性能的影响

离子注入对金属腐蚀行为的研究已达30年．研究结果表明离子注入对改变金属表面成分和表面性能是极为有效的技术．本文概述了离子注入对铁及其低合金、铝及其合金的腐蚀电化学行为的影响．涉及的注入离子达十余种。     

等离子体浸没式离子注入-离子束增强沉积TiN膜研究

本文采用一种新型的等离子体浸没式离子注入 离子束增强沉积的技术(PIII IBAD),在Cr12MoV钢基体上制备出了TiN膜,对沉积膜的组织进行了光电子能谱分析,并对沉积膜进行了硬度检测、摩擦试验及磨痕形貌分析。试验结果表明,沉积膜中的组织为TiN、TiO2和Ti2O3,TiN膜具有高达Hv3200的高硬度和极其优良的摩擦性能。     

无锡市运河实验中学改扩建设计随感

通过对无锡市运河实验中学改扩建项目的回顾,阐述如何发掘原有校园空间环境的价值,并且通过借鉴中国古典园林的设计手法,使得老校园焕发出新生机。     

增加黄金储备规避外汇风险

近几年，我国外汇储备逐年增加，而美元汇率偏弱，使我国承担很大的外汇风险。为了规避外汇风险，应增加黄金储备。文中提出了我国增加黄金储备总量的理由以及增加黄金储备的途径。这些建议具有可操作性，可以提供给有关部门参考。     

Zeolite synthesis from paper sludge ash with addition of diatomite

BACKGROUND: This study aimed to investigate the synthesis of zeolites from paper sludge ash (PSA) with added diatomite to remove both NH₄⁺ and PO₄^3? for water purification. The PSA had low Si and significant Ca contents. Four types of diatomite: white (T‐W) and brown (T‐B) from deposits of marine origin in Takanosu, and white (S‐W) and gray (S‐G) from lacustrine deposits in Shonai, were added to NaOH solution to increase the Si content and thereby synthesize zeolites with high cation exchange capacity (CEC). RESULTS: The order of the amounts of Si extracted from the diatomite to the alkali solution was S‐W > T‐W = T‐B > S‐G, which correlates with the amorphous SiO₂ content of diatomite. The original ash without addition of diatomite yielded hydroxysodalite with CEC of about 1.0 mmol g^?1. For all samples, the addition of diatomite to the solution yielded zeolite‐P with a higher CEC, but the addition of excess Si inhibited the synthesis of zeolite‐P, and the CEC of the product was low. A product with high CEC including zeolite‐P was obtained in a solution with around 500 mmol L^?1 of Si concentration, and had the ability to remove both NH₄⁺ and PO₄^3?. CONCLUSION: Diatomite has the potential for used as an additive for the synthesis of high CEC zeolite from PSA. The product with zeolite‐P exhibited relatively high CEC, capacity for NH₄⁺ uptake, and the ability to remove PO₄^3? by precipitation, which is preferable for water purification applications. Copyright © 2008 Society of Chemical Industry     

大庆蜡油在酸性催化剂上反应机理的研究

以大庆蜡油为原料，采用两种不同类型的催化剂，在流化床反应器实验装鬣上进行催化裂化反应。结果表明，大庆蜡油在酸性催化剂上反应所产生的干气组成与高烯烃催化裂化汽油相同，干气的产生主要是单分子裂化反应所造成的。从干气产率、组成以及液化气组成可以看出，大庆蜡油在不同类型的催化剂上明显地表现出裂化反应类型的差异。     

Preparation and adsorption behavior of a cellulose‐based,mixed‐mode adsorbent with a benzylamine ligand for expanded bed applications

A novel mixed‐mode expanded bed adsorbent with anion‐exchange properties was explored with benzylamine as the functional ligand. The cellulose composite matrix, densified with stainless steel powder, was prepared with the method of water‐in‐oil suspension thermal regeneration. High activation levels of the cellulose matrix were obtained with allyl bromide because of the relative inertness of the allyl group under the conditions of the activation reaction. After the formation of the bromohydrin with N‐bromosuccinimide and coupling with benzylamine, the activated matrix was derived to function as a mixed‐mode adsorbent containing both hydrophobic and ionic groups. The protein adsorption capacity was investigated with bovine serum albumin as a model protein. The results indicated that the prepared adsorbent could bind bovine serum albumin with a high adsorption capacity, and it showed salt tolerance. Effective desorption was achieved by a pH adjustment across the isoelectric point of the protein. The interactions between the cell and adsorbent were studied, and the bioadhesion was shielded by the adjustment of the salt concentration above 0.1M. Stable fluidization in the expanded bed was obtained even in a 2% (dry weight) yeast suspension. The direct capture of target proteins from a biomass‐containing feedstock without extra dilution steps could be expected with the mixed‐mode adsorbent prepared in this work, and this would be especially appropriate for expanded bed adsorption applications. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008