溶胶-凝胶法制备磷钨酸-硅胶催化合成苹果酯

采用溶胶-凝胶法制备了一系列磷钨酸-硅胶催化剂(PW/SG),考察了该催化剂催化乙酰乙酸乙酯与乙二醇液相缩合制备苹果酯的反应性能。实验结果表明,PW质量分数为40%时的PW/SG催化剂表现出最佳的催化活性;40%PW/SG催化剂制备苹果酯的最佳工艺条件为:n(乙酰乙酸乙酯)∶n(乙二醇)=1∶1.2,催化剂用量占反应物质量的0.36%,带水剂环己烷用量占反应物体积的30%,反应温度383K,反应时间90min;在此条件下,乙酰乙酸乙酯的转化率可达95.5%,苹果酯的选择性大于97%;催化剂稳定性实验表明,经5次重复使用,40%PW/SG催化剂的活性基本保持不变,乙酰乙酸乙酯转化率稳定在95.0%左右。     

Numerical Simulation of Independent Advance of Ore Breaking in the Non-pillar Sublevel Caving Method

The mechanism of stress generation and propagation by detonation loading in five separate independent advance of ore breaking patterns is discussed in the paper. An elastic numerical model was developed using AN- SYS/LS-DYNA 3D Nonlinear Dynamic Finite Element Software. In this package ANSYS is the preprocessor and LS-DYNA is the postprocessor. Numerical models in the paper to actual were l：10 and the element mesh was dissected in scanning mode utilizing the symmetry characteristics of the numerical model. Five different advance rates were studied. Parameters, such as the time required to maximum stress, the action time of the available stress, the maximum velocity of the nodes, the stress penetration time, the magnitude of the stress peak and the time duration for high stress were numerically simulated. The 2.2 m advance appeared optimum from an analysis of the simulation results. The results from numerical simulation have been validated by tests with physical models.     

SOME NEW ASPECT OF LYAPUNOV TYPE THEOREMS FOR STOCHASTIC DIFFERENCE EQUATIONS WITH CONTINUOUS TIME

Some new Lyapunov type theorems for stochastic difference equations with continuous time are proven. It is shown that these theorems simplify an application of Lyapunov functionals construction method.     

大角度倾转法在碳化物研究中的应用

蠕变过程中碳化物形貌，类型，数量和分布状态的变化直接影响着材料的高温性能，因而在材料的蠕变得到了广泛的重视，介绍了一种在碳膜萃取复型样品上利用Ｈ－８００透射电子显微镜的双倾样品台进行了大角度倾转，来观察碳化物形貌并鉴定其类型的试验方法。     

重油隧道窑的红外温度测量

在分析重油隧道窑工况的基础上，分析了窑内烟气、燃烧物发射率、窑墙效应、环境温度对红外测温的影响以及热电偶测温的缺点，采取了相应的措施。利用中国发现专科实现了传感器输出信号的一致性。给出了传感器在重滑隧道窑现场使用２．５年后的复校数据。最后，估算出了用红外温度计替代热电偶测窑温产生的经济效益。     

Nonlinear filtering structure for image smoothing in mixed-noise environments

This paper introduces a new nonlinear filtering structure for filtering image data that have been corrupted by both impulsive and nonimpulsive additive noise. Like other nonlinear filters, the proposed filtering structure uses order-statistic operations to remove the effects of the impulsive noise. Unlike other filters, however, nonimpulsive noise is smoothed by using a maximum a posteriori estimation criterion. The prior model for the image is a novel Markov random-field model that models image edges so that they are accurately estimated while additive Gaussian noise is smoothed. The Markov random-field-based prior is chosen such that the filter has desirable analytical and computational properties. The estimate of the signal value is obtained at the unique minimum of the a posteriori log likelihood function. This function is convex so that the output of the filter can be easily computed by using either digital or analog computational methods. The effects of the various parameters of the model will be discussed, and the choice of the predetection order statistic filter will also be examined. Example outputs under various noise conditions will be given.     

现场地质预测与决策技术

油气的生成、运移、分布、成藏、保存具有规律性，技术人员可以依据其规律性对地下地质情况进行推理、预测和决策。钻井过程的现场地质预测技术方法主要是外推法、因果法和直观法三大类。外推法是常用的预测方法，包含了岩性、沉积旋回、标志层、标准层、重矿物等岩石地层学对比方法和生物地层学方法及地球物理方法。现场地质预测与决策是通过确定预测目标、收集相关资料、进行对比分析、形成地质预测结果、拟定地质决策方案、方案优选、方案实施等环节来完成。该技术是现场地质监督的核心技术，在实践中取得显著成效。     

Engset multi‐rate state‐dependent loss models with QoS guarantee

We consider a single link loss system of quasi‐random input, described by the Engset multirate loss model (EnMLM). Blocked calls may once reattempt to be connected to the system requiring less bandwidth; then the system is described by the single retry model for finite sources (f‐SRM). The EnMLM and the f‐SRM are extended with the single threshold finite source model (f‐STM), where calls may attempt to be connected to the system with less bandwidth requirements, according to the link occupancy, before blocking occurs. We focus on CBP equalization in the EnMLM, f‐SRM and f‐STM, under the bandwidth reservation (BR) policy. For this analysis, we apply two approximate methods, the Roberts' method and the method of reverse transition rates (RTR), which lead to a recursive CBP calculation. We evaluate the accuracy of the above models under the BR policy by comparing the analytical with simulation CBP results, based on the relative approximation errors (RAE). The results are highly satisfactory because they show that the proposed models (formulas) lead to small RAE. Copyright © 2005 John Wiley & Sons, Ltd.     

大红山铜矿岩体结构调查分析

大量工程实践已证明岩体结构是控制岩体稳定性的重要影响因素。为此，以大红山铜矿为研究背景，在选定有代表性调查地段的基础上，引入详细观测线法对其岩体结构进行了详细调查与统计。分析结果表明：调查区域内巷道岩体节理裂隙比较密集和发育，主要发育有倾向N53E、走向N37W、倾角53°，倾向W26S、走向N36W、倾角68°；倾向E1S、走向NIE、倾角89°的三组优势结构面，其中优势结构面第二组和第三组构成不稳定块体，并且断层及软弱夹层比较发育，加剧了巷道的破碎程度，对巷道围岩的稳定性有控制作用。最后提出了在巷道施工中密切注意围岩稳定性变化，避免工程事故的发生的建议。     

Optimized Schwarz methods without overlap for highly heterogeneous media

In this paper an original variant of the Schwarz domain decomposition method is introduced for heterogeneous media. This method uses new optimized interface conditions specially designed to take into account the heterogeneity between the sub-domains on each sides of the interfaces. Numerical experiments illustrate the dependency of the proposed method with respect to several parameters, and confirm the robustness and efficiency of this method based on such optimized interface conditions. Several mesh partitions taking into account multiple cross points are considered in these experiments.