S3C6410和CR95HF的RFID读卡系统设计

针对目前读卡器主频低、速度慢、便携性差等不足,提出了一种基于S3C6410的RFID读卡系统设计方案。本文以高性能的S3C6410嵌入式微处理器为核心,选用新型的CR95HF射频芯片,开发设计了一款高主频的搭载Android嵌入式系统的新型手持式RFID读卡器。该读卡器工作在高频13.56MHz,支持ISO14443、ISO15693等多种协议。实验证明,该读卡器能对符合协议的标签进行读写操作,读写距离能够满足需要,具有便携、稳定性高、处理速度快等特点。     

STM32和OV2640的嵌入式图像采集系统设计

基于STM32嵌入式系统及200万摄像头OV2640设计了图像采集系统,分析了系统的基本硬件架构,分别对不同模块的功能特点作出了简单的介绍;对系统的软件设计给出了详细的说明,介绍了系统初始化的基本思路和流程,以及相关外围设备模块在程序中的使用;并给出了系统的整体设计思路,实现了系统的稳定运行。     

高吸水性树脂与PVC共混的研究

用高吸水性树脂与PVC共混制备了吸水膨胀性PVC共混物。实验证明,部分水解丙烯酸甲酯—醋酸乙烯酯HP(MA—VAC)和丙烯酸甲酯—醋酸乙烯酯—甲基丙烯酸甲酯HP(MA—VAC—MMA)共聚物与PVC共混效果更好。研究了影响共混物吸水率和力学性质的各种因素。结果表明,随高吸水性树脂用量增加,共混物吸水率显著增加。当吸水树脂用量大于40%时,共混物的拉伸强度和断裂仲长率下降。共混物最大吸水率达22.17克水/克共混物,最大膨胀度为15倍。     

Direct Measurement of Transformation Zone Strains in Toughened Zirconia

Residual strains responsible for crack tip shielding have been measured within transformation zones surrounding cracks in Mg-PSZ. Two techniques were used for strain measurement: moiré interferometry and high-resolution image matching. Both methods provide maps of differential in-plane displacements within the specimen surface intersected by the crack, the latter method with the higher resolution. The results are compared with finite-element analysis to assess surface relaxation effects, and the measured strains are used to evaluate the crack tip shielding stress intensity factor. Calculations based on the assumption that the unconstrained transformation strain is hydrostatic dilatation yielded results that were significantly smaller than the measured toughness increases.     

Light-sensitive elastomers modified by 4-(N-dimethylmaleimido)-benzenesulphenyl chloride

New light-sensitive polymers were prepared by modification of four different elastomers with 4-(N-dimethylmaleimido)-benzenesulphenyl chloride (DMI-BSCI). Polydienes modified by DMI-BSCI form block copolymers. These polymers show a strong increase of the glass transition temperature T_g whereby the T_g increase of modified poly(octenamer) is much smaller. Higher modified polydienes have two T_g. Modified poly(octenamers) show a melting temperature dependence T_m on the content of trans double bonds which is characteristic of statistical copolymers. The ratio of rate constants with which trans- and cis-structures in poly(octenamer) are occupied by DMI-BSCI, is

$\text{k}{}_{\mathrm{trans}}\text{k}{}_{\mathrm{cis}}\text{= 0.34}$

     

Characterization of boron-doped diamond electrodes by electrochemical impedance spectroscopy

Charge transfer on boron doped diamond (BDD) electrodes was studied by cyclic voltammetry and electrochemical impedance spectroscopy. The diamond films of 5 μm thickness and boron content between 200 ppm and 3000 ppm were prepared by the hot filament CVD technique on niobium substrate and mounted in a Teflon holder as rotating disk electrodes. The electrochemical measurements were carried out in aqueous electrolyte solutions of 0.5 M Na₂ SO ₄ + 5 mM K₃[Fe(CN)₆]/K₄[Fe(CN)₆]. Significant deviation in the redox behaviour of BDD and active Pt electrodes was indicated by a shift of the peak potentials in the cyclic voltammograms with increasing sweep rate and lower limiting diffusion current densities under rotating disk conditions. In the impedance spectra an additional capacitive element appeared at high frequencies. The potential and rotation dependence of the impedance spectra can be described quantitatively in terms of a model based on diffusion controlled charge transfer on partially blocked electrode surfaces. Direct evidence for the non-homogeneous current distribution on the diamond surface was obtained by SECM measurements.     

Fatty acid composition of spanish shortenings with special emphasis on <Emphasis Type="Italic">trans</Emphasis> unsaturation content as determined by fourier transform infrared spectroscopy and gas chromatography

A Fourier transform infrared spectroscopic procedure was used to analyze 34 edible fats (22 shortenings and 12 vegetable margarines) as neat fats (IR_NF) to determine their total trans fatty acid (TFA) content. The sloping baseline was corrected with a reference spectrum based on a nonprocessed olive oil. The calibration was done using seven partially hydrogenated fats with an individual TFA content previously determined by the combination of gas chromatography (GC) with argentation thin-layer chromatography. Taking into account the different absorptivities of various trans isomers, different correction factors were calculated using the calibration standards (0.83 and 1.71 for single trans bonds in both diethylene and triethylene and for trans, trans-diethylene fatty acids, respectively) and applied to calculate the total TFA of samples. Moreover, the samples were converted to their methyl esters and reanalyzed following the same procedure (IR_FAME). Differences in TFA content of fats were not found when a t-test was used to compare the results obtained by IR_NF vs. either IR_FAME or GC, suggesting that IR of neat fats could be used, thus avoiding the need to prepare sample solutions in organic solvents and to prepare fatty acid methyl esters. The mean TFA content (determined by IR_NF) of a representative group of Spanish shortenings (22 samples) that varied widely in terms of fat sources, processes, and purposes (bakery, sandwiches, ice cream, coatings, chocolate coverings) was 6.55±11.40%, although more than 54% contained <3% of TFA. Fatty acid composition of shortenings by direct GC using a 100-m polar cyanopolysiloxane capillary column indicated that the mean trans-18∶2 isomer content was 0.58%, ranging from 0.9 to 3.4%. Small amounts of trans-18∶3 isomers (<0.3%) were observed in 18 of the 22 shortenings studied; the maximal value was <2%. The mean value of the fraction saturated+TFA of shortenings was high (59.95±12.73%), including two values higher than 83%.     

'Polymorph Method' Determination of Monoclinic Zirconia in Partially Stabilized Zirconia Ceramics

The polymorph method, which provides phase analysis from a small number of integrated intensities in a powder diffraction scan, is adapted for the determination of monoclinic zirconia in a mixture with cubic, tetragonal. and orthorhombic zirconias and the γ-phase (Mg₂Zr₅O₁₂). Such a mixture is representative of Mg-PSZ after subeutectoid aging. The quantitative determination of the monoclinic depends in principle on a knowledge of the relative amounts of the other phases present in the mixture. It is demonstrated, however, that without this knowledge, even in complex mixtures, the traditional polymorph method analysis gives an acceptable estimate of the monoclinic fraction in the sample.     

基于粗糙集的载体桩质量核心影响因素分析

针对载体桩质量不容易控制的特点,在剖析载体桩承载机理的基础上,分析了影响载体桩质量的各因素,并引入粗糙集理论,建立了影响因素约简模型。以邯郸地区载体桩工程为例,通过模型约简得出最小的影响因素集,从而确立了影响载体桩质量的核心影响因素,为载体桩的质量预测和控制提供理论依据。结果显示该方法克服了目前人们以主观和定性分析为主的缺点,可信度较高。     

电磁管道抗垢装置的功放及回馈电路关键技术

分析比较了超声波防垢、机械去垢、管道化学酸洗、管道高压水射流清洗和电磁防垢的方法和效果。利用电磁防垢的防垢、除垢、杀菌和灭藻的功能原理,研制了嵌入式音频电磁共振管道抗垢装置。音频功率放大器件是装置的关键部分,既保证了足够的功率输出,又具有短路保护和过热保护作用。电路设计上,根据推动负载线圈功率信号的特点,将常规的线性功率放大电路改进成比较开关电路,有效降低了功放芯片的自身损耗。装置还通过线性光耦回馈负载线圈上的信号,进行峰值检测,经过微处理器运算后输出最佳频率,优化了管道抗垢去垢功效。