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11.
《矿业科学技术学报(英文版)》2021,31(3):507-513
A novel method of pellet calcification roasting-H_2 SO_4 leaching was proposed to efficiently separate and extract vanadium(V) from vanadium-titanium(V-Ti) magnetite concentrates.The leaching rate of V is as high as 88.98%,while the leaching rate of impurity iron is only 1.79%.Moreover,the leached pellets can be used as raw materials for blast furnace ironmaking after secondary roasting.X-ray photoelectron spectroscopy(XPS) and scanning electron microscopy with energy dispersive X-ray spectrometry(SEMEDS) analyses showed that V~(3+) was oxidized to V~(5+) after roasting at 1200℃,and V~(5+) was then leached by H_2 SO_4.X-ray diffraction(XRD) analyses and single factor experiment revealed a minimal amount of dissolved Fe_2 O_3 during H_2 SO_4 leaching.Therefore,a high separation degree of V and iron(Fe) from V-Ti magnetite concentrate was achieved through H_2 SO_4 leaching.Compared with the traditional roastingleaching process,this process can achieve a high selectivity of V and Fe,and has excellent prospects for industrial production. 相似文献
12.
13.
重金属强化含金矿石的氰化浸出 总被引:2,自引:0,他引:2
通过分析铊、铋、汞和铅等重金属强化金氰化溶解的电化学原理,对含金氧化物矿石和难浸硫化物金精矿进行了重金属强化浸金研究.结果表明:重金属对金氰化溶解的阳极过程有显著的强化作用,但在常规供氧条件下,金的溶解速率并未显著提高;只有同时采用阴极强化措施,才能使重金属起到显著提高金溶解速率的作用;对于含金氧化物矿石,单独采用重金属强化即可明显提高浸金速率,如果在过氧化氢助浸的基础上添加重金属,金的浸出速率会有更大幅度的提高;对硫化物金精矿而言,单独采用重金属无明显强化效果,只有在添加过氧化氢作为辅助氧化剂的基础上,重金属对金的浸出才能起到强化的作用,该体系中过氧化氢起到了强化阴极过程和氧化硫化物的双重作用. 相似文献
14.
LI Ximing CHEN Jiayong Institute of Chemical Metallurgy Academia Sinica Beijing ChinaR.KAMMEL Institut Für Metallurgie Technische Universitt Berlin Germany Research Assistant Institute of Chemical Metallurgy Academia Sinica Beijing China 《金属学报(英文版)》1992,5(9):153-157
The influence of mechanical activation on the leaching behaviour of scheelite was studied bymeans of fine grinding in an attritor and subsequently HCl leaching in presence of PO_4~(3-).Results showed that after fine grinding in the attritor,the reaction rate of scheelitewith HCl-Na_3PO_4 solution was remarkably increased,the extraction of W increased fromabout 8 to 99%.The IR spectra and X-ray diffraction analysis indicated that in addition toan enlargement of surface area the fine grinding action had made also changes of fine struc-ture and reactivity of solid surface,hence the leaching process of scheelite can be carried outunder mild leaching conditions. 相似文献
15.
Behavior of calcium silicate in leaching process 总被引:3,自引:0,他引:3
1 INTRODUCTIONIngeneral ,aluminacan tbeproducedeconomicallybyBayerprocessinChinabecausethebauxitecharacter izesindiasporeandabout 80 %bauxiteexistinlowde greeofthemassratioofaluminatosilica(A/S)whichvariesfrom 4to 9[1] .Andabout 4 0 %ofaluminaispro ducedbysintering… 相似文献
16.
Corrosion in wet lime/limestone systems used for flue gas desulfurization in thermal power plants is of great concern. The
frequent variations in acidity and in chloride and fluoride ion concentrations experienced by such systems pose a serious
threat to the materials of construction. Currently used materials mostly type 316L stainless steel often fail to meet their
life expectancy. The present study evaluates the performance of advanced Ni- Cr- Mo alloys 59 and C- 276 in a simulated sulfur
dioxide scrubber environment. Accelerated tests showed that high Ni- Cr- Mo alloys have little tendency to leach metal ions
such as chromium, nickel, and molybdenum at different impressed potentials. Scanning electron microscopy was used to examine
the morphology of pitting attack. 相似文献
17.
18.
Slow growth and high seedling mortality limit direct seeding establishment of guayule (Parthenium argentatum G.). This study was conducted to assess seedling growth enhancement by the addition of different rates and forms of N fertilizers and Ca salts. Experiments were conducted in a greenhouse with cultivar 593 under both surface and subirrigated conditions using water low in salts (salinity of 0.8 dSm–1, SAR of 5.0 and 10 mg Ca L–1). Under surface-irrigated conditions, seedling height and fresh plant weight increased with N application to the irrigation water to 70 mg L–1. The best seedling growth was observed when (NH4)2SO4 was added in combination with CaCl2 or CaSO4. Progressively less growth was observed by addition of (NH4)2SO4 alone, CO(NH2)2 plus CaSO4, CO(NH2)2 alone and Ca(NO3)2. When seedlings were subirrigated, however, the best growth was observed with Ca(NO3)2. Intermediate growth was obtained with (NH4)2SO4 plus CaSO4 and lowest growth rates with (NH4)2SO4 alone. These differential responses may be explained by the differences in leaching and volatile characteristics of the N forms. Growth enhancement from N and Ca additions increased with time with significant increases 45 days after seeding. Nitrogen application with Ca may be effective amendment in promoting subsequent growth of direct seeded guayule. 相似文献
19.
Characterization of nanoporous materials prepared from montmorillonite clay and its application to the decolorization of mare's milk oil 总被引:1,自引:0,他引:1
J. Temuujin M. Senna Ts. Jadambaa D. Burmaa Sh. Erdenechimeg J. Amarsanaa G. Burmaa 《Journal of Porous Materials》2006,13(1):49-53
Nanoporous materials have been prepared by leaching the purified montmorillonite clay with sulfuric acid (H2SO4) solution with varying concentrations (0.5–2 M) at 80°C for 0.5–4 h. Acid leaching causes partial amorphisation of the clay
with depletion of MgO, Al2O3, CaO and Fe2O3 components mostly from interlayer and octahedral sites. This increases the specific surface area by more than 3 times, i.e.
from 49.1 to 157 m2/g. The pore-size distribution curves calculated from the adsorption isotherms of the leached montmorillonite show that most
of the pores are in the mesoporous region with their diameter ranging 3–4 nm. This material turns out to be appropriate for
bleaching of the mare's milk oil. The chemical and structural changes of the acid-leached montmorillonite are discussed in
terms of the decolorization capacity. 相似文献
20.
从煤矸石制取氯化铝联产橡胶填料的研究 总被引:1,自引:0,他引:1
在实验室小试、中试装置上进行了从煤矸石制取氯化铝联产橡胶填料的研究,考察了煤矸石性质、工艺条件等对产品质量的影响,结果发现最佳工艺参数为焙烧温度600~q00℃.焙烧时间为15~90min.焙烧温度对产品质量影响更为显著,制得结晶氯化铝产品质量达到合格品标准,填料用作橡胶制品填充剂具有较好补强与抗曲性能,其胶片的物理机械性能达到普通橡胶板标准。 相似文献