Preparation and characterization of trilobal activated carbon fibers

The objective of this research was to evaluate the effectiveness of several different methods for controlling the pore size and pore size distribution in activated carbon fibers. Variables studied included fiber shape, activation time, and the addition of small amounts of silver nitrate. Pure isotropic pitch and the same isotropic pitch containing 1 wt.% silver were melt spun to form fibers with round and trilobal cross sections. These fibers were then stabilized, carbonized, and activated in carbon dioxide. Field emission scanning electron microscopy (FE SEM), electron dispersive spectra (EDS), and wavelength dispersive spectra (WDS) were used to monitor the size and distribution of the silver particles in the fibers before and after activation. Each of these analyses showed that the distribution of silver particles was extremely uniform before and after activation. The fibers were also weighed before and after activation to determine the percent burn-off. The BET specific surface areas of the activated fibers were determined from N₂ adsorption isotherms measured at −196 °C. The results showed that round and trilobal fibers with equivalent cross-sectional areas yielded similar burn-off values and specific surface areas after activation. Also, activation rates were found to be independent of CO₂ flow rate. The porosity of the activated fibers depended on the total time of activation and the cross-sectional area of fibers. The N₂ adsorption measurements showed that the activated fibers had extremely high specific surface areas (greater than 3000 m²/g) and high degrees of meso- and macro-porosity. FE SEM was also used to investigate surface texture and size of pore openings on the surfaces of the activated fibers. The photos showed that silver particles generated surface macro- and mesopores, in agreement with the inferences from N₂ adsorption measurements.     

Preparation and characterization of antibacterial silver-dispersed activated carbon aerogels

Silver-dispersed carbon aerogels (CAs) were obtained by direct immersion of organic aerogels prepared by ambient pressure drying technique in AgNO₃ aqueous solution and then carbonization. The effect of preparation conditions such as the resorcinol/catalyst ratio, the feed AgNO₃ concentration, the ratio of aerogel mass/solution volume, immersion time and carbonization temperature on the bulk density and silver content as well as the BET surface area of the dispersed CAs was studied. The dispersion and structure of silver nanoparticles in obtained materials were investigated by means of scanning electron microscopy, transmission electron microscopy and X-ray diffraction. The Ag-dispersed CAs prepared exhibit strong and long-term antibacterial activity.     

无线传感网中基于成对节点探测不确定性的目标容错跟踪方法

针对无线传感器网络(Wireless Sensor Networks,WSN)中的节点在真实环境中的不可靠感知现象及其对目标跟踪精度的影响,首先分析计算了成对传感器节点感知存在的不确定区域及其边界,在此基础上,提出了一种基于成对节点探测不确定性的目标容错跟踪方法(Tracking with Pairwise Uncertainty of RSSI,TPU-RSSI),即通过匹配分组感知采样得到的感知向量(sampling vector)和跟踪区域划分面(face)的特征向量(signature vector)来进行移动目标容错跟踪。该方法在保持跟踪方法灵活性的基础上,能够减小由环境因素带来的跟踪误差。为了降低计算复杂度,提出了一种基于邻居面连接的启发式匹配算法。大量的仿真实验结果均表明,所提方法相比同类的其他方法具有更强的灵活性和更高的定位精度。     

沉淀法白炭黑化学指标与胶料物理性能的关系

分析了沉淀法白炭黑BET，CTAB，Ssears比表面，DBP吸油值，平均粒径与粒径分布对胶料物理性能的影响。得出结论：满足轮胎综合力学性能的沉淀法白炭黑应为低BET比表面积，低BET与CTAB比，高BET与Ssears比，适中的DBP吸油值，中值粒径小且易崩解的产品。     

多壁纳米碳管的超声短切处理

采用超声方法对多壁纳米碳管进行短切处理，比较系统地考察了超声时间对纳米碳管的长度、孔结构和形貌的影响。结果表明，超声粉碎可以有效地短切多壁纳米碳管，随超声时间的延长，纳米碳管的长度显著减小。在超声处理120min后，纳米碳管被短切到平均长度为400nm。超声短切后的纳米碳管比表面积和孔容均显著增加。进一步延长超声时间，其比表面积和孔容反而下降。     

居住区儿童户外游戏场地的安全性研究

游戏是儿童的天性,是儿童接触自然、提高创造力的有效途径。本文通过总结目前我国居住区儿童游戏场地中存在的一些安全问题,提出了加强居住区儿童游戏场地安全性设计的措施与方法。旨在探索出提高居住区儿童户外游戏场地安全性的有效途径。     

基于MEMS三轴加速度传感器的摔倒检测

摔倒作为人体活动的一部分,是影响人体健康的一大因素,尤其对病人和老年人而言,摔倒检测至关重要。基于MEMS三轴加速度传感器采集的人体活动加速度信号,提出了一种基于固定阈值的信号幅度向量滑动平均法SVMSA。该方法根据人体活动时的加速度信号特征,利用预先设定的阈值对加速度信号幅度向量SVM的滑动平均SVMSA进行判决,同时使用差分信号幅度域DSMA区分快速跑步等剧烈运动,准确实现了人体的摔倒检测。主要优势在于分析并区别了人体快速跑步等剧烈运动对摔倒检测的影响。通过对8位实验者的测试,该算法实现了94.4%的精确度。实验表明该算法能够较为准确地实现人体的摔倒检测。     

动态传感器网络区域受限的移动sink路径选择研究

针对sink区域受限及节点特征参数的问题,如何规划sink路径选择以满足动态传感器网络高效数据收集及低能耗的要求,提出了一种动态传感器网络区域受限的移动sink路径选择方法。该方法在缓存节点辅助通信模式下,建立sink受限区域图模型。针对不同应用情况,分别讨论了sink移动全局路径信息已知和sink移动局部路径信息已知这两种情况下的最优移动路径。在全局路径信息已知时,采用Vornon单元划分的思想求解总传输能耗和节点平均负载;在局部路径信息已知时,采用启发式策略进行路径寻优,并证明其路径寻优的正确性。最后通过仿真实验与理论计算来验证移动sink最佳路径寻优策略的有效性和可行性。     

烧碱蒸发装置的改进

通过改进工艺流程，科学确定加热面积的配比，合理选择采盐泵等技术改进措施，提高了生产强度，满足了高气压的生产条件，延长了洗效周期，减少了设备的腐蚀，提高了成品碱的质量，满足了生产联二脲的要求并降低了汽耗和电耗，年可节约ll0万元。     

Molecular simulation of hydrogen adsorption in organic zeolite

The adsorption of molecular hydrogen on model zeolites has been simulated employing Grand Canonical Monte Carlo (GCMC) procedure. The effects of cation type, available volume, surface area, temperature, pressure and pre-adsorbed organics such as benzene on the hydrogen uptake are analyzed. The hydrogen adsorption can be affected mainly by the available volume and surface area per g-zeolite at the same temperature and pressure. Increase of temperature results in the decrease of sorption intensity and capacity. The adsorption capacity correlates well with the pressure with high linearity at room temperature. Adsorption is lowered by the pre-adsorbed benzene molecule. The orientation and the number of benzene molecule in zeolite affect the adsorption capacity. The organic zeolite with larger available volume shows larger adsorption capacity.