Indium tin oxide nanosized composite powder prepared using waste ITO target

Indium tin oxide （ITO） nano-particles were prepared directly using waste ITO target, which had been coated by magnetron controlled sputtering. The waste ITO target was cleaned with de-ionized water, and then dissolved in acid, filtrated, neutralized, manipulated through azeotropic distillation and finally dried, and in this way the precursor of indium tin hydroxide was obtained. The nanosized rio composite powder was prepared after the precursor heat-treated at 500℃ for 2 h. TEM images show a narrow distribution of particle size is 5-20 nm and the particle size can be controlled. Its granule has a spherical shape and the dispersion of the particle is well. X-ray diffraction （XRD） patterns indicate the only cubic In2O3 phase in the ITO powder hot-treated at 500℃. The purity of ITO composite powder is 99.9907%. The content of radium within filtrate was detected by using the EDTA titration of determination of indium in the ITO powder and ITO target. Appropriate amount of SnCl4.5H2O was dissolved in the filtrate, and then ITO powder containing 10 wt.% SnO2 was successfully prepared by heat-treating.     

Three-dimensional combined finite-discrete element approach for simulation of single layer powder Compaction process

The application of a combined finite-discrete element modeling approach to simulate the three-dimensional microscopic compaction behavior of single-layer metal powder system was described. The process was treated as a static problem, with kinematical component being neglected. Due to ill condition, Cholesky‘s method failed to solve the system equations, while conjugate gradient method was tried and yielded good results. Deformation of the particles was examined and compared with the results of physical modeling experiments. In both cases, the inner particles were deformed from sphere to polygonal column, with the edges turning from arc to straight line. The edge number of a particle was equal to the number of particles surrounding it. And the experiments show that the ductile metal particles can be densified only by their plastic deformation without the occurrence of rearrangement phenomenon.     

钛镍多孔材料的制备及其显微组织与形状记忆性能

采用粉末烧结法制备了高孔隙率的Ti-50.8 at%Ni形状记忆合金(SMA),并对其显微组织和形状记忆性能进行了研究。结果表明,用该种方法制备的多孔合金样品具有孔隙分布均匀以及开孔率高的特点,其平均孔径在200μm左右。合金组织主要由奥氏体NiTi相(B2)和单斜马氏体NiTi相(B19’)组成。循环加载-卸载实验结果表明,该多孔材料能表现出一定的形状记忆效应,而且形状记忆效应随孔隙率的增加而降低。     

分步酸溶法提取镍基高温合金粉末中非金属夹杂物的研究

本文提出利用分步酸溶法准确提取镍基高温合金粉末中非金属夹杂物,实现夹杂物的定量表征。首先选用最佳配比为HCl:HNO3=6:1的混合浓酸溶解镍基高温合金粉末,然后利用H2O2-草酸体系和稀酸将酸溶产物和难溶金属元素完全溶解。利用SEM、EDS等表征手段分析了最终获得的非金属夹杂物的数量、形貌、成分和尺寸分布,结果表明,该方法具有简便快速、分离效率高、回收率高、对非金属夹杂物的影响较小、可提取夹杂物粒径范围广等优点。此外,本文还对比了分步酸溶法和水淘洗法的提取效果,发现分步酸溶法对粒径大于50μm的夹杂物提取效果与常用的水淘洗法基本一致,而对粒径小于50μm的夹杂物提取效果显著提升。     

电弧喷涂碳纤维增强铝基耐蚀减磨复合涂层研究

目的 制备耐蚀减磨性能优异的碳纤维增强铝基复合涂层。方法 利用粉芯丝材技术制备碳纤维增强铝基复合粉芯丝材,再利用电弧喷涂技术将制备的复合粉芯丝材制备成复合涂层。对铝基涂层使用SEM、XRD进行微观形貌、物化性能检测,使用摩擦磨损试验机、电化学工作站、中性盐雾试验机等对涂层的摩擦学、耐腐蚀性能等进行检测,综合评价在涂层体系中添加碳纤维对铝基涂层性能的影响。结果 添加碳纤维的铝基复合涂层相较于纯Al涂层,其摩擦学性能得到显著提升,摩擦系数由纯Al涂层的~0.4下降至~0.2,磨损率由纯Al涂层的~2.0×10^–3 mm³/(N.m)下降至~8×10^–4 mm³/(N.m),相关指标均下降了50%以上。同时,利用扫描电子显微镜观察涂层表面的磨痕及对磨副的划痕,并分析了铝基涂层的磨损机理,结果表明,Al/CFs复合涂层主要以磨粒磨损为主导机制,而纯Al涂层则以粘着磨损为主导机制。通过电化学工作站测试涂层的动电位极化曲线和Bode曲线分析涂层发生腐蚀的趋势,其电化学结果表明,添加碳纤维后不显著影响铝基涂层的耐腐蚀性能。进一步中性盐雾试验结果表明,中性盐雾试验720 h后,铝基涂层均未出现明显的腐蚀产物,涂层展现了优异的耐腐蚀性能。结论 利用粉芯丝材技术和电弧喷涂技术可以制备碳纤维增强铝基复合粉芯丝材及其涂层,在不影响原有铝涂层耐腐蚀性能的前提下,添加碳纤维可显著降低复合涂层的摩擦系数和磨损率,使涂层具有耐蚀减磨性能,可拓展铝基涂层在耐蚀减磨领域中的应用。     

粉末粒度对碳/碳基体上羟基磷灰石涂层的影响

采用等离子喷涂技术在碳纤维增强碳复合材料(简称碳／碳复合材料)上制备了羟基磷灰石涂层,研究了原始粉末粒度对涂层的表面形貌、剪切强度、相组成等方面的影响,并分析了涂层与基体的界面结合状况。结果表明：采用粗粉末喷涂后得到的涂层结合强度较高．结晶程度也较高,但涂层与基体的结合机制仍为机械嵌合。     

深井、超深井套管磨损监测方法研究及应用

介绍了井口磨屑分析法和工具接头磨损检测法的理论依据。为了对深井、超深井中的套管磨损行为作出确切的描述，将井口磨屑分析法和工具接头磨损检测法2种方法结合起来应用到钻井现场的套管磨损监测中，结果表明，此方法能相对准确地反应井下套管的磨损状况，可以及时地掌握套管的磨损变化信息，确定套管的磨损机制，从而为钻井现场开展套管磨损状态监测提供了一条切实可行的技术路线。     

无铅焊锡微粉雾化量与性能的关系

对自行设计的超音速雾化实验制粉设备，进行了不同雾化合金质量的生产效率及不同雾化量的宏观形貌研究。结果表明，雾化设备的最大雾化合金质量为400g；大、小批量雾化的粉末在宏观方面几乎无差别。找出了无铅焊锡微粉工业生产设备要满足的基本条件。     

WC-12Ni/NiCrBSi爆炸喷涂涂层制备及其滑动磨损特性

利用爆炸喷涂方法制备了不同比例的WC-12Ni/NiCrBSi涂层,研究了NiCrBSi含量对涂层的组织形貌、硬度与结合强度的影响,用扫描电镜和能谱仪分析了涂层的滑动磨损行为.结果表明:由于NiCrBSi的加入,改善了WC颗粒的熔融状态,提高了涂层的结合力,涂层中含15%的NiCrBSi时,可以明显的提高涂层的磨损抗力.     

粒状氮化镓微晶的合成及其结构性能的研究

在950℃的氮化温度下,通过单氢氧化镓（GaO2H）粉末与流动的NH3反应35 min制备出粒状GaN微晶.通过X射线衍射（XRD）和扫描电镜（SEM）研究发现,GaN粉末是六角纤锌矿结构的粒状微晶,其晶格常数a和c分别为0.3191 nm和0.5192 nm.X射线光电子能谱（XPS）揭示试样中有Ga-N键形成,Ga与N两元素比为1∶1.