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21.
Laiyuan Chen Liwu Lin Zhusheng Xu Tao Zhang Dongbai Liang Qin Xin Pinliang Ying 《Catalysis Letters》1995,35(3-4):245-258
Infrared investigations on the interaction of methane with silica, aluminas (, and ) and HZSM-5 zeolite have been carried out. At low temperature (173 K), methane adsorption was observed over these oxides and HZSM-5 zeolite. Our findings featured that the infrared inactive
1 band (2917 cm–1) of a gaseous methane molecule became active and shifted to lower frequencies (2900 and 2890 cm–1) when it adsorbed on the surfaces of these adsorbents. Our results also demonstrate that hydroxyl groups played a very important role in methane adsorption over the acidic oxides and the HZSM-5 zeolite. When interaction between the hydroxyl groups and methane took place, the band shift of the hydroxyl groups varied with different oxides. The strength of the interaction decreased according to the following sequence, Si-OH-Al>Al-OH>Si-OH, which is in accordance with the order of their acidities. At higher temperatures, methane interacted quite differently with various oxides and HZSM-5 zeolite. It has been observed that the hydroxyl groups of silica, -alumina and HZSM-5 zeolite could exchange with CD4 at temperatures higher than 773K, while those on -alumina could exchange at a temperature as low as 573 K. Another interesting observation was the formation of formate species over Al2O3 (both and ) at temperatures higher than 473 K. The formate species would decompose to CO2, or produce carbonate at much higher temperatures. Formation of formate species was not observed over silica and HZSM-5 under similar conditions, -Al2O3 did not adsorb or react with methane in any case. 相似文献
22.
Electrophoretic deposition of carbon nanotubes 总被引:1,自引:0,他引:1
Aldo R. Boccaccini Johann Cho Judith A. Roether Boris J.C. Thomas E. Jane Minay Milo S.P. Shaffer 《Carbon》2006,44(15):3149-3160
Electrophoretic deposition (EPD) has been gaining increasing interest as an economical and versatile processing technique for the production of novel coatings or films of carbon nanotubes (CNTs) on conductive substrates. The purpose of the paper is to present an up-to-date comprehensive overview of current research progress in the field of EPD of CNTs. The paper specifically reviews the preparation and characterisation of stable CNT suspensions, and the mechanism of the EPD process; it includes discussion of pure CNT coatings and CNT/nanoparticle composite films. A complete discussion of the EPD parameters is presented, including electrode materials, deposition time, electrode separation, deposition voltage and resultant electric field. The paper highlights potential applications of the resulting CNT and CNT/composite structures, in areas such as field emission devices, fuel cells, and supercapacitors. 相似文献
23.
The present investigation describes the quantitative measurement of surface functional groups present on commercially available different PAN based carbon fibers, their effect on the development of interface with resol-type phenol formaldehyde resin matrix and its effect on the physico-mechanical properties of carbon-carbon composites at various stages of heat treatment. An ESCA study of the carbon fibers has revealed that high strength (ST-3) carbon fibers possess almost 10% reactive functional groups as compared to 5.5 and 4.5% in case of intermediate modulus (IM-500) and high modulus (HM-45) carbon fibers, respectively. As a result, ST-3 carbon fibers are in a position to make strong interactions with phenolic resin matrix and HM-45 carbon fibers make weak interactions, while IM-500 carbon fibers make intermediate interactions. This observation is also confirmed from the pyrolysis data (volume shrinkage) of the composites. Bulk density and kerosene density more or less increase in all the composites with heat treatment up to 2600 °C. It is further observed that bulk density is minimum and kerosene density is maximum upon heat treatment at 2600 °C in case of ST-3 based composites compared to HM-45 and IM-500 composites. It has been found for the first time that the deflection temperature (temperature at which the properties of the material start to decrease or increase) of flexural strength as well as interlaminar shear strength is different for the three composites (A, B and C) and is determined by the severity of interactions established at the polymer stage. Above this temperature, flexural strength and interlaminar shear strength increase in all the composites up to 2600 °C. The maximum value of flexural strength at 2600 °C is obtained for HM-45 composites and that of ILSS for ST-3 composites. 相似文献
24.
25.
Composite polymer electrolyte based on a new class of filler added to a PEGDME/LiClO4 model system has been investigated. “Ceramic super acids” used consist of grafted SO42− groups on Al2O3 particles surface obtained by calcinations route. Conductivity, DSC and FT-IR measurements performed on such composite electrolytes, when compared to the model PEGDME/LiClO4 electrolyte, showed only slight improvement of their inner characteristics. In contrary, Li/Li symmetric cells study, by means of impedance spectroscopy, has presented a spectacular decrease of the interfacial resistance compare to the model electrolyte. This result opens a new pathway of investigation to master the lithium metal/polymer electrolyte interface. 相似文献
26.
多编组协同任务分配模型及DLS-QGA 算法求解 总被引:1,自引:0,他引:1
为解决多智能体编组协同任务分配问题, 定义任务、智能体编组和相关的分配过程变量, 建立以最高任务执行效率为目标的数学模型. 在问题模型中设计考虑资源损耗的编组资源能力更新机制, 提出用于求解该模型的动态列表规划和量子遗传算法的混合任务分配算法, 使用动态列表规划选择处理的任务, 利用量子遗传算法为选定任务分配最合适编组. 最后通过算例表明, 所提出的方法在解决时序逻辑任务分配时能够得到更优更稳定的方案.
相似文献27.
以过硫酸铵为引发剂,十二烷基硫酸钠为乳化剂,采用种子聚合工艺,合成了偏氯乙烯质量分数为23%~43%的羧基偏氯乙烯丁苯胶乳。通过电镜观察到所合成的胶乳粒子具有核-壳结构。通过测定胶闰子表面层的羧基数量,研究了羧基的分布,结果表明,羧酸种类对羧基在胶乳粒子中及在聚合体系中的分布有重要影响,该胶乳作为地毯背衬粘合剂,具有粘合力高,极限氧指数高的特点,是一种较好的阻燃性粘合剂。 相似文献
28.
含多羟基功能基树脂的合成及其与硼酸螯合性能的研究 总被引:1,自引:0,他引:1
合成了数种含有多羟基醇单醚功能基的树脂,研究了反应条件及树脂的吸附性能。 相似文献
29.
Hagen V Frings S Wiesner B Helm S Kaupp UB Bendig J 《Chembiochem : a European journal of chemical biology》2003,4(5):434-442
[7-(Dimethylamino)coumarin-4-yl]methyl (DMACM) and [7-(diethylamino)coumarin-4-yl]methyl (DEACM) esters of 8-bromoadenosine 3',5'-cyclic monophosphate (8-Br-cAMP) and 8-bromoguanosine 3',5'-cyclic monophosphate (8-Br-cGMP) are described as novel caged compounds for 8-bromo-substituted cyclic nucleotides. Synthesis is accomplished by treatment of the free acids of the cyclic nucleotides with the corresponding 7(dialkylamino)-substituted 4(diazomethyl)coumarins. Irradiation of the DMACM- and DEACM-caged cyclic nucleotides with UV light stimulates the release of the cyclic nucleotides within roughly a nanosecond. The new caged compounds are resistant to hydrolysis in aqueous buffers and exhibit long-wavelength absorption properties with maxima at 400 nm, high extinction coefficients, and high quantum yields (0.15-0.31). Their favorable properties render these compounds the most efficient and rapid phototriggers of 8-bromo-substituted cyclic nucleotides known. The usefulness of the compounds for physiological studies under nondamaging light conditions was examined in HEK293 cells expressing the alpha subunit of the cyclic-nucleotide-gated (CNG) channel of cone photoreceptors (CNGA3) and of olfactory neurons (CNGA2) by using confocal laser scanning microscopy and the patch clamp technique. 相似文献
30.
本文主要研究活性炭表面氧化对其吸附二苯并噻吩性能的影响。将活性炭在不同低温下氧化制得表面氧化活性炭,用静态吸附法进行了二苯并噻吩在初始及氧化活性炭上的吸附等温线,应用Langmuir方程对吸附等温线进行拟合,用漫反射红外谱(DRIFTS)表征活性炭表面含氧基团,用Boehm滴定测定活性炭表面官能团含量,讨论了活性炭表面化学性质对其吸附二苯并噻吩的影响。结果表明:活性炭表面酸性含氧基团对二苯并噻吩的吸附有重要影响,酸性含氧基团越多,其吸附量越大。低温气相氧化活性炭提高了活性炭表面酸性含氧基团,提高了其对二苯并噻吩的吸附。氧化温度越高,其表面含氧基团含量越多,其对二苯并噻吩的吸附量也越大。Langmuir吸附等温线可适用于描述二苯并噻吩在活性炭表面上的吸附。 相似文献