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101.
102.
Cu—Zn—Cr合金的时效特性 总被引:5,自引:0,他引:5
研究了不同时效工艺对Cu-Zn-Cr合金的力学性能、电学性能及其显微组织的影响。结果表明:固溶-冷变形后合金的时效过程由过饱和固溶体的析出过程和基体的再结晶两个过程控制;合金高强度主要来源于加工硬化和第二相铬粒子的析出强化,合金的高导电性则主要来源于贫化后成份接近于铜锌固溶体的基体。 相似文献
103.
Ying Chen Shuichi Iwata Tetsuo Mohri 《稀有金属(英文版)》2006,25(5):437-440
Theoretical investigation of the phase equilibria of the Fe-Ni alloy has been performed by combining the FLAPW total energy calculations and the Cluster Variation Method through the Cluster Expansion Method. The calculations have proved the stabilization of the LIE phase at 1:3 stoichiometry, which is in agreement with the experimental result, and predicted the existence of L1 0 as a stable phase below 550 K; this L1 0 phase has been missing in the conventional phase diagram. The calculations are extended to the Fe-rich region that is characterized by a wide range phase separation and has drawn considerable attention because of the intriguing Invar property associated with a Fe concentration of 65%. To reveal the origin of the phase separation, a P-V curve in an entire concentration range is derived by the second derivative of free energy functional of the disordered phase with respect to the volume. The calculation confirmed that the phase separation is caused by the breakdown of the mechanical-stability criterion. The newly calculated phase separation line combined with the L1 0 and L12Eorder-disordered phase boundaries provides phase equilibria in the wider concentration range of the system. Furthermore, a coefficient of thermal expansion (CTE) is attempted by incorporating the thermal vibration effect through harmonic approximation of the Debye-Gruneisen model. The Invar behavior has been reproduced, and the origin of this anomalous volume change has been discussed. 相似文献
104.
纳米W-Cu粉末的均相沉淀法制备及其烧结性能 总被引:5,自引:0,他引:5
采用湿化学工艺--蒸氨均相沉淀法,制备了纳米CuWO4·2H2O/Cu2WO4(OH)2均相沉淀物,然后煅烧、还原,得到含Cu 30%的W-Cu复合粉.将该复合粉压坯在H2气氛中于不同温度下烧结后,对烧结体的微结构和物理、力学性能等进行了测试分析.实验结果表明:蒸氨均相沉淀法制备的W-Cu复合粉体具有纳米粒度和均匀的化学组成,其烧结活性高,在较低温度下烧结即可达很高的致密化程度.由上述W-Cu粉体所制备的烧结体具有良好的物理、力学性能. 相似文献
105.
针对酸性氯化物中黄铁矿还原浸出锰结核的溶液成分特点,选择黄钠铁矾法进行了沉淀分离铁的研究。结果表明温度和晶种以及溶液pH值是影响铁矾沉淀的重要因素。在pH2.0左右,溶液温度高于90℃,足量晶种加入的情形下,150min后可将溶液中的铁含量降至0.1g/L。沉矾过程的表观活化能为94.66kJ/mol。黄铁矿氧化生成的硫酸根随铁一同沉淀,从而消除了SO2-4在氯化物体系中的积累。 相似文献
106.
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108.
J. R. Clearwater S. P. Foster S. J. Muggleston J. S. Dugdale E. Priesner 《Journal of chemical ecology》1991,17(2):413-429
The specific status ofCtenopseustis obliquana pheromone-types I, II, and III has been more fully examined. Females of types I and III produce a mixture of (Z)-8- and (Z)-5-tetradecenyl acetates (Z8-14:Ac, Z5-14: Ac). The previously reported different ratios of these two components in females of the two types (type I=8020, III=9010) have been reinvestigated. The median ratios of each type differed significantly, although there was some overlap in the ranges of these ratios. A field cage trial showed that males of type III are attracted to females of type I, so the observed differences may be ascribed to intraspecific variation. In contrast to females of types I or III, females of type II produce Z5-14Ac but no Z8-14Ac. The electroantennogram (EAG) profile of antennae of type II males shows a maximum response to Z5-14Ac, while the EAG profiles of types I and III show a strong response to Z8-14Ac. In wind tunnel tests using mixtures of these two compounds, type II males prefer blends consisting of all or mostly Z5-14: Ac, while type I males showed a preference to a mix of 70% Z8-14Ac plus 30% Z5-14Ac. We found that type I males are attracted to type I females when offered a choice between type I and type II females in a field cage test and that type II males similarly prefer type II females. Males of types I and II have specialist cells for Z8-14Ac and Z5-14Ac but differ with respect to relative densities of these cells and to further cell types responsive to other alkenyl acetates. Type IIC. obliquana is considered therefore a sibling species of types I and III. In addition, the amount of Z5-14Ac produced by type II females varied geographically. Females from the North Island produced significantly less (median=1.2 ng) Z5-14Ac than females from the South Island (median=2.2 ng). Type II populations in the North Island morphologically resembled sympatric type I, rather than type II from the South Island and are designated as type II (North Island). Type II (North Island) populations have so far been found only at Rukuhia (near Hamilton) and from Kerikeri. In contrast, type II populations are sympatric with type III populations over much of the South Island. In a field cage trial, males of types II and II (North Island) were attracted to females of both II and II (North Island). We tentatively ascribe the differences between type II and type II (North Island) to intraspecific variation. 相似文献
109.
110.