长庆上古生界气层CO2增能压裂工艺

长庆上古气藏物性差,压力系数低,水锁伤害大,采用常规水力压裂,入井液返排困难,气井产量低。在储层改造地质研究的基础上,通过对CO2泡沫压裂技术进行室内攻关,引进开发了CO2泡沫压裂酸性交联技术,优化了CO2泡沫方案设计及现场施工工艺,配套了CO2增能压裂工艺技术。经过现场应用,充分说明了CO2增能压裂是一项行之有效的工艺技术,对于提高单井产量和长庆气田整体开发水平都是有益的。     

Studies on chitin 3—effect of coagulants and annealing on the preparation and the properties of chitin membrane

Chitin membrane was prepared by casting a N,N-dimethyl acetamide, N-methyl 2-pyrrolidone and lithium chloride (DMA-NMP-LiCl)solution of chitin and coagulating with several media. The effect of the coagulants on membrane formation was studied. 2-Propanol was found to be more favourable than methanol, ethanol, acetone and mixtures of 2-propanol and water. The membrane obtained in 2-propanol was subjected to annealing. Annealing made the membrane dense and strong. The tensile strength of the membrane annealed at 145°C for 2hr was about twice that of an unannealed membrane. The solute permeability of the annealed membranes was lower than that of the original one. These phenomena could be clearly interpreted in terms of crystallinity.     

正交曲线坐标下三维代数应力通量模型

针对弯曲及不规则明渠的水动力及物质输运特性，本文建立了曲线坐标系下的三维代数应力通量数学模型，对平面上弯曲及不规则复杂边界情形，采用Poisson方程进行正交曲线坐标变换，各向异性的湍流代数应力通量模型被引用于本文的模拟计算中，以体现复杂边界条件引起的水动力及物质输运特性的变化。通过180度强弯曲明渠水槽及贵溪电厂不规则边界河段物理模型试验两个实例计算表明，实测值与计算吻合良好，效果令人满意。     

低渗透油藏生产井关井测压时间的计算与应用

低渗透油藏的生产井压裂后，在单井试油试采过程中，压力恢复测试关井时间不同，其中有些井压力恢复曲线不能出现边界反应段，渗流不能反映地层中真实流动特征。针对这种情况，基于长庆绥靖油田塞39井区长：低渗透油藏大量试井和实际生产资料，利用现代试井解释理论，研究合理关井时间的界限及其计算方法。结果表明，当油井关井测压时间达到3倍地层径向流开始出现的时间后，利用此时的压力数据解释地层参数和地层压力，其结果的误差小于5％，同时能较准确地判断边界类型。计算的理论曲线和霍纳法解释值非常接近，对于塞39井区，若预先知道某生产井地层有效渗透率值，可从理论曲线查出压力恢复试井的关井时间，否则，建议按照该井区地层有效渗透率（大约在6mD左右），将不稳定试井测试时间控制在25d以上为宜。图4表3参14     

Growth,characterization and electrical anisotropy in GaTe—a natural semiconducting superlattice

GaTe is a III–VI semiconductor which has layered structure with large anisotropy in electrical properties. Growth of single crystals by the Bridgman technique permitted the measurement of thermoelectric power in orthogonal directions from which the anisotropy of hole effective masses were determined for the first time. From resistivity and Hall effect measurements the carrier activation energies and scattering mechanisms between 10–300°K were found. Study of the temperature dependence of conductivity revealed a variety of conduction mechanisms including weak localization below 20°K, hopping conduction between 20–50 K and band conduction in and across the layer planes atT>70 K. Weak localization was confirmed through observation of negative magnetoresistance. TheI–V characteristics showed quantized behaviour due to tunneling across potential barriers, which may be due to stacking faults between layer planes as observed by TEM studies.     

Properties of Edible Films from Total Milk Protein

The mechanical properties and water vapor permeability of edible films made from various total milk proteins (TMPs) were investigated. Two TMPs obtained from nonfat dry milk (NDM) by removing lactose and three TMPs obtained from a commercial source were studied. Lactose was extracted from NDM by ultrafiltration or suspension in ethanol followed by filtration. TMP concentrate obtained by ultrafiltration (UF) produced films with the lowest water vapor permeability (WVP) and the highest tensile strength at break. Commercial TMP concentrates produced films more ductile than those from the UF-TMP or retentate from ethanol extraction. Further research is needed to improve mechanical properties of UF-TMP films without increasing the WVP.     

耐高温微生物驱油提高低渗透油藏采收率先导性试验

胜利油田东辛高温低渗透油藏含蜡高,常温微生物无法存活,针对这一问题,引进美国NPC公司耐高温菌种,在Y6-16井组开展高温低渗油藏微生物驱油提高采收率研究和现场试验。施工后Y6-16井日增注52m3,表皮系数由施工前的2.069减小为施工后的-6.31,油层污染得到较好改善;原油含蜡量、胶质沥青质含量降低,轻质组分增加,重质组分降低;井组采收率提高5.09个百分点。     

低压低渗气藏钻探过程中的保护方案

针对鄂尔多斯塔巴庙区块低压低渗气藏物理特性复杂的情况，推荐一套切实可行的气层保护方案。即实行全面钻井液监控；采用欠平衡钻井技术；储层保护前期研究；采用与地层流体配伍性好的阳离子钻井液体系；降低钻井完井液的滤失量，API滤失量小于5mL、高温高压滤失量小于15mL、固相含量小于8％、含砂量小于0．3％；根据储层裂缝的宽度和走向使用保护剂；对裸眼完钻的气层利用洗井清除井壁附近的污染带，恢复储层原始渗透率；固井作业防止气窜；采用具有抑制地层水敏、速敏保护气层的优质射孔液；水力压裂优化压裂设计，严格压裂施工。总之，气层保护技术是一个系统工程，任何一个环节的问题，都将对气层产生伤害．因此需加强气层保护研究，做到在钻开气层到投产的每道工序都采取积极有效的气层保护措施。     

特低渗油藏水平井布井方式研究

本文以西峰油田董志区长8油藏为例，运用数值模拟技术，研究了水平井组合方式及其井网形式。研究结果表明，水平井是提高特低渗油藏开发效果的有效途径。结合长庆特低渗储层吸水性能好的特点，认为采用直井注水，水平段走向垂直于储层最大主应力方位的水平井采油的井网组合开发效果最佳。     

横波速度各向异性初步探讨：—多波勘探资料的应用

在纵波、SH 型横波资料处理和解释过程中,我们发现四川 HBC 地区地下介质普遍存在方向各向异性。当横波通过方向各向异性介质时,分裂成两个波:一个波的偏振方向与裂缝平行,叫快横波;另一个波的偏振方向与裂缝走向垂直,叫慢横波。采用相应的观测和处理方法,便可获得快横波和慢横波剖面。根据同一界面的快、慢横波的旅行时可以求得各向异性系数。同样,还可以利用 SH 波与转换波的速度比求取各向异性系数。各向异性系数的大小,反映了裂缝的发育程度。如果野外作了 X、Y 分量观测,室内又作了坐标旋转处理,那么,就可以进一步确定裂缝带的方向。如果未作上述工作,也可以根据构造线走向,大致确定裂缝带的发育方向。