N.m.r. study of the ferroelectric phase transition in a 7030mol% copolymer of vinylidene fluoride (VF2) and trifluoroethylene (TrFE)

Nuclear magnetic resonance (n.m.r.) studies of ¹⁹F nuclei in a $\text{70}\text{30}\text{mol}\text{\%}$ random copolymer of vinylidene fluoride and trifluoroethylene were performed at 9.14 MHz and 20.0 MHz. The free induction decays (FIDs) were analysed in terms of two T₂ components attributed to the amorphous and crystalline portions of the polymer. The changes in crystallinity as well as the effects of the ferroelectric transition were observed during cycles of heating and cooling between 20°C and 140°C. The crystalline component of the FID lengthens by a factor of 2 at 100°C on heating and decreases by this factor at 60°C on cooling, thus exhibiting the thermal hysteresis of this ferroelectric transition. The spin-lattice relaxation was also investigated. From measurements at 9.14 MHz the observed longitudinal relaxation time T₁ appears to be dominated by the dynamics of the amorphous phase and exhibits no anomaly through the phase transition. However, from measurements at 20 MHz, well defined minima of T₁ were observed, which are associated with the ferroelectric transition (especially after repeated annealing of the samples). Results are discussed in terms of the crystalline phase structure, which appears dynamically disordered above the ferroelectric phase transition. An analogy is considered with the plastic phase transitions encountered in molecular crystals.     

Means of enhancing and promoting the use of solar energy

The development of renewable technologies in the last decade has been exceptional. In photovoltaic (PV) for example, efforts were not only limited to merely improving their efficiency but also to the reduction of the cost of cells and modules via volume production for commercial markets. There are many national schemes promoting the use of PV technology and regional targets for a share of renewable energy production. This paper attempts to relay to the reader a journey, based on experience, approaches for enhancing the prospect of utilising solar energy within the society we live in. The issue of expansion or enhancing the utilisation of solar energy can be undertaken by individuals, groups, institutions and governments. The aim of this paper is to provide some examples, which could serve as a framework in which action could be taken to promote solar technology.     

太阳能热管的研制和应用

介绍了太阳能热管发展的社会背景和历史沿革、太阳能热管单管的工质选择和管壳结构、热管式真空集热管的结构特点及太阳能热管在热水器中的应用     

Analyses of the practical adhesion strengths of the metal/polymer interfaces in electronic packaging

There is a plethora of techniques to measure the adhesion strength of metal/polymer interfaces. However, the practical adhesion strength, which is the work done in separating the film from the substrate (or one film from another), is very sensitive to the test methods and the mechanical effects, such as the residual stress, thickness and mechanical properties of the layers, strain rate, and phase angle. Deriving intrinsic-adhesion properties of the interfaces, which are independent of such parameters, from the practical adhesion-strength measurements is a formidable task. In the present work, data from the three commonly used adhesion tests; pull-out, 90°-peel, and T-peel tests are compared with the intrinsic-adhesion properties of the interface, such as the interface-fracture toughness or the interface-fracture energy, and their implications are discussed. Material systems analyzed were Cu-based lead frame/epoxy-molding compound (EMC) and Cu/Cr/polyimide.     

码头建筑物对水位影响的模型试验及计算方法

河岸码头建筑物势必导致其上游水位壅高及对码头附近水流流态产生影响。以汉江沙洋河段为对象 ,通过定床概化物理模型试验研究了码头建筑物对河道水位与流速场的影响。并基于能量平衡原理 ,采用河道恒定非均匀流水面曲线基本方程 ,结合物理模型试验资料 ,计算了码头建筑物附近的水位变化值 ,并提出了码头建筑物产生的水位壅高值的计算方法。     

反向阳光间被动式太阳能空气采暖系统

介绍一种多层建筑中反向阳光间被动式太阳能空气采暖系统。它通过置于屋顶和地面的风管实现公寓中南部阳光间的太阳能得热向北部阳光间的自然传递。南部阳光间受热的空气上升，进入置于屋顶的风管，并通过这些风管流向北部阳光间；同时，南部阳光间置换出的空气被由北部阳光间的通过置于地面风管流向南部阳光间的较冷的空气所代替。由于系统还可用于东西阳光间之间，建筑物不受相对于太阳朝向的限制。     

Local wind patterns for modeling renewable energy systems by means of cluster analysis techniques

A method based on cluster analysis techniques is proposed in order to obtain representative local wind patterns. Modeling renewable energy systems, in an accurate way which strongly depends on wind loads, requires reliable data to analyze their response and evaluate their performance. Otherwise poor agreement with the models may be obtained. In a case study for La Paz, Baja California Sur, Mexico, four different wind patterns were obtained from a one-year data set recorded at 10-min intervals.     

地源热泵的地热能利用方式与工程运用

地源热泵是一种新型的高效、节能、环保的空调系统 ,是我国调整能源利用结构 ,发展利用可再生能源策略的重点推广项目之一。本文介绍了地源热泵的工作原理及四种地热能利用方式。根据笔者的设计经验 ,为地源热泵空调系统的工程设计和推广应用提供了一些设计参数和参考意见     

长庆上古生界气层CO2增能压裂工艺

长庆上古气藏物性差,压力系数低,水锁伤害大,采用常规水力压裂,入井液返排困难,气井产量低。在储层改造地质研究的基础上,通过对CO2泡沫压裂技术进行室内攻关,引进开发了CO2泡沫压裂酸性交联技术,优化了CO2泡沫方案设计及现场施工工艺,配套了CO2增能压裂工艺技术。经过现场应用,充分说明了CO2增能压裂是一项行之有效的工艺技术,对于提高单井产量和长庆气田整体开发水平都是有益的。