NNI-1型C_5/C_6烷烃异构化催化剂长周期运行分析及建议

中国石化海南炼油化工有限公司0.2 Mt/a C5/C6烷烃异构化装置以连续重整装置的拔头油为原料,使用NNI-1催化剂,采用一次通过流程,不设脱异戊烷塔和稳定塔,经设在连续重整装置内的脱丁烷塔稳定处理后作为汽油调合组分。该装置于2006年9月开工投产,截至2015年3月已连续运行3个周期。长周期运行分析结果表明:前两个周期中NNI-1催化剂具有较高的异构化活性及选择性,C5异构化率为60%左右,C6异构化率为80%左右,C6选择性为15%左右,产品辛烷值基本达到技术指标要求(RON≥78);而在第三周期运行中,催化剂积炭增加等原因导致其异构化活性及选择性降低,异构化产品辛烷值提升能力呈现逐步衰减的趋势,提高反应苛刻度已不能弥补催化剂活性下降造成的产品辛烷值降低。为保证装置长周期运行,建议择机停工对催化剂进行再生,或是直接换用与装置原料性质匹配的异构化催化剂。     

Learning keyword phrases from query logs of USPTO patent examiners for automatic query scope limitation in patent searching

Professional search in patent repositories poses several unique challenges. One key requirement is to search the entire affected space of concepts, following well-defined procedures to ensure traceability of results obtained. Several techniques have been introduced to enhance query generation, preferably via automated query term expansion, to improve retrieval effectiveness. Currently, these approaches are mostly limited to computing additional query terms from patent documents based on statistical measures. For conceptual search to solve the limitation of traditional keyword search standard dictionaries are used to provide synonyms and keyword phrases for query refinement. Studies show that these are insufficient in such highly specialized domains. In this paper, we present an approach to extract keyword phrases from query logs created during the validation procedure of the patent applications. This creates valuable domain-specific lexical databases for several specific patent classes that can be used to both expand as well as limit the scope of a patent search. This provides a more powerful means to guide a professional searcher through the search process. We evaluate the lexical databases based on real query sessions of patent examiners.     

Scheduling Algorithms for Packet-Oriented MAC Protocols in Wireless Multimedia Systems

Future generation wireless multimediacommunications will require efficient Medium AccessControl (MAC) protocols able to guarantee suitable Qualityof Service (QoS) levels for different traffic classes whileachieving a high utilization of radio resources. This paperproposes a new scheduling technique to be adopted at the MAClevel in wireless access systems, named Dynamic Scheduling-Time DivisionDuplexing (DS-TDD), that efficiently managesvideo, voice, Web and background traffics. A theoretical approachis proposed in this paper to evaluate the DS-TDD performance withvoice and Web traffics. Simulation results have permitted tohighlight the following promising characteristics of the DS-TDDscheme: (i) a high capacity of real-time traffics isattained with a QoS insensitive to Web and background trafficloads; (ii) a high throughput can be guaranteed whilepreserving the QoS levels of the different traffic classes;(iii) heavier downlink traffic loads do not modify the QoSof uplink traffics. Finally, extensive comparisons with differentscheduling schemes proposed in the literature have permitted tohighlight the better performanceof DS-TDD.     

企业中层管理人员培训的思考

以分析企业中层管理人员培训的现状为突破口,阐述了中层管理人员培训需求分析的思路和方法。在此基础上对培训内容进行整体设计,指出针对此类培训应采用的培训方式和评估方法。以期对企业中层管理人员的培训起到一些启发和借鉴作用。     

锅炉对流管爆裂原因分析

采用化学分析、金相检验及力学性能测定等方法，对锅炉对流管爆裂原因进行了分析。结果表明，长期超温运行而引起的蠕变是导致爆裂的主要原因。     

非关联双模场对Kerr介质中电子绝热跃迁转移现象的影响

本文研究了充满Kerr介质的高Q腔中非关联双模相干态场与级联三能级原子非共振相互作用情况下,电子的绝热跃迁转移现象与非关联场之间的关系。数值计算显示:级联三能级原子在与非关联双模相干态的相互作用下,该现象依然存在,但呈现不同于原子与关联场相互作用的新特征。     

高温预析出对Al-Zn-Mg系铝合金时效硬化和应力腐蚀的影响

研究了高温固溶后降温处理工艺对中强可使预析出LC52和7039铝合金的组织、时效硬化和应力腐蚀的影响。金相观察发现,高温预析出可优先在晶界处产生,并提高随后时效状态下晶界析出相的不连续分布程度,温度降低到一定程度晶内和晶界产生大量析出。合金拉伸性能和应力腐蚀结果表明,预析出在保持强度和塑性的同时,可提高抗应力腐蚀性能。而预析出温度降低,合金强度呈下降趋势。     

Analysis of Multiphase Flow and Heat Transfer: Pressure Buildup in an Unsaturated Porous Slab Exposed to Hot Gas

This study develops a mathematical model for coupled heat and mass transfer in an unsaturated porous slab exposed to a flowing hot gas. Effects of the initial saturation conditions on associated variables, i.e., total pressure, temperature, moisture content, and multiphase flow, are studied. The Newton-Raphson method based on a finite volume technique is applied. This study emphasizes the influence of initial saturation level and gravitational effect in heat and multiphase flow phenomena associated with this system. Gravity enhances the downward flow of liquid within the porous slab. Pressure buildup occurs near the interface between the wet and the dry zone. However, it appears that the order of magnitude to the total pressure is small. This study explains the fundamental mechanism of multiphase flow that involves heat and mass transfer in a heated unsaturated porous slab.     

平差法预计矿区导线网精度

分析了矿区导线网精度预计经典方法存在的问题 ,推导出严密平差法精度预计的数学模型 ,并编制机算程序。