低温无铅乳浊玻璃釉性能研究

采用熔融法,选取Na2O-BaO-ZnO-B2O3-SiO2系低熔点玻璃为基釉,以TiO2为乳浊剂,通过乳浊剂不同的加入方式制备了低温无铅乳浊玻璃釉.通过X射线衍射、扫描电镜及EDS能谱分析,研究了TiO2的不同加法及TiO2同一含量不同釉烧温度下对釉面性能及釉的显微结构的影响,并对以TiO2作为乳浊剂的乳浊釉的乳浊机理进行探讨.结果表明:乳浊剂不同的加入方式、加入量不同,乳浊相的存在状态、乳浊机理、乳浊效果不同.当采用双加法(即熔加和磨加相结合)后,既有未熔、散布在基体中晶粒的,也有析出晶相并促使所存晶相发育良好相结合从而使釉面形成良好乳浊.在620℃釉烧温度下以熔加2%并磨加5.5%TiO2时,发现釉中晶体数量密集,尺寸与可见光相近,分散性高,使釉对光的折射和散射能力强,釉面乳白效果最好,白度可达到71.88.     

火焰化学气相沉积法制备多晶纳米二氧化钛及其在气体净化中的应用

综述了作者近年来在火焰化学气相沉积(CVD)法制备多晶纳米二氧化钛及其在光催化气体净化中应用的研究成果。总结了以工业丙烷为燃料、空气为催化剂、四氯化钛为先驱物的火焰CVD法制备多晶纳米二氧化钛中热负荷对燃烧室内的温度分布和金红石含量的影响。以光致发光(PL)光谱为表征手段,研究了金红石含量对光激电子和空穴的分离作用。用管式光催化反应系统,研究了初始浓度和相对湿度对多晶纳米二氧化钛光催化降解挥发性有机物(VOC)气体和氨气的影响,及最佳光催化效率的金红石含量。针对多晶纳米二氧化钛在低相对湿度下光催化降解效率低的缺陷,用复合法对其性能进行了改进,研究了改进的光催化剂在低相对湿度和干燥空气中光催化降解苯的效率。对500 m3/h模块化的填料式光催化气体净化设备进行了净化效率和催化剂寿命实验,讨论了光催化饱和浓度对净化设备设计的影响。     

碳氟表面活性剂FCI-3及其复配体系对碳钢表面的缓蚀性能

本文采用失重法,电化学交流阻抗法,极化曲线法和扫描电镜法等观察缓蚀剂在HCl介质中,FCI-3及普通碳氢表面活性剂（CTAB,SDS,TX-100）复配体系对Q235钢的缓蚀性能.结果表明,FCI-3对碳钢表面有较好的缓蚀性能,三种方法测试的结果均达到90％以上;三种普通碳氢表面活性剂分别与FCI-3复配后,发现三个体系仍有较好的缓蚀效果,缓蚀效率达到90％以上,缓蚀效率从高到低的顺序是CTAB＞ TX-100＞ SDS.     

Numerical Simulation and Analysis of Migration Law of Gas Mixture Using Carbon Dioxide as Cushion Gas in Underground Gas Storage Reservoir

One of the major technical challenges in using carbon dioxide（ CO2） as part of the cushion gas of the underground gas storage reservoir（ UGSR） is the mixture of CO2and natural gas. To decrease the mixing extent and manage the migration of the mixed zone,an understanding of the mechanism of CO2and natural gas mixing and the diffusion of the mixed gas in aquifer is necessary. In this paper,a numerical model based on the three dimensional gas-water two-phase flow theory and gas diffusion theory is developed to understand this mechanism. This model is validated by the actual operational data in Dazhangtuo UGSR in Tianjin City,China.Using the validated model,the mixed characteristic of CO2and natural gas and the migration mechanism of the mixed zone in an underground porous reservoir is further studied. Particularly,the impacts of the following factors on the migration mechanism are studied： the ratio of CO2injection,the reservoir porosity and the initial operating pressure. Based on the results,the optimal CO2injection ratio and an optimal control strategy to manage the migration of the mixed zone are obtained. These results provide technical guides for using CO2as cushion gas for UGSR in real projects.     

基于互联网的计算机网络实验体系的研究与实现

针对高校计算机网络实验开展所面临的问题,提出了基于互联网开展计算机网络实验的建议。分析了计算机网络实验所具有的特性,并指出了互联网化过程中相关软件系统应具备的基本功能,设计了远程实验管理平台的体系结构,开发了体系结构中各个不同的子系统,实现了计算机网络实验互联网化的目标,解决了高校计算机网络实验开展过程中存在学生感觉实验时间不足、实验室却长时间闲置的问题。     

高职院校二级分院用人机制改革探讨

高职院校用人机制改革是各项改革中的重中之重,也是高职院校改革是否成功的重要标志之一。实施用人机制的改革就是要搞活用人机制,加大二级分院用人的自主权,引进企业的优质资源,专任教师与兼职教师相结合,通过"混编师资团队"建设完善"双师结构"师资队伍建设,从而提高人才培养质量。     

Fabrication of Pebax/SAPO mixed matrix membranes for CO2/N2 separation

Mixed matrix membranes (MMMs) were prepared by solvent evaporation method using Pebax-1074 polymer as matrix and inorganic zeolite SAPO-23 as dopant. The morphology, surface functional groups, microstructure, thermal stability, and separation performance of MMMs were analyzed by scanning electron microscopy, Fourier transform infrared spectroscopy, X-ray diffraction, thermogravimetric analysis, and gas permeation, respectively. The effects of dopant loading amount, permeation temperature, and permeation pressure on the structure and properties of MMMs were investigated. The results showed that the introduction of SAPO zeolite reduced the crystallinity of the MMMs and improved the CO₂/N₂ selectivity. Under the conditions of 30°C and 0.15 MPa, the MMMs prepared by incorporating with 5% SAPO zeolite in content exhibited the highest CO₂/N₂ selectivity of 72.0 together with the CO₂ permeability of 98.2 Barrer.     

Crack growth angle prediction of an internal crack under mixed mode load for unfilled elastomer using the strain energy density factor

This article investigates the prediction of the crack growth angle of an existing internal crack under mixed mode loading at the crack tip for an unfilled ethylene propylene diene terpolymer rubber (EPDM). For the realization of mixed mode loading, the cracks of the uniaxial loaded specimens were oriented with different angles to the loading direction. The energy density factor was used as a potential criterion for determining the crack growth angle. The determination of the strain energy density factor was carried out simulatively in Abaqus. The second-order Ogden model was used to describe the rubber-like material behavior. The relative local minimum of the strain energy density factor provides the possible growth angle. The experimental investigations show that the initial cracks grow orthogonally to the loading direction for the different crack orientation angles. For the crack orientation angle parallel to the load direction, the crack growth was observed because the strong stretching of the specimen caused strong necking in the crack region. The crack growth for the remaining crack orientation angles were induced due to shear loading at the crack tip. The predictive angle of different crack orientation angles shows very good accordance to the measured crack growth angles.     

高电压磷酸钴锂正极材料性能调控研究

高性能、高安全储能电池的迫切需求加速了橄榄石型高电压正极材料的研究步伐。为了改善高电压磷酸钴锂(LiCoPO₄)的综合电化学性能,采用溶剂热法研究了溶剂比、过渡元素(Fe、Mn)单掺杂和双掺杂(掺杂元素总量占10%)对正极材料形貌、尺寸、反位缺陷和电化学性能的影响。结果表明,当溶剂比为2.3时,未掺杂LiCoPO₄在0.1C下表现出163.1 mAh·g^-1的最高理论比容量;双掺杂LiCo_0.9Mn_0.05Fe_0.05PO₄正极材料具有突出的循环性能,在0.5C电流密度下,循环100圈后的容量保持率为78.9%,循环稳定性得到明显改善。     

RuTiSnMn/Ti阳极的电化学性能

热分解制备了RuTiSnMn／Ti阳极，在4mA／cm^2的电流密度下进行了恒电流试验。通过循环伏安法和交流阻抗谱研究了阳极在35g／LNaCl溶液、20g／LNaOH溶液和模拟孔隙液中的电化学行为．利用EsEM对阳极失效前后的微观形貌进行了观察,结果表明：阳极具有优良的耐析氯、氧反应能力；钛基体逐渐形成TiO2的钝化膜使阳极的氧化物膜电阻增大，活性组元的消耗使法拉第电荷传递电阻增加，这两者最终导致阳极失效。