浇注型耐热聚氨酯树脂材料的合成及性能

以二异氰酸酯(4,4’-二苯甲烷二异氰酸酯MDI;4,4’-二环己基甲烷二异氰酸酯Hl2MDI),聚醚多元醇(PPG),小分子交联扩链剂,催化剂及助剂合成了一系列耐热聚氨酯树脂材料。用FT-IR表征了结构,用X射线衍射分析了微观结构,用DSC,TGA对其热稳定性进行了分析测试,对力学性能也进行了测试。结果表明,合成的聚氨酯材料具有高耐热性和卓越的力学性能。     

超声波检测过程的曲面重建技术

为了提高超声波检测技术的自动化程度和精度,在针对大型曲面结构的自动化超声检测过程中,采用二次建模方法进行曲面重建,即基于边界线和特征线的初始曲面建模方法与基于扫描线的网格划分曲面重建方法,并对此方法进行了计算机仿真与试验。     

电锤钻头冷挤压工艺及模具设计

叙述了电锤钻头用冷挤压工艺代替传统的金属切削加工方法的优点,并对电锤钻头进行了工艺分析。介绍了电锤钻头冷挤压工艺及模具设计。     

光面爆破在卡鲁玛尾水隧洞开挖中的改进与应用

在乌干达卡鲁玛尾水隧洞8#支洞Ⅲ类围岩开挖中,为了解决光面爆破施工中用的25mm细药卷短缺、绑扎光面爆破药串用的竹片无法买到等问题,采用了经过加工的32mm常规药卷,调整了光面爆破孔内装药结构和装药方法,并在选用常规周边光面爆破孔孔距条件下,适当减小光面爆破层厚度,将周边光面爆破孔密集系数提高到1.25~1.43。爆破实践表明:通过一系列改进,即便在只有最常见的32mm常规药卷和导爆索条件下,仍能取得良好的光面爆破效果。这一改进简化了光面爆破药串加工工序,减少了光面爆破层脱落需要克服的阻力,减轻了爆破对洞周被保留岩体的伤害。     

燃气开环磁流体发电机的研制

介绍了磁流体发电的原理,设计制造了燃气开环磁流体发电机的实验样机。阐述了实验样机的结构和功能,总结了样机设计的要点。     

Verrucosidin Derivatives from the Deep Sea Cold-Seep-Derived Fungus Penicillium polonicum CS-252

Six novel verrucosidin derivatives, namely, poloncosidins A–F (1–6), together with one known analogue (7), were isolated and identified from the deep-sea-derived fungus Penicillium polonicum CS-252, which was obtained from cold-seep sediments collected in the South China Sea at a depth of 1183 m. Their structures were mainly established on the basis of a detailed interpretation of NMR spectroscopic and mass spectrometric data. The relative and absolute configurations of compounds 1–6 were determined by ECD calculations and a DP4+ probability analysis. Compounds 1–5 represent the first examples of verrucosidins with a 2,5-dihydrofuran ring which is uncommon among the known analogues. These compounds exhibited inhibitory activities against several human and aquatic pathogens with MIC values ranging from 4 to 32 μg/mL.     

On the use of mesophase pitch for the preparation of hierarchical porous carbon monoliths by nanocasting

Abstract

A detailed study is given on the synthesis of a hierarchical porous carbon, possessing both meso- and macropores, using a mesophase pitch (MP) as the carbon precursor. This carbon material is prepared by the nanocasting approach involving the replication of a porous silica monolith (hard templating). While this carbon material has already been tested in energy storage applications, various detailed aspects of its formation and structure are addressed in this study. Scanning electron microscopy (SEM), Hg porosimetry and N₂ physisorption are used to characterize the morphology and porosity of the carbon replica. A novel approach for the detailed analysis of wide-angle x-ray scattering (WAXS) from non-graphitic carbons is applied to quantitatively compare the graphene microstructures of carbons prepared using MP and furfuryl alcohol (FA). This WAXS analysis underlines the importance of the carbon precursor in the synthesis of templated porous carbon materials via the nanocasting route. Our study demonstrates that a mesophase pitch is a superior precursor whenever a high-purity, low-micropore-content and well-developed graphene structure is desired.     

Structural control of Fe-based alloys through diffusional solid/solid phase transformations in a high magnetic field

Abstract

A magnetic field has a remarkable influence on solid/solid phase transformations and it can be used to control the structure and function of materials during phase transformations. The effects of magnetic fields on diffusional solid/solid phase transformations, mainly from austenite to ferrite, in Fe-based alloys are reviewed. The effects of magnetic fields on the transformation temperature and phase diagram are explained thermodynamically, and the transformation behavior and transformed structures in magnetic fields are discussed.