Sorption of Acid Green 25 on chitosan: Influence of experimental parameters on uptake kinetics and sorption isotherms

Acid Green 25, which is a diazoic dye bearing two sulfonic groups, is efficiently sorbed on chitosan. The protonation of chitosan may explain the electrostatic attraction of this anionic dye and that its optimum pH is close to 3. Preliminary protonation of amine groups (obtained by contact with a sulfuric acid solution) reduced the variation of solution pH following sorbent addition but significantly reduced sorption performance: the maximum sorption capacity of raw chitosan, 525 mg dye/g (0.84 mmol dye/g), was halved by acidic preconditioning. The acidic conditioning also reduced the kinetic rate—the time necessary to reach equilibrium increased up to threefold depending on the experimental conditions. The size of sorbent particles influenced sorption kinetics and equilibrium because of resistance to intraparticle diffusion, but the sorption appeared to occur not only at the surface of the sorbent but also in the intraparticle network of the polymer. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 1073–1080, 2003     

双层堤基的井涌破坏与无害管涌

双层堤基水文地质结构特殊，堤基承压水常具独特的“渗而不流”特征。在“不流”条件下，堤后盖层薄弱处受超高承压水头顶裂破坏，产生的局部冒水孔实属承压自流井，由此形成的管涌实质为井涌。底部进水的承压井流影响范围不大，井涌的破坏范围更小，据此可区分出有害管涌与无害管涌。前者局限于堤脚附近，小范围压渗为首选方案；对后者，既无需专门防治，更不必追求根治。     

安塞低渗油田孔隙结构对渗流特征曲线的影响

渗流曲线的测定是认识油藏流体渗流规律的基础。实验发现安塞油田储集层岩心渗流曲线在低有效净围压下近似表现为两段直线，通过压汞实验和毛管压力曲线数据分析，认为这种特征与储集层孔隙结构有关。在分析渗流特征时应综合考虑孔隙结核特征、流体与孔隙介质的相互作用等因素。     

青海省桥头电厂河子沟灰场拦洪坝粘滞流模型试验分析

本文采用粘滞流模型试验对青海桥头电厂河子沟灰场拦洪坝设计方案进行了论证，分析了多种防渗条件下的渗流场特点，提出了满足工程运作的既经济又合理的建议。     

FLOW OF NEWTONIAN FLUIDS THROUGH SINUSOID ALLY CONSTRICTED TUBES. NUMERICAL AND EXPERIMENTAL RESULTS

Numerical and experimental predictions of pressure drops in the flow of Newtonian fluids through sinusoidally constricted tubes (SCT) are carried out. The numerical evaluations analyzed in this work are obtained from the following methods: Geometric Iteration (GJM), Geometric Iteration with First and Second Upwinds (GIM1, GIM2), Successive Over Relaxation by Line (SORBLM), Global Galerkin Spectral Method (GGSM), Collocation (CM) and Dufort-Frankel (DFM). The GIM1, GIM2 and SORBLM are applied to SCT and explained in this work. The other methods have been previously reported in the literature with the same purpose. Experiments are accomplished for constrictions of approximately 40,60 and 80% of the average tube diameter and results compare well with numerical predictions of the steady flow. It is concluded that special attention should be given to evaluations of the friction factor ƒ for Reynolds numbers Re between the onsets of flow separation and turbulence due to flow instability. Finally, the SCT as a model for porous media (PM) is discussed.     

Bi3+对纳米MnO2水热合成的影响研究

在中性和酸性条件下，以MnO2作为锰源，通过水热合成了纳米MnO2，通过XRD和TEM对产物进行的观察表明，在酸性条件下，向溶液中添加一定量的Bi^3 ，产物的晶型由α型向γ型转化，产物形貌由针状、丝状向颗粒状转变。     

基于米氏散射及夫朗和费衍射的FAM激光测粒仪

提出了综合运用夫朗和费衍射和米氏散射，即在大粒径范围内采用夫朗和费衍射理论，而在小粒径范围内采用米氏散射理论，来改善小粒径范围内的测量精度，保证激光测粒仪在整个粒径范围内的测量精度。     

调节阀流量特性控制分析

介绍了调节阀的流量基本知识，从控制理论的角度，分析了调节阀的理想流量特性、工作流量特性和系统稳定性，指出了在热工领域内应用调节阀时的一些注意事项。     

雾化水流计算模式

本文描述了雾化水流现象并提出了雾化水流的一个计算模型。得出了雾化水流影响领域的各种不同的计算公式和方法。