全球移动增值业务发展现状

移动增值业务在全球的发展速度依然很快,非话音收入占电信总收入的比重越来越大.在移动增值业务的发展上,日本遥遥领先,韩国紧随其后.在中国,虽然短信业务收入开始下降,但无线应用协议(WAP)、交互式语音回应(lVR)等业务收入快速攀升,从而保证了移动增值业务在中国的发展速度.由于中国信息产业部整顿收费混乱的移动增值业务市场,使服务提供商/内容提供商(SP/CP)的暴利时代成为过去,增值业务市场进入精耕细作期.随着用户对移动增值业务新的需求的不断增长,整首音乐下载、移动E-mail以及手机电视等业务将成为未来全球最有前途的移动增值业务.     

电容传感器在使用中存在的几个问题及处理方法

随着电容测量技术的迅速发展，电容传感器在非电量测量和自动检测中得到广泛应用，但它在使用过程中也存在一些问题，针对在使用电容传感器过程中存在的几个问题，从电容传感器的原理和工作过程两个方面进行了讨论，并提出行之有效的处理方法。     

大坝安全信息权研究

大坝原型观测数据本身包含了丰富的信息，内在反映了监测项目之间的某种客观关系，基于此，应用PCA法及PPA法建立了确定大坝安全评价信息权重的正分析模型，一方面能够对数据进行降维处理，另一方面能挖掘数据内在信息，提取指标的相对重要性；并基于最优化准则，建立了信息赋权整合模型，解决了多种数学方法计算结果不一致性问题，最大限度地保持原始信息的完整性。     

黄河下游河道萎缩致灾机理探讨

本文基于水力学原理，结合实体模型试验及原型实测资料分析，探讨了黄河下游河道萎缩的概念、致灾效应和致灾机理。分析表明，河道萎缩是造床过程中河道排洪输沙功能衰退的一种演变现象，其致灾效应是使洪水涨率增大，同流量下洪水水位不断抬升。致灾的现象主要表现在畸型河势增加、工程险情增多、直接造成工程损失及滩区经济损失等。试验研究揭示，主河槽宽度缩窄造成洪水水位涨幅增大，河底平均高程抬升和过水断面面积减小造成洪水水位起涨的基准面抬升是河道萎缩致灾的主要原因。河道萎缩致灾效应的大小与萎缩模式有关，其中以“集中淤槽”模式所形成的致灾效应尤为明显。     

基于事例学习的建筑结构的虚拟实现

提出基于事例学习的目标规划问题,并进一步研究了建模思想的可行性和建模方法的可操作性。利用知识工程、机器学习理论,人工智能技术来存贮和运用专家的经验,实现了在虚拟环境中建筑结构设计、施工,设备的仿真试验,并可对初学者或尚无经验的设计、施工者进行培训学习。该项研究为目标规划问题开辟了基于事例学习的模型生成途径。     

Effect of ionic content,solid content,degree of neutralization,and chain extension on aqueous polyurethane dispersions prepared by prepolymer method

There are many variables in the preparation of aqueous polyurethane (PU) dispersions. Carboxylic acid content, solid content, degree of pre/postneutralization of the carboxylic acids, and chain extension all impact dispersion particle size, viscosity, pH, molecular weights, and glass transition temperature. This study evaluated the impact of these variables on a given PU dispersion formulation prepared from isophorone diisocyanate, an aliphatic polyester polyol, dimethylol propionic acid, and hexamethylene diamine with triethyl amine as the neutralizing base and N‐methyl pyrrolidone as the cosolvent. Changes in carboxylic acid content, degree of preneutralization, and chain extension were found to have the expected impacts on dispersions properties. Increased ionic content in the dispersion step led to lower particle size and higher viscosity, increased chain extension with its concurrent increase in molecular improved subsequent film properties. Surprising results were obtained by varying the amount of postneutralization and from increased solids content at the time of dispersion. Unexpectedly, both of these variations led to much higher dispersion viscosities and particle size in solution. To have these changes take place, it is theorized that there is a major change in solution morphology caused by these modifications. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 98: 2514–2520, 2005     

Assessing organo-clay dispersion in polymer layered silicate nanocomposites: A SAXS approach

A SAXS method for the quantitative assessment of the morphology of polymer layered silicate nanocomposites is proposed. Fitting the SAXS patterns, the number of clay layers, the periodicity of the layers in the tactoids, the thickness of the regions interposed between the clay platelets and their distributions can be measured. A good agreement with TEM data was obtained, avoiding the inconsistencies with microscopical observations often reported in the literature.     

Synthesis and characterization of a series of star-branched poly(ε-caprolactone)s with the variation in arm numbers and lengths

A series of star-branched poly(ε-caprolactone)s (SPCLs) was synthesized with structural variation of the arm numbers and lengths through ring-opening polymerization under bulk condition. Arm numbers were varied to be 3, 4, and 6 by using multifunctional initiating cores such as trimethylol propane, pentaerythritol, and dipentaerythritol, respectively. The lengths of the poly(ε-caprolactone) arms were varied by controlling the molar ratio of monomer-to-initiating hydroxyl group molar ratio ([CL]₀/[-OH]₀=5, 10, 15). Molecular weights were determined by both ¹H NMR end-group analysis and MALDI-TOF mass spectrometry, which gave reasonably consistent values. On the contrary, the GPC method failed to give accurate values of molecular weight of SPCLs due to the discrepancy with the linear standard. The branching architecture of SPCLs was evaluated by the branching ratio, g, which is the ratio of the mean-square radius of SPCL to that of liner counterpart, linear poly(ε-caprolactone) (LPCL), which is of the same chemistry and having the same molecular weight. The radii of gyration of SPCLs and LPCLs were determined using small-angle X-ray scattering (SAXS) from the initial slopes of Zimm plots, represented as 1/I(q) vs q² with I(q) and q being the scattered intensity and scattering vector, respectively. The g values were observed to decrease with increasing arm numbers, indicating more compact molecular structure for SPCLs with higher arm numbers, while no such effect was observed for arm length variation. Thermal properties as well as the degree of crystallinity of SPCLs were found to be also dependent on structural variations. The melting points and the degradation temperatures were observed to increase with increasing arm lengths but with constant arm number. On the other hand, arm number variation with constant arm length gave no such changes to the thermal transitions of SPCLs. However, for the SPCLs with equivalent molecular weights, the degree of crystallinity was found to decrease with increasing arm numbers.     

Potential tissue implants from the networks based on 1,5-dioxepan-2-one and ε-caprolactone

The synthesis and characterization of degradable polymeric networks for biomedical applications was performed. Cross-linked films of poly(ε-caprolactone) (PCL) and poly(1,5-dioxepan-2-one) (PDXO) having various mole fractions of monomers and different cross-link densities were successfully prepared using 2,2′-bis-(ε-caprolactone-4-yl) propane (BCP) as cross-linking agent. Reaction parameters were carefully examined to optimise the film-forming conditions. Networks obtained were elastomeric materials, easy to cast and remove from the mould. Effect of CL content and cross-link density on the final properties of the polymer network was evaluated. High CL content or degree of cross-linking led to increase in Young's modulus and decrease in elongation at break. An increase in crystalline domains in films having a higher CL content was observed by optical microscopy. A greater thermal stability was observed in films having a high CL content. The hydrophilicity of the materials could be tailored by changing the CL content. The surface of the films became rougher with higher CL content.     

Protein binding study of isoflavone, perillyl alcohol and S-ibuprofen by high-performance frontal analysis

High-performance frontal analysis (HPFA) was used for a protein binding study of isoflavones (daidzein, genistin, and genistein), enantiomers of perillyl alcohol and S-ibuprofen to human serum albumin (HSA). The analyses were performed on a Develosil and Inertsil 100-Diol-5 column (10 cm×4.6mm). Sodium phosphate solution (pH 7.4, ionic strength 0.17) was used as the mobile phase at a flow rate of 1 ml/min. To ensure the drug to be eluted as a trapezoidal peak with a plateau, injection volumes were each fixed up the zonal profile with an evident plateau appears. The unbound drug concentration was determined from a plateau height of the plateau region after that experimental data were fitted by Scatchard equation. The binding constants (K) and total binding affinities (nK) of drugs to HSA were calculated, respectively.