纳米4-H碳化硅薄膜的掺杂现象

对纳米晶SiC薄膜进行了P和B的掺杂,B掺杂效率比P高,其暗电导预前因子与激活能遵守Meyer-Neldel规则,并有反转Meyer-Neldel规则出现.掺杂效率比非晶态碳化硅薄膜高是纳米碳化硅薄膜的特点之一.非晶态中的隧穿和边界透射对输运有一定贡献.     

Effect of oxygen flow rate on the structural and electrochemical properties of lithium nickel oxides synthesized by the sol–gel method

The structural and electrochemical properties of LiNiO₂ powders were investigated as a function of the oxygen flow rate employed in the preparation of lithium nickel oxide. It was found that oxygen played an important role in the synthesis of highly crystallized LiNiO₂(R3¯m). In the crystallization process of LiNiO₂, a deficiency of oxygen in the calcination reactor induced the formation of impurities and cubic rock-salt structure (Fm3m) in LiNiO₂ powders. For LiNiO₂ prepared at higher oxygen flow rates, the electrode delivered high discharge capacities with relatively good retention rates. But very low electrode capacity was obtained from LiNiO₂ prepared at lower oxygen flow rates.     

Influence of heat transfer on anodic oxidation of aluminium

The influence of convective heat transfer on constant current density anodizing of aluminium in sulfuric acid has been examined in a wall-jet electrode reactor. The uniformity of the anodic film thickness is related to the local electrode temperature distribution, which is dependent on the convection. The higher the local temperature, the greater the local oxide thickness. An increased local temperature enhances local field assisted oxide dissolution at the pore bases, and consequently acts to increase the local current density. At relatively high current densities, local features develop on the electrode surface, accompanied by high initial, local temperature rises. The relevance of such local features, limiting useful oxide growth, is considered further.     

加氢催化剂器外再生技术(HCRT)的开发与应用

淄博恒基化工有限公司开发的加氢催化剂器外再生技术 (HCRT) ,具有工艺合理、再生催化剂物性恢复好、活性损失少等特点 ,该技术已达到国外器外再生技术的水平。近年来已再生全国 19个炼油厂、2 3个品种的催化剂 12 95t,工业应用均取得满意结果     

C5/C6异构化催化剂的首次工业应用

采用中石化金陵分公司研究院研制的CI-50(Pd/丝光沸石)作C5/C6烷烃异构化催化剂.详细介绍了该催化剂的工业放大试验装置的工艺流程、首次开工过程中技术问题及处理方法.     

薄相屏闪烁的数值分析

本文在弱闪烁条件下，利用广泛适用于星际闪烁、行星际闪烁和电离层闪烁的薄相屏理论，以行星际闪烁为算例，对薄相屏闪烁进行了数值分析。结果表明：垂直于介质运动方向上的不规则结构的大小对闪烁有着重要的影响，直接表现在频谱的变化趋势和振荡幅度的不同。尤其是当小于Ｆｒｅｓｎｅｌ尺度时，数值计算表明此时没有闪烁发生。     

Sol-gel processing: A versatile concept for special glasses and ceramics

The various parameters related to sol-gel processing are discussed with special reference to those which usually attract less attention but depending on the final product in mind, can play important roles. The versatility of the sol-gel technique in materials preparation is demonstrated by discussing the various products developed at the author’s laboratory by using this processing method.     

3961连续重整催化剂性能考察

新一代高活性，高水热稳定性3961（PS－Ⅳ）型连续重整催化剂于1996年在上海石化芳烃厂400kt/a连续重整装置上首次进行工业应用试验。开工5a，催化剂跟踪分析结果表明，该剂保持了良好的物化性质和反应性能，表现为良好的比表面积稳定性和持氯能力，经过200个以上再生周期的催化剂未发现有明显的相变和金属分散度的变化。     

A detailed analysis of ambipolar diffusion in nanostructured metal oxide films

In this paper a transport equation is derived which describes the behaviour of the nanostructured metal oxide films in a photoelectrochemical cell. It is shown that a detailed analysis of the charge compensation mechanism necessarily leads to a transport equation with characteristics similar to but logically distinct from the pure diffusion equation. The studied phenomenon was named ambipolar diffusion in the early 1950s. It takes into account the fact that the diffusion processes of ions and electrons occur at different speeds. A weak electric field therefore couples the processes together to preserve charge neutrality. The electric field in turn affects the transport resulting in a deviation from purely diffusive behaviour. However, this has not been widely recognised in the literature for nanostructured semiconductor films until very recently. In this paper a detailed analysis is presented. It is based on the assumption that the current density is solenoidal. It is shown that application of the ambipolar diffusion model to a photoelectrochemical cell based on a nanostructured metal oxide film leads to an additional term in the transport equation, rather than only a new diffusion coefficient as in earlier work. It is also shown that the boundary conditions interact closely with the equation to form a transport model.     

Investigation of Scale Formation in Heat Exchangers of Phosphoric Acid Evaporator Plants

The primary problem in concentrating phosphoric acid is due to fouling on the tube‐side of the heat exchangers of the evaporator units. Scaling on the heat transfer surfaces occurs because of high supersaturation of phosphoric acid liquor with respect to calcium sulphate. A review of the existing literature reveals that no information is available on heat transfer and on crystallization fouling of industrial phosphoric acid solutions. In this investigation, the solubility of different calcium sulphate types in phosphoric acid solution was studied and its dependency on acid concentration and temperature was investigated. A large number of fouling experiments were carried out in a side‐stream of a phosphoric acid plant at different flow velocities, surface temperatures and concentrations to determine the mechanisms, which control the deposition process. After identifying the effects of operational parameters on the deposition process, a model was developed for prediction of fouling resistances. The reaction of calcium sulphate crystallization followed a second order rate with respect to the supersaturation. The activation energy evaluated for the surface reaction of the deposit formation was found to be 57 kJ/mol. The predicted fouling resistances were compared with the experimental data. Quantitative and qualitative agreement between measured and predicted fouling rates is good.