Review of the economic viability of investing and exploiting biogas electricity plant - Case study Vizelj, Serbia

Construction and operation of plants that produce energy from renewable energy sources is the subject for discussion in all the countries that have accepted the sustainable development concept and Kyoto protocol as their own development direction. Enlargement of the renewable energy production is clearly an imperative, but only economically viable construction and operation can result in long-term sustainability, which is initially the goal when deciding upon such investments. In line with this goal, this paper presents the estimation of the economic viability of constructing and operating biogas electricity plant on the farm Vizelj in Serbia. The timeframe for this estimation is from 2011 until 2020. This paper also presents all parameters which are necessary for performing this estimation, respectively, analysis of revenues and expenditures, projection of economic and financial flow, ratio analysis, dynamic and static analysis, and analysis of sensitivity of the project, i.e. impact of the changes in prices and raw material on the overall performance of the project. The observed investment is predicted to be financed from the EBRD's credit line for renewable energy in Western Balkans, while the total investment is estimated at Euro 958,000.00. After the performed economic assessment, the conclusion is that the observed investment in biogas electricity plant is very acceptable and it can serve as a role model for similar investments in the region.     

Variation in the volatile terpenoids of two industrially important basil (Ocimum basilicum L.) cultivars during plant ontogeny in two different cropping seasons from India

BACKGROUND: Two Ocimum basilicum cultivars, ‘Vikarsudha’ and ‘CIM‐Saumya’, grown in the Kumaon region of western Himalaya were evaluated for their essential oil yield and composition at different stages of plant growth during two distinct cropping seasons (spring–summer and rain–autumn). RESULTS: The highest yield of essential oil was obtained at full bloom stage in both cultivars in both cropping seasons. The essential oils obtained from different stages in two cropping seasons were analysed by capillary gas chromatography with flame ionisation detection, and gas chromatography–mass spectrometry. The major component of cultivar ‘Vikarsudha’ was methyl chavicol (84.3–94.3%), while for cultivar ‘CIM‐Saumya’ the main components were methyl chavicol (62.5–77.6%) and linalool (14.4–34.1%). CONCLUSION: This study clearly indicated that cultivar, cropping season, plant ontogeny and plant part had significant effects on the yield and quality of the essential oil of O. basilicum. Further, the amount of methyl chavicol in the cultivars grown in this region was higher than in cultivars from other parts of India. Copyright © 2011 Society of Chemical Industry     

Optimal conditions of isobutane dehydrogenation in radial flow moving bed hydrogen-permselective membrane reactors to enhance isobutene and hydrogen production

In the isobutane dehydrogenation process, coupling reaction and separation and optimization of the intensified process can improve the isobutane conversion and selectivity, reduce operational costs and lets to produce pure hydrogen. In this research, the radial flow moving bed reactors in the Olefex technology have been supported by Pd–Ag membrane plate to remove hydrogen from the reaction zone. The reactions occur in the tube side and the hydrogen is permeated from the reaction zone to the sweep gas stream. The proposed configuration has been modeled heterogeneously based on the mass and energy conservation laws considering reaction networks. To prove the accuracy of the considered model, the simulation results of the conventional process have been compared against available plant data. The Genetic algorithm as an effective method in the global optimization has been considered to optimize the operating condition of membrane reactors to enhance isobutene productivity. In this optimal configuration, the isobutene production has been enhanced about 3.7%.     

CO2汽提法尿素装置低压开车总结

介绍了CO2汽提法尿素装置低压开车的特点与优点,分析了低压开车法的可靠性,总结了低压开车法的操作要点,提出了推广普及低压开车法的建议.     

Chemically Synthesized 58‐mer LysM Domain Binds Lipochitin Oligosaccharide

Recognition of carbohydrates by proteins is a ubiquitous biochemical process. In legume–rhizobium symbiosis, lipochitin oligosaccharides, also referred to as nodulation (nod) factors, function as primary rhizobial signal molecules to trigger root nodule development. Perception of these signal molecules is receptor mediated, and nod factor receptor 5 (NFR5) from the model legume Lotus japonicus is predicted to contain three LysM domain binding sites. Here we studied the interactions between nod factor and each of the three NFR5 LysM domains, which were chemically synthesized. LysM domain variants (up to 58 amino acids) designed to optimize solubility were chemically assembled by solid‐phase peptide synthesis (SPPS) with microwave heating. Their interaction with nod factors and chitin oligosaccharides was studied by isothermal titration calorimetry and circular dichroism (CD) spectroscopy. LysM2 showed a change in folding upon nod factor binding, thus providing direct evidence that the LysM domain of NFR5 recognizes lipochitin oligosaccharides. These results clearly show that the L. japonicus LysM2 domain binds to the nod factor from Mesorhizobium loti, thereby causing a conformational change in the LysM2 domain. The preferential affinity for nod factors over chitin oligosaccharides was demonstrated by a newly developed glycan microarray. Besides the biological implications, our approach shows that carbohydrate binding to a small protein domain can be detected by CD spectroscopy.     

Formulation and characterisation of nanosuspension of herbal extracts for enhanced antiradical potential

Nanotechnology is a promising technique to increase the bioavailability of herbal medicines. This paper presents the nanosuspension approach for increasing the aqueous solubility and thereby bioactivity of important herbal extracts. Nanosuspensions of the seeds of three plants extract (Silybum marianum, Elettaria cardamomum and Coriandrum sativum) were prepared by using polyvinyl alcohol (1.5% w/v) as a stabiliser. Prepared nanoparticles were characterised by scanning electron microscope. Activity of nanosuspension formulation was assessed by using four in vitro antioxidant assays. S. marianum, E. cardamomum and C. sativum particle size was observed to fall in range of 446.1 ± 112.6, 456.63 ± 339.2 and 432.1 ± 172.8 nm, respectively, most of the particles were having spherical shape and smooth topology. These synthesised nanoparticles were found to be more effective against quenching free radical than their crude extracts and standards [butylated hydroxyl toluene and ascorbic acid]. C. sativum nanosuspension showed most free radical scavenging potential against 2,2-diphenyl-1-picrylhdrazyl (DPPH) and superoxide free radical scavenging assays (IC₅₀ 0.59 ± 0.01 and 0.81 ± 0.11 mg/ml). S. marianum nanosuspension was found to be most effective against DPPH radicals scavenging (IC₅₀ 0.34 ± 0.02 mg/ml). It was concluded that nanosuspension of herbal medicines potentiates the antioxidant potential.     

醋酸装置安装工程中锆管焊接工艺及应用研究

介绍了锆材Zr702焊接工艺评定试验及其在50万t/a醋酸装置安装工程中的应用,提出了焊接控制要点。工程实践表明,该工艺方案可行。     

气相流化床聚乙烯冷凝技术的应用与运行优化

介绍了气相流化床聚乙烯冷凝技术特点,分析了气相流化床聚乙烯冷凝模式操作参数的相互影响关系,提出了装置投料开车及冷凝模式下稳定运行的优化措施。运行结果表明,在冷凝操作模式下应确定各参数的安全操作范围,冷凝操作的进入或退出应尽快完成。装置开车阶段对原料和回收液(气)要预先取样分析合格,投催化剂后出现静电大幅波动应消除杂质来源再提负荷,进冷凝操作模式时原始种子床粉料应排出彻底,为防止反应器爆聚应提高对异常现象的判断及处置速度。装置运行阶段应强化原料质量和原料精制床精制效果的监控。     

Treatment of oilfield wastewater using algal–bacterial fluidized bed reactor

This study was carried out to investigate the ability of an artificial microalgal–bacterial consortium to remediate an oilfield wastewater using laboratory-scale fluidized bed reactors (FBRs) under lighting. The consortium consists of an oil-degrading bacterial community and a microalgae, Scenedesmus obliquus GH2. The microbes were immobilized onto Ca-alginate beads and filled to the FBRs. The influence of hydraulic retention time (HRT) on the removal of chemical oxygen demand (COD), total nitrogen, NH₃-N and oil concentration was investigated over 40 operational days. The synergistic relationship in the algal–bacterial microcosm was clearly demonstrated, since for the four parameters tested, the highest removal was recorded in the system inoculated with both algae and bacteria. In the algal–bacterial FBR, at 16 h HRT, the average effluent concentrations of COD, NH₃-N and oil were 92, 24 and 4.8 mg/L, respectively, corresponding to removal efficiencies of 70.8%, 61.2% and 84.2%, respectively. The effluent could meet the grade 2 as required by the national discharge standard of China. However, the effluent quality of the bacterial- or algal-only case could not satisfy the grade 3 discharge standard at 16 h HRT. The algal–bacterial biomass exhibits lowest effluent microtoxicity and highest dehydrogenase activity in comparison with bacterial-only and algal-only cases. This study reveals that the consortium containing dual microbial species has potential for microbial remediation of oilfield wastewater.     

Performance of the bearing reinforcement earth wall as a retaining structure in the Mae Moh mine,Thailand

In this research, a Bearing Reinforcement Earth (BRE) wall with a residual clay stone backfill was successfully implemented as an alternative truck ramp support for an on-site crusher plant in the Mae Moh mine, Thailand. The performance of the BRE wall during and after the end of construction as well as during the service state was evaluated in terms of, settlement, bearing stress, lateral movement, lateral earth pressure and tension force in the reinforcements. Bearing reinforcement is a cost-effective inextensible earth reinforcement, which is composed of a longitudinal member and transverse members. The maximum settlement at the end of construction (20 days) was about 5 mm. The installation of the truck ramp (10 days after the end of construction) resulted in an immediate settlement of about 2 mm. The final settlement due to the backfill, truck ramp and truck load after 270 days was found to be uniform due to the contribution of bearing reinforcement and was approximately 25 mm. The bearing stress which was uniformly distributed was found to increase rapidly with construction time, which was in agreement with the relatively uniform settlements. The lateral wall movement at the front and lateral sides at the end of construction was very small with the maximum movement (at the top of the wall) found to be less than 10 mm. As such, the ratio of lateral movement to height (δ/H) was found to be approximately 0.12%, which was lower than the allowable value of 0.4%. With this low δ/H and the insignificant change in the measured settlement and lateral movement during service, the BRE wall was considered to have a very high stability. The coefficients of lateral earth pressure, K and depth relationship were proposed based on the analysis of measured maximum tensile force in the reinforcements. The maximum tension plane of the BRE wall could be represented by the coherent gravity hypothesis. Using the proposed K and maximum tension plane, the internal stability of the BRE wall was furthermore examined. A proposed method of designing the BRE wall with claystone backfill was also proposed.