生物质中元素分布特征的聚类分析研究

测定了稻草秆、小麦秆、玉米秆、棉花秆、大豆秆、玉米芯、花生壳和柳树、松树、桦树、杨树、杉树 1 2个农业生物质和林业生物质种类 2 7个样品中主要元素 K,Ca,Na,Mg,Al,Fe,P和痕量元素 As,Cr,Co,Cu,Cd,Mn,Mo,Ni,Pb,Ti,Zn,V,Si,Ba,Be,Se,Sb,Ge,Hg的含量 ,并用SPSS聚类分析法分别进行了 R型和 Q型聚类研究 ,对这些元素在生物质中的分布特征进行了研究 .结果显示 :杨木、杉木和桦木与松木和柳木归成一大类 ,经济类作物黄豆秆和棉花秆分别归类后又归入一大类 ;农业生物质稻草秆和小麦秆、玉米秆被归入一类 ;虽然 2 7种生物质样品分别取自我国东北、华东、华北和西南地区 ,在地理位置上相距极远 ,但样品聚类谱系图表明 ,元素的分布特征与生物质的种类的关系显著 ,与产地的关系不明显 ,即元素的分布特征受种类的影响大 ,而受生长环境、气候、土壤条件的影响小 .     

Characterization of microporous-mesoporous MCM-41 silicates prepared in the presence of octyltrimethylammonium bromide

MCM-41 silicates prepared in the presence of octyltrimethylammonium bromide either by a conventional method or by post-synthesis hydrothermal treatment were characterized by nitrogen adsorption in a wide range of relative pressure from 10^-6 to 1. Hydrothermally restructured samples were found to have lower BET surface areas, lower external surface areas and thicker silica walls than the non-treated sample. More importantly, in addition to their characteristic mesopores (ca. 3 nm), they were shown to have considerable amounts of micropores. The relative amount of micropores and mesopores was shown to be dependent on the treatment conditions. Thus, it is demonstrated that the postsynthesis hydrothermal restructuring is a convenient synthesis route to MCM-41 silicates with bimodal pore size distribution involving controllable amounts of microporosity. This revised version was published online in July 2006 with corrections to the Cover Date.     

Bayesian bivariate generalized Lindley model for survival data with a cure fraction

The cure fraction models have been widely used to analyze survival data in which a proportion of the individuals is not susceptible to the event of interest. In this article, we introduce a bivariate model for survival data with a cure fraction based on the three-parameter generalized Lindley distribution. The joint distribution of the survival times is obtained by using copula functions. We consider three types of copula function models, the Farlie–Gumbel–Morgenstern (FGM), Clayton and Gumbel–Barnett copulas. The model is implemented under a Bayesian framework, where the parameter estimation is based on Markov Chain Monte Carlo (MCMC) techniques. To illustrate the utility of the model, we consider an application to a real data set related to an invasive cervical cancer study.     

种子法制备聚合物乳液技术的进展

从建筑乳液的生产现状、自生种子法与外加种子法的区别、种子乳液的特点及外加种子法生产的乳液特性等方面介绍了种子法制备乳液技术的进展。     

COMPUTER SIMULATION OF HYDRODEMETALLATION IN FIXED-BED REACTORS

An isothermal model for hydrodemetallation (HDM) of crude oils in catalytic fixed-bed reactors is proposed. This model involves a consecutive reaction mechanism, which is capable of accounting for particle deposit profiles with interior maxima. Consistent with the fact that HDM catalysts are conglomerates formed by precipitation, the porous catalyst itself is modeled as randomly overlapping spheres of equal size. The metal is deposited as growing metal sulfide crystallites on the inner surface of the catalyst. These crystallites originate from a certain number of randomly scattered nuclei and increase in size as the deposition proceeds. The random sphere model for the catalyst and the deposit provides the changes in the catalyst pore structure—local porosity and surface area.

The mass transport within the domain of the particle is due to restricted liquid diffusion, since the diameter of the metal bearing compound (porphyrin) and the intermediate are comparable to the pore size. The diffusion restrictions taken into account are the enhanced drag imposed on a molecule by adjacent pore walls and steric partitioning.

Since the deposition process is much slower than diffusion and reaction, the pseudo-steady-state assumption can be justified. The equations of conservation for mass are solved by orthogonal collocation on finite elements. Based on this solution technique a computer simulation program of HDM is designed that allows two modes of operation: constant temperature and constant conversion. The simulation program “SIMULA” is highly flexible with regard to reaction kinetics, catalyst structure, reactor design, and operating conditions. In comparison to a base case with uniform activity, the effect of intraparticle (radial) and bed (axial) activity profiles on the conversion rate is discussed. For the case investigated, a radial distribution of activity higher at the center of the particle than at the edge can increase catalyst life by 25%, but axial distribution was less successful.     

基于MPLS的VPN互访技术

针对VPN互访问题,根据IPSec-VPN互访方法的不足,提出动态MPLS-VPN方法.利用随机分配的标签,在需要互访的不同VPN网络节点之间构建MPLS通道,利用互访规则集检验节点的连接申请,根据过滤规则控制数据包的传输,通过设定传输时长限制节点互访的时间,实现VPN之间接节点、按方向、按时间的细粒度互访控制,确保数据传输的安全性和高效性.给出动态MPLS-VPN方法实现互访的步骤,对方法进行分析比较.     

基于数据转换服务实现卷烟吸阻达标率的计算

针对吸阻达标率计算过程复杂,操作步骤繁多的问题,提出运用SQL Server工具DTS(Data Transformation Service数据转换服务)计算卷烟吸阻达标率,其实现过程包括数据库连接、数据表建立、视图创建、DTS包设计、代码编写、JOB作业建立和Excel透视表建立等步骤。结果证明吸阻达标率计算程序的开发不仅为达标率的实际应用提供技术支撑,还有助于企业更好地控制产品质量,提高生产工艺水平。     

基于城市小区域的车联网模型

随着社会进步及车辆增多,交通问题日益突出,使得城市环境下车联网的研究受到越来越多的关注。基于真实数据的分析和验证,可以得到城市不同区域的车联网网络度分布服从广义的幂律分布,即网络是无标度网络。根据此性质利用复杂网络理论建立车联网网络模型,通过分析和仿真验证该模型的正确性和有效性。     

两级定位-路径问题的变邻域人工蜂群算法

建立了两级定位-路径问题的数学模型,提出了一种求解该问题的人工蜂群算法。针对该算法容易出现早熟现象,将近年来国外出现的一种新颖的轨迹式启发式算法--变邻域搜索融入其中,由此提出三种变邻域搜索策略。基于不同变邻域搜索策略的人工蜂群算法和人工鱼群算法的求解效果进行对比仿真。实验结果表明,变邻域人工蜂群算法能有效求解两级定位-路径问题。