Effect of temperature on methyl radical generation over Sr/La2O3 catalysts

The role of gas phase CH₃ radicals in the oxidative coupling of CH₄ over 1 wt% Sr/La₂O₃ is supported by the observations that (i) this is a very effective catalyst for the generation of CH₃ · radicals and (ii) the concentration of CH₃ · radicals increases with temperature over the range of 450 °C–800 °C.     

轧后穿水冷却工艺对棒材组织性能的影响

针对轧机产量提高后冷床冷却能力不足的问题 ,研制开发了棒材轧后穿水冷却技术。通过对小规格 2 0MnSiV热轧带肋钢筋进行轧后穿水冷却 ,钢材上冷床温度降低了 90～ 110℃ ,提高了产品质量 ,改善了各项力学性能 ,抗拉强度平均提高了 3 5～ 40MPa ,钢材性能合格率由 97.5 %提高到了 99.6% ,解决了冷床冷却能力不足、制约生产的瓶颈问题。     

浆砌石衬砌在渠道防渗中的应用及对策

总结了浆砌石应用的历史,介绍了浆砌石的结构特性和施工工艺,从造价方面、防渗效果及施工三方面分析了浆砌石衬砌主要存在的问题,并提出了相应的解决对策,指出浆砌石衬砌在渠道防渗应用中应控制施工质量,从而更好地提高防渗效果。     

气体悬浮焙烧炉内衬烘炉曲线的确定

根据所使用的低水泥浇注料的性能，对中铝山西分公司检修厂4号焙烧炉制定了合理的烘烤曲线，提高了耐火内衬的质量，延长了内衬的使用寿命。     

钢纤维聚合物混凝土抗压本构关系

钢纤维聚合物混凝土是由聚合物混凝土基体和钢纤维共同组成的纤维增强复合材料，它的力学行为不仅依赖于聚合物混凝土基体的行为，而且与钢纤维的掺量、分散特征以及钢纤维的几何尺寸有关，本文将基于损伤力学原理研究在不同纤维掺量下的钢纤维聚合物混凝土的全程压力-应变曲线及其本构模型。     

A new method for the determination of wax precipitation from non-diluted crude oils by fractional precipitation

Wax precipitation is one of the most important flow assurance problems. Unfortunately, experimental data are very scarce to confirm existing models for prediction of such precipitation problem. This work reports a new experimental method. Multistage fractional wax precipitation was carried out by decreasing the temperature of crude oil. No solvent dilution was used, so the effect of solvent on temperature wax precipitation was avoided. The reproducibility of the method was tested with comparable results. The precipitation curve and the wax appearance temperature were obtained for two crude oils with different chemical nature using the reported method.     

Microstructural investigation of long-term degradation mechanisms in GFRP dowel bars for jointed concrete pavement

Steel dowel bar is used to transfer loads in concrete pavement slab. However, once the steel dowel bar corrodes, it may cause faults, such as joint freezing in concrete pavement, level differences resulting from spalling or decreased efficiency of load transfer, etc., which are the same problems experienced by typical reinforcing steel. This study evaluated the applicability of glass fiber-reinforced polymer (GFRP) dowel bar as a substitute for steel dowel bar. A microstructural analysis was conducted to examine the decrease in durability of GFRP dowel bar exposed to deterioration environments. To analyze the deterioration mechanism of GFRP dowel bar, scanning electron microscopy was employed and the porosity was measured by the gas absorption method. It was concluded that the longer the GFRP dowel bar was exposed to deterioration environments, the more the interlaminar shear stress decreased. This result was validated by the microstructural analysis. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Effect of high temperature alkali cooking on the constituents,structure and thermal degradation of hemp fiber

Degumming of hemp fiber by high temperature alkali cooking was investigated, and the effect of temperature and dosage of alkali on the constituents, structure, and thermal degradation of hemp fiber was also discussed in this work. The morphology, structure, and thermal degradation of hemp fiber after high temperature cooking were investigated through SEM, FTIR, WAXD, and TG analysis. The results indicated that the high temperature cooking process was effective for removing hemicelluloses and lignin and could also improve the thermal stability of cellulose. Crystallinity index of the treated hemp fiber was increased, which was related to the cooking temperature and NaOH dosage. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Functional copolymer of geraniol and acrylonitrile: Synthesis and characterization

The radical copolymerization of acyclic terpene namely geraniol [GER] with acrylonitrile [AN] in DMF at (70 ± 0.1)°C for 1 h, using benzoylperoxide (BPO) as an initiator has been carried out under inert atmosphere of nitrogen. The kinetic expression for reaction is R_p ∝ [BPO]^0.5 [AN]^1.0 [GER]^1.0. The IR spectrum of the copolymer shows bands at 3432 and at 2244 cm^?1 due to ? OH group of GER and ? CN group of AN, respectively. The ¹³C‐NMR spectrum shows peaks at 73–75 δ ppm and 116–120 δ ppm due to ? OH group of GER and ? CN group of AN, respectively. The thermogravimetric analysis and differential scanning calorimetry study shows that copolymer is thermally stable up to 407°C and has glass transition temperatures (T_g) 56°C. The reactivity ratios r₁ (AN) and r₂ (GER) have been calculated as 0.05 and 0.005, respectively. The Alfrey‐Price Q‐e parameter for GER has been calculated as 0.094 and ?2.0, respectively. The molecular weights of the copolymers have been evaluated by gel‐permeation chromatography. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

转炉脱磷效果影响因素分析

从氧气顶吹转炉脱磷的热力学分析入手,探讨了冶炼过程中温度、炉渣碱度、(FeO)对磷含量的影响,回磷的原因、影响因素及防止措施等,指出应控制炉渣碱度、终点温度、(FeO)在合理范围内,应重视钢水回磷问题。