Effect of chloride ions on immersion plating of copper onto porous silicon from a methanol solution

The effect of chloride ions (Cl⁻) during the immersion plating of copper onto porous silicon (PS) from a methanol (MeOH) solution has been studied. The presence of Cl⁻ in the Cu²⁺ solution was found to slow down the rate of copper deposition, as confirmed by inductively coupled argon plasma emission spectroscopy and X-ray photoelectron spectroscopy measurements. The threshold concentration of Cl⁻ at which the deposition of copper is very severely diminished was found to be 0.1 M. The inhibition effect is discussed on the basis of the rest potential values of PS and polarization curve measurements. They revealed that the rest potential of PS upon dipping in these solutions appears to direct the metal deposition. Current density-potential curves show that at Cl⁻ concentrations higher than 0.1 M, the reduction of Cu ions proceeds in two steps; the reduction of Cu(II) to Cu(I) followed by the reduction of Cu(I) to Cu(0). This suggests that Cu(I) species in MeOH solution can be stable over a certain potential range and this stability of Cu(I) is responsible for the inhibition of metal deposition. Fourier transform infrared spectroscopy and scanning electron microscopy (SEM) were also performed to investigate the structural changes and characterizations of PS samples after the plating process.     

The relationship between denitrifying bacteria and methanogenic bacteria in a mixed culture system of acclimated sludges

The interaction between denitrification and methanogenesis, with methanol functioning as an electron donor, has been examined through usage of a mixed culture system of denitrifying sludge and methanogenic sludge in an anaerobic bioreactor. Competition for methanol between these two kinds of biocommunity could not be observed, whereas methanogenesis was suppressed as long as nitrate and nitrite were made available in the mixed system. The inhibition of methanogenesis in the methanogenic sludge caused by nitrogen oxides was studied. The redox potential (E_h) of the culture was monitored and/or controlled for the sake of characterizing the behavior of the biocommunities. An addition of nitrite elevated the E_h of the culture less than nitrate did. Nitrite addition, however, exerted a stronger inhibitory effect on methanogenesis as compared to nitrate at the same concentration. The influence of redox potential on the methanation of methanol was examined by using a methanogenic sludge in the E_h-stat batch culture. The hypothesis that the inhibitory effect being expressed by the nitrogen oxides is not simply attributed to an elevation of the redox potential of the culture is supported by the experimental results. The toxic effect of the nitrogen oxides themselves could also have possibly contributed significantly.     

升平气田产能预测方法

依据升平气田的试井资料，建立了气井产能与压差之间的二次项产能方程。运用此方程可以预测升平气田的单井产能，并且建立了压差平方与kh值相关的气田综合产能方程。当求得气田的平均kh值后，利用该方法可以求得气田的平均产能或生产压差。     

瓶组气化站的建筑、结构设计要点

瓶组气化站的建筑，结构设计关系到安全，满足使用要求和投资的大小，本文根据多年的实践和最新的有关设计规范的要求，阐述瓶组气化站建筑，结构设计的要点。     

柴达木盆地北缘侏罗系烃源岩干酪根13C核磁共振研究

柴达木盆地北缘是柴达木盆地三大油气区之一,其源岩为早、中侏罗世煤系地层.烃源岩有机质类型以Ⅲ₁型和Ⅱ型干酪根为主,Ⅰ₂型干酪根仅在局部地区有分布.通过对柴达木盆地北缘侏罗系烃源岩中不同类型干酪根的¹³C核磁共振研究,指出了研究区Ⅰ₂、Ⅱ、Ⅲ₁型干酪根的化学结构特征以及化学结构中“芳构碳”、“油潜力碳”与“气潜力碳”的相对含量,据此从定量分析的角度对不同类型干酪根的生油气贡献作了评价.Ⅰ₂、Ⅱ、Ⅲ₁型干酪根的生烃能力依次减弱,对生油的贡献也依次减弱,且生成油气的比例不同,Ⅰ₂、Ⅱ型干酪根以生油为主,Ⅲ₁型干酪根则以生气为主.     

The intervalley X6→Γ6, L6 scattering time in GaAs measured by ultrafast pump-probe infrared absorption spectroscopy

A direct measurement of the dynamics of electrons in the X₆ valley for a GaAs crystal by time-resolved absorption spectroscopy is reported for the first time. IR picosecond probe pulses were used to monitor the growth and decay of the population in the X₆ valley subsequent to excitation by a 527 nm pump pulse. The intervalley X₆→Γ₆, L₆ scattering time t_x of 0.70 ± 0.50 ps is determined and the crossection for the X₆→X₇ transition is estimated to be 1.8 × 10⁻¹⁶ cm².     

Evaluation of different coating systems by electrochemical methods

Corrosion protection of organic coated steel is determined by free corrosion potential measurements and impedance spectroscopy. The results are classified by means of very basic considerations and evaluation figures are developed. These electrochemical data are correlated with the extent of the corrosion for each coating system. The evaluation figures are used for ranking coating systems and this ranking is correlated with the ranking with reference to the results of standardized and exposure tests.     

基于人工势场方法的WSN传感覆盖率提高算法

感覆盖率是WSN系统中重要的性能指标之一。Sink节点的移动性能提高系统的传感覆盖率,人工势场能描述普通节点与Sink节点之间的关系。提出了一种利用人工势场方法有效的Sink节点移动控制策略,通过Sink节点的移动能够提高系统的传感覆盖率。普通节点搜集的数据能通过多跳的方式传送给Sink节点。在最初的随机部署之后,由人工势场产生的力迫使移动Sink节点移动到整个环境中的平衡点以获得更高的传感覆盖率。在整个算法执行过程中无需事先了解环境的情况,此方法能在实时的环境中采用。给出了具体的算法步骤,最后利用一个仿真实例对控制效果进行了说明。     

裂纹对石墨烯拉伸力学性能影响的数值仿真

为研究裂纹对石墨烯力学性能的影响,以锯齿型石墨烯为研究对象,基于分子动力学方法,采用Tersoff势函数分析裂纹长度对石墨烯拉伸力学性能的影响以及含有裂纹的石墨烯在不同应变率下的拉伸变形破坏过程.结果表明,裂纹长度的增加大大减小石墨烯的抗拉强度和抗拉应变,对弹性模量有一定影响;裂纹降低石墨烯的抗拉应变对应变率的敏感性,但对于含有裂纹的石墨烯,仍可以增大加载速率来提高石墨烯的抗拉性能.     

降膜蒸发过程的数值模拟和传热传质分析

利用CFD软件对逆流降膜蒸发过程进行了实验模拟研究,研究了速度边界层、热边界层和浓度边界层的变化对降膜蒸发传热传质特性的影响规律;通过建立一维逆流降膜蒸发的数学方程编程求解出了对流传热传质的Nu数和Sh数,利用Fluent软件模拟出的实验结果采用回归分析得出了气液流量比Raw、流道的长宽比αL、空气进口无量纲温度θai以及空气进口Re数与Nu数、Sh数之间的无量纲关系式,可为降膜蒸发换热器的设计提供参考。