Two‐phase production of cyclohexene and cyclooctene oxides in water as an approach to pollution prevention

Liquid–liquid two‐phase epoxidation from cyclohexene and cyclooctene in aqueous potassium peroxymonosulfate (commercially available as Oxone^®) solution was studied as an application in pollution prevention. To avoid potential emissions of volatile organic compounds an aqueous solution was employed to replace the usual chlorinated solvents used in epoxide production. A droplet column reactor and stirred tank reactor were used to investigate two‐phase synthesis of epoxide. An aqueous Oxone^® solution was used to oxidize a dispersion of alkene droplets and form epoxide. The study of aqueous epoxidation in both reactors showed that the epoxidation of alkenes can be represented as a first order reaction with respect to alkene. The salting out effect of Oxone^® concentration was studied in both reactors and found to be very similar at optimal conditions. In comparing the two reactors, it was found that the droplet column reactor produces larger quantities of product per unit reactor volume for the same reaction time. The objective of this study is to provide an alternative reactor design and synthesis route that can meet pollution prevention goals. Copyright © 2004 Society of Chemical Industry     

Particle Penetration through Inclined and L-Shaped Cracks

This paper presents a particle penetration model predicting particle penetration coefficient (Pp) through a narrow crack of arbitrary incline angles (θ). The objective was to simulate Pp for outdoor-to-indoor particle penetration for residential infiltration conditions. This model assumes laminar infiltration flow and considers particle deposition from both gravitational sedimentation and Brownian diffusion. For micron-sized particles, modeling results indicate that gravitational sedimentation is the major deposition mechanism. Pp increases monotonically with ∣θ∣ because effective particle sedimentation velocity (vs?cos?θ) decreases monotonically with ∣θ∣. For submicron-sized particles (0.1?μm), Brownian diffusion is the major particle deposition mechanism. Because Brownian diffusion is a nondirectional deposition mechanism, crack inclination did not affect Pp. This study applied this model to estimate Pp for L-shaped cracks, and validated modeling results with experiments. Experimental results indicated that inertial impaction and crack entrance cutoff effects were not significant particle deposition mechanisms for the test micron-sized particles. Gravitational sedimentation was the major deposition mechanism. An L-shaped crack can be simulated as the combination of horizontal and vertical sections. This model agreed reasonably with experimental results.     

土壤中石油污染物微生物降解及其降解去向

通过多因素对比预实验，将筛选出的7个石油烃降解的主要影响因素以正交表方法组合起来，对其进行了实验研究。探讨了石油迁移转化对于各种土壤物理化学条件及其他环境因素改变的敏感程度，并找出了各主要影响因素的重要性和最佳水平；测定了土壤中所存在的石油污染物在生物降解作用下的后期产物，研究了不同条件下的样品残留污染物组分之间的差异。影响土壤中石油烃类降解的主要因素有土壤石油污染强度、营养物(NH4NO3、K2HPO4)、氧化剂(3%H2O2溶液)、表面活性剂(TW80)、温度、土壤含水率和土壤透气性；在降解的不同阶段，各个因素的重要性以及最佳水平会发生相应的变化；在生物降解后期，土壤中残留的石油污染物主要是正构和异构烷烃；正构烷烃的色谱图由原来的对称钟形变为左陡右缓的偏钟形；异构烷烃所占比重增大，正十五烷和正二十一烷之间的谱图基线被明显抬高。     

井冈山水厂设计体会

阐述水厂设计中对水厂规模、水源地、净水厂位置及净水工艺的确定过程，根据原水的特点，通过分析对无阀滤池进行改良。     

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川东北海相碳酸盐岩所生成的天然气主要聚集在喜山期形成的构造圈闭中。本文针对此特点,划分了背斜圈闭的成因类型,建立了海相碳酸盐岩孔隙、裂缝复合型背斜气藏模式,并指出了当前勘探的三大领域及寻找富集型气藏的前景。     

激光热源形成过程的定量描述

研究了热传导方程的通解，进而提出激光热源形成的微观机理和热源形成过程的三个理论计算式。对激光热效应的应用具有指导意义。     

一种辐射源距离的估算方法

提出利用测量设备与辐射源相对运动速度及测量设备所接收到的辐射功率的估算测量设备到辐射源距离的一种方法。对计算精度进行了分析，通过算例对理论分析进行了检验。     

绿色包装材料——生物降解塑料

对绿色包装材料-生物降解塑料的降解机理、特点，国内外研究现状和进展及存在的问题和发展前景进行了介绍。     

鄂尔多斯盆地含油气系统

鄂尔多斯盆地含油气系统研究目前尚无成熟的划分方案和系统成果,本文主要依据油气赋存的层位并参考油气源将其划分为下古生界含气系统、上古生界含气系统及中生界含油气系统。各含油(气)系统平面分布范围主要受生油岩、储集岩分布和油气运移方向的控制;其中,下古生界含气系统、中生界含油气系统主要分布于盆地中部。上古生界含气系统主要分布于盆地北部。     

Waves generated by a source below a free surface in water of finite depth

The free-surface flow due to a submerged source in water of finite depth is considered. The fluid is assumed to be inviscid and incompressible. The problem is solved numerically by using a boundary integral equation formulation due to Hocking and Forbes [6]. The numerical results show that there is a train of waves on the free surface in accordance with the results of Mekias and Vanden-Broeck [5]. For small values of the Froude number, the amplitude of the waves is so small that the free surface is essentially flat in the far field. These waveless profiles agree with the calculations of Hocking and Forbes [6].