Influence of heat transfer on anodic oxidation of aluminium

The influence of convective heat transfer on constant current density anodizing of aluminium in sulfuric acid has been examined in a wall-jet electrode reactor. The uniformity of the anodic film thickness is related to the local electrode temperature distribution, which is dependent on the convection. The higher the local temperature, the greater the local oxide thickness. An increased local temperature enhances local field assisted oxide dissolution at the pore bases, and consequently acts to increase the local current density. At relatively high current densities, local features develop on the electrode surface, accompanied by high initial, local temperature rises. The relevance of such local features, limiting useful oxide growth, is considered further.     

Design and control of an olefin metathesis reactive distillation column

This paper considers the design and control of a reactive distillation column in which one reactant is consumed and two products are formed (A?B+C). The volatilities are α_B>α_A>α_C, i.e. the reactant is intermediate boiling between the two products. The metathesis of 2-pentene is considered as the demonstrative example. The column has a single feed of the intermediate boiling reactant. The distillate contains mostly light component and the bottoms mostly heavy.Three designs are considered: the base case (low-conversion/low-pressure), a low-conversion/high-pressure case and a high-conversion/high-pressure case. The base design is obtained from the literature, and the other two steady-state designs are optimized with respect to the total annual cost. All the designs are found to be openloop stable. Five control structures are studied for the base design. Then the best two structures are applied to the remaining two designs. This category of reactive distillation exhibits less challenging problems than other categories since it uses a single feed, which eliminates the need for the control structure to perfectly balance two fresh feeds.Simulation results demonstrate that effective dynamic control is provided by a control structure that uses two temperatures to maintain the purities of both product streams. No internal composition measurement is required. This structure is found to be robust and stable and rejects loads and tracks setpoints very well.     

Neutral poly(3,4-ethylenedioxythiophene-2,5-diyl)s: preparation by organometallic polycondensation and their unique p-doping behavior

Neutral and non-doped poly(3,4-ethylenedioxythiophene), PEDOTh(Ni), and its hexyl derivative, PEDOTh-C₆(Ni), have been prepared by organometallic dehalogenation polycondensation of 2,5-dichloro-3,4-ethylenedioxythiophene and its hexyl derivative with a zerovalent nickel complex. PEDOTh-C₆(Ni) was soluble in organic solvents and ¹H NMR data indicated that it had an M_n of 11,000. MALDI-TOF mass analysis of PEDOTh(Ni) gave M_n and M_w of about 1700 and 2400, respectively. PEDOTh-C₆(Ni) showed a UV-Vis absorption peak at 546 nm in CHCl₃. Electrochemical oxidation of PEDOTh-C₆(Ni) started at about −0.40 V vs Ag⁺/Ag and gave a peak at 0.20 V vs Ag⁺/Ag. Chemical and electrochemical oxidation (or p-doping) of PEDOTh-C₆(Ni), both in solutions and in a solid state, led to weakening of the original π-π^∗ peaks and rise of new peak(s) in a region of 800-1500 nm. The p-doping of PEDOTh-C₆(Ni) caused not only a decrease in the intensity of ¹H NMR signals of the bridging ethylene hydrogens but also a decrease in that of the hexyl side chain, suggesting a strong interaction of the p-dopant with the side chain. NMR data of poly(3-methoxythiophene-2,5-diyl) also supported an assumption that p-doping brings about a severe change in electronic state of the substituent attached to the polythiophene main chain. PEDOTh(Ni) had a density of 1.71 g cm⁻³; the molecular packing mode of PEDOTh(Ni) is discussed based on the density of the polymer and its XRD data.     

电流模式n阶传输函数的OA-OTA实现

提出了一种新的实现任意 n阶电流模式传输函数的网络结构。该电路仅含运算放大器 (OA)和运算跨导放大器 (OTA)有源器件 ,因而适于全集成。适当设置 OTA的跨导值能实现任意高阶传输函数 ,且传输函数的系数可独立调整。文中推导了滤波器的设计公式 ,并给出了截止频率为 1 0 0 k Hz的三阶巴特沃斯低通滤波器实例 ,PSPICE仿真结果表明所提电路及设计公式是正确的     

Rich photoluminescence emission of SnO2–SiO2 composite aerogels prepared with a co-fed precursor sol–gel process

Tin oxide–silica composite aerogels were successfully prepared with a co-fed precursor sol–gel process. The crystallinity of the tin oxide nanoparticles, embedded in the mesoporous SiO₂ network, was improved with increasing the post-reaction thermal treatment temperature. The composite aerogels exhibited a rich photoluminescence (PL) emission contributed by both SnO₂ and SiO₂. The PL peak of 346 nm was from the near band edge emission of the tin oxide nanoparticles, and the ones located at 310 and 476 nm were attributable to the oxygen deficiencies of the silica network. Three more emission peaks, 387, 432, and 522 nm, were observed, with the 387 nm peak contributed by the oxygen vacancies V_O⁺⁺, the 432 nm peak by the Sn interstitials, and the 522 nm peak by the oxygen vacancies V_O⁺, respectively, of the tin oxide nanoparticles. The intensities of these three defect level emissions were found decreased, as compared to that of the near band edge emission, with increasing the post-reaction thermal treatment temperature as the tin oxide crystallinity improved.     

对完善公司物资供应管理体系的思考

针对经“债转股”和资产重组成立的北京东方石油化工有限公司物资供应管理特点和存在的问题，从供应管理模式、采购方式、采购过程监控、信息化管理、物资储备、人员结构等6个方面，分析了目前供应管理存在的问题和不足，并针对问题通过对物资供应管理体制的分析和思考，提出对策，为新的物资供应体制的建立提供参考。     

Catalytic steam reforming of methane over La0.8Sr0.2CrO3 based Ru catalysts

La_0.8Sr_0.2CrO₃ based Ru catalysts were studied as potential new anodic materials for Solid Oxide Fuel Cells directly fed with methane and operating at intermediate temperature under water deficient conditions. Two kinds of materials very close in composition were obtained following two different preparation procedures. Catalyst samples were characterized by physicochemical methods (XRD, SEM, BET and Chemical Analysis) and studied in methane steam reforming under water deficient conditions. Carbon formation during catalytic testing was studied by temperature programmed oxidation (TPO). Both types of catalysts were found very active and resistant to carbon formation. The unusual oscillatory behavior of the catalytic activity observed for one type of catalyst was discussed.     

利用自生气的油气田开发开采工艺技术概况

油气田开发工艺技术中使用的自生气有N2、O2、CO2、ClO2和混合气五大类型，来源于化学反应和微生物的代谢产物。自生N2主要来自亚硝酸盐和铵盐的氧化还原反应。自生O2则来自过硫酸盐和过氧化物的高温分解。白生CO2来自碳酸盐与酸的反应及含氮类有机物的高温分解。自生混合气包括高能气体和生物气，高能气体是火药或炸药爆燃产生的混合气，生物气是微生物代谢产生的混合气。自生气工作液在油气田现场已应用于固井、射孔、解堵、压裂、调剖和三次采油等广阔的领域。本文概述油气田开发开采中利用五大类自生气的19项工艺技术。参43.     

高层民用建筑安全疏散及应急对策

文章从高层建筑的火灾特点出发,分析了高层民用建筑安全疏散的重要性和必要性,并结合高层民用建筑安全疏散通道因素存在的问题提出了若干对策,以求更好地满足现代高层建筑对消防安全的需要.