Continuous precipitation of calcium sulfate dihydrate from waste sulfuric acid and lime

Precipitation of calcium sulfate dihydrate, gypsum, from (i) a pure sulfuric acid/lime suspension and (ii) a waste sulfuric acid/lime suspension in a continuous pilot plant in the temperature range from 40 °C to 80 °C was studied. It was observed that in the case of waste sulfuric acid with a high content of Mg²⁺ and Fe²⁺ ions, several hours after the beginning of the precipitation, partial dissolution of the product and modification of the crystals from needle‐ and plate‐like to agglomerated structures occurred. It is suggested that the secondary changes occur due to the increased concentration of Mg²⁺ and Fe²⁺ ions in the reactor. Below 60 °C, and above 70 °C plate‐like and needle‐like single crystals respectively were formed. The mean size (d₅₀) of the crystals was found to increase with increasing temperature and decrease with the initial concentration of lime. Gypsum produced between 70 °C and 80 °C is suitable for further processing for construction plaster. In a precipitation process with pure sulfuric acid only single perfect needle‐like crystals occurred. Copyright © 2005 Society of Chemical Industry     

Diversity training in graduate school: An exploratory evaluation of the Safe Zone project.

How can psychologists and graduate students become more affirmative of lesbian, gay, bisexual, and transgender (LGBT) issues? Safe Zone is a diversity-training program to increase sensitivity toward, knowledge of, and advocacy for LGBT populations and issues that affect them. In this exploratory study, the implementation of Safe Zone is described within a school of professional psychology; its effectiveness was assessed by self-reported behavioral and attitudinal changes and from participant evaluations. Results were encouraging with regard to the goals of Safe Zone and its adaptation to institutions interested in improving relations with the LGBT community, but additional empirical studies are needed. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

真空相变锅炉低排烟温度设计与低温腐蚀

真空相变锅炉是否会明显发生烟气低温腐蚀，一直众说不一。文章从锅炉发生低温腐蚀的机理人手，通过理论分析计算并通过实践检验，提出了真空相变锅炉虽然不能完全避免低温腐蚀问题，但不论排烟温度是否高于烟气露点，低温腐蚀的程度都很弱的观点；给出了真空相变锅炉沿烟气流程金属壁面的腐蚀速度与壁面温度的关系曲线，和烟气温度低于酸露点时金属壁面的腐蚀速度与壁面温度的关系曲线；同时，文章推荐真空相变锅炉的设计排烟温度取130℃左右的低排烟温度。根据上述观点设计的数百台产品已经过多年实际运行，未发现明显     

Effect of sampling density on the measurement of stream condition indicators in two lowland Australian streams

There is widespread application of indicators to the assessment of environmental condition of streams. These indicators are intended for use by managers in making various comparative and absolute assessments and often have a role in resource allocation and performance assessment. Therefore, the problem of formally defining confidence in the results is important but difficult because the sampling strategies used are commonly based on a compromise between the requirements of statistical rigour and the pragmatic issues of access and resources. It is rare to see this compromise explicitly considered and consequently there is seldom quantification of the uncertainty that could affect the confidence a manager has in an indicator. In this paper, we present a method for quantitatively assessing the tradeoffs between sampling density and uncertainty in meeting various monitoring objectives. Assessments using judgement‐based representative reaches are shown to be unreliable; instead a sampling approach is recommended based on the random selection of measuring sites. A detailed dataset was collected along two streams in Victoria, Australia, and the effect of sampling density was assessed by subsampling from this dataset with precision related to the number of sites assessed per reach length and the intensity of the sampling at each site. The sampling scheme to achieve a given precision is shown to depend on the monitoring objective. In particular, three objectives were considered: (1) making a baseline assessment of current condition; (2) change detection; and (3) detection of a critical threshold in condition. Change detection is shown to be more demanding than assessing baseline condition with additional sampling effort required to achieve the same precision. Sampling to detect a critical threshold depends on nominating acceptable values of Type I and II error and the size of the effect to be detected. Copyright © 2006 John Wiley & Sons, Ltd.     

In‐Situ Observation of the Formation of MnS during Solidification of High Sulphur Steels

A Confocal Scanning Laser Microscope equipped with a gold image furnace was used to directly observe the precipitation of MnS during solidification of high sulphur steels under isothermal conditions in the temperature region 1440 to 1480°C on the free surface of the steel melt. For the case of Al‐killed steels, below 1480°C MnS particles were found to precipitate with Fe forming simultaneously around them. This MnS containing structure continued to grow rapidly (264 μm/s) as a surface film. The film gradually changed, as the level of S in the melt decreased, into a eutectic structure (with lamella spacing of 2 μm) as predicted by thermodynamics. In Si‐ killed steels there was significantly lower tendency to form MnS both in terms of time until precipitation occurred and growth rate.     

种分Δαk与种分首槽αk的关系

针对烧结法和拜尔法种分槽的 Δαk 变化进行了概述 ,阐述了种分 Δαk 与种分首槽 αk 的关系。     

Threshold and growth mechanism of fatigue cracks under mode II and III loadings

ABSTRACT The fatigue crack growth behaviour of 0.47% carbon steel was studied under mode II and III loadings. Mode II fatigue crack growth tests were carried out using specially designed double cantilever (DC) type specimens in order to measure the mode II threshold stress intensity factor range, ΔK_IIth. The relationship ΔK_IIth > ΔK_Ith caused crack branching from mode II to I after a crack reached the mode II threshold. Torsion fatigue tests on circumferentially cracked specimens were carried out to study the mechanisms of both mode III crack growth and of the formation of the factory‐roof crack surface morphology. A change in microstructure occurred at a crack tip during crack growth in both mode II and mode III shear cracks. It is presumed that the crack growth mechanisms in mode II and in mode III are essentially the same. Detailed fractographic investigation showed that factory‐roofs were formed by crack branching into mode I. Crack branching started from small semi‐elliptical cracks nucleated by shear at the tip of the original circumferential crack.     

Review of Emotion-focused therapy: Coaching clients to work through their feelings.

Reviews the book, Emotion-focused therapy: Coaching clients to work through their feelings by Leslie S. Greenberg (see record 2002-00066-000). This book was written for both novice therapists who have had little experience working with emotions in treatment, as well as for experienced therapists looking to systematize their understanding of how emotional change works. The book is divided into four parts. Part I examines the nature and function of emotions. Part II examines the first part of emotional coaching--arriving at emotion. Part III examines the second part of emotional coaching--leaving emotion. Finally, Part IV examines the application of emotion-focused therapy to the problems of living, in the context of individuals, couples therapy, and parenting. This book offers a wealth of therapeutic techniques and theoretical principles about the process of change. As such, it is an important and natural companion to seminal works in cognitive behaviour therapy and interpersonal therapy. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

The Israeli-Palestinian peace process and its vicissitudes: Insights from attitude theory.

The vicissitudes of the Israeli-Palestinian peace process since 1967 are analyzed using attitudes and related concepts where relevant. The 1967 war returned the two peoples' zero-sum conflict around national identity to its origin as a conflict within the land both peoples claim. Gradually, new attitudes evolved regarding the necessity and possibility of negotiations toward a two-state solution based on mutual recognition, which became the building stones of the 1993 Oslo agreement. Lacking a commitment to a final outcome, the Oslo-based peace process was hampered by reserve options, which increased avoidance at the expense of approach tendencies as the parties moved toward a final agreement. The resulting breakdown of the process in 2000 produced clashing narratives, reflecting different anchors for judgment and classical mirror images. Public support for violence increased, even as public opinion continued to favor a negotiated two-state solution. Reviving the peace process requires mutual reassurance about the availability of a partner for negotiating a principled peace based on a historic compromise that meets the basic needs and validates the identities of both peoples. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Plasma Sprayed Hydroxyapatite Coatings with Nano-hydroxyapatite Prepared by Ultrasonic Precipitation Process

Nano-particle hydroxyapatite （ HA ） was prepared with a novel ultrasonic precipitation process and the as-prepared nanopowder was used to produce hydroxyapatite （ HA ） coatings on titanium substrate via plasma spraying. The phase and the microstructare of the coating were characterized by X- ray diffraction （XRD） and scanning electron microscopy （SEM）. Results showed that spherical particles could be prepared by ultrasonic precipitation process; and a corresponding dense HA coating with molten surface and low-porosity cross-section structure was acquired. During the plasma spraying process, new phases of Ca3 （ PO4 ）2 and Ca2 P2O7 were generated. After heat-treating at 800℃ for 1 h, the contents of Ca3 （ PO4 ）2 and Ca2 P2O7 decreased while HA content increased. Tensile adhesion tests showed that the plasma sprayed coating prepared with the spherical nanoparticles exhibited high tensile bond strength.