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101.
102.
Xinhua Wang Changyao Wang Changpin Chen Qidong Wang 《Journal of Alloys and Compounds》2006,420(1-2):107-110
In this paper, we deduced an empirical equation for predicting the stabilities of the hydrides of AB5-type compounds with the consideration of the effects of geometrical factor and electric factor. The theoretical curves derived from this equation are in good agreement with the test results of La1−xCaxNi5, Ml1−xCaxNi5 and La1−xCexNi5 compounds. With this model, we can easily interpret the phenomenon that the initial partial substitution of R by Ca in R1−xCaxNi5 (R is rare earth metal) compounds cause an increase of hydrogen desorption pressure to a maximum value, whereas in the range of larger Ca content x the hydrogen desorption pressure decreases with increasing x. 相似文献
103.
通过选用透明度高、太阳能吸收率高的丙烯酸树脂和高亮度、长余辉时间的镝和铕稀土离子共掺杂的稀土硅酸盐光致发光粉末材料aCaO·bZnO·cBaO·dMgO·nSiO2:Eu,Dy,制备出了具有较强的蓄光能力和较长发光时间的夜光涂料,并论述了其制备方法和特性。 相似文献
104.
High‐density polyethylene (HDPE) beads were successfully surface‐crosslinked in a modified plasma reactor. The modified plasma reactor treats large amounts of beads, which are uniformly surface‐crosslinked. In this study, effects of the gas pressure, radio‐frequency (RF) power, and the treatment time on the degree of surface crosslinking were systematically investigated. Degree of surface crosslinking was measured by solvent extraction method (boiling xylene method, BXM). The gel content of plasma‐treated HDPE increases from 0.0 to 1.05% within 10 min at 100 mTorr, 200 W. FTIR and DSC analyses show that the crosslinked layer after plasma treatment is limited only at HDPE surface without changing the bulk thermal property of HDPE. Through the analysis of FTIR, it was confirmed that main peaks corresponding to CH2 bands were decreased and two peaks corresponding to CF2 and CF3 were observed after plasma surface modification. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 2921–2929, 2002; DOI 10.1002/app.10295 相似文献
105.
通过X射线衍射谱(XRD)、气态吸放氢行为(PCT曲线)、电化学充放电性能、电化学阻抗谱(EIS),考察了Ni添加对Ti_(0.47)V_(0.28)Mn_(0.15)Cr_(0.1)储氢合金的电化学性能的影响。结果表明:Ti_(0.47)V_(0.28)Mn_(0.15)Cr_(0.1)的电化学活性很差,在碱液中几乎不能放电,添加Ni之后得到了明显改善。随着Ni含量的增加,Ti_(0.47)V_(0.28)Mn_(0.15)Cr_(0.1)Ni_x(x=0~0.25)合金电极的放电容量先增大后减小,在x=0.15时达到最大值310mA·h·g~(-1)。 相似文献
106.
Soybean oil (900 g) was heated by deep frying at 200°C for 1 h with the addition of 0, 50, 100, 150 and 200 mL water, and
then stored at 55°C for 26 weeks. Soybean oil, corn oil and lard were heated by stir frying and then stored at 55°C for 30
weeks. The volatiles and peroxide values of these samples were monitored. All samples contained aldehydes as major volatiles.
During heating and storage, total volatiles increased 260-1100-fold. However, aldehyde content decreased from 62–87% to 47–67%,
while volatile acid content increased from 1–6% to 12–33%; especially hexanoic acid which increased to 26–350 ppm in the oils
after the storage period was completed. Water addition to the oils heated by deep frying tended to retard the formation of
volatile compounds. The total amount of volatile constituents of lard heated by stir frying increased more during storage
than that of corn oil or soybean oil. Peroxide values did not reflect the changes of volatile content in the samples. 相似文献
107.
Faliang Zhang Yongchun Luo Anqiang Deng Zhaohui Tang Long Kang Jianhong Chen 《Electrochimica acta》2006,52(1):24-32
(La, Ce, Pr, Nd)2MgNi9 hydrogen storage alloys were prepared through induction melting followed by a long annealing treatment. The structure and electrochemical properties of annealed alloys have been investigated by orthogonal design experiments. Both the individual effects of each substituting element and their interaction in alloys were studied systemically. It has been shown that the structure of main phase in alloys belongs to PuNi3-type with a space group R-3m. Substituting rare-earth elements have a significant effect on both the phase structure of alloys and microstructure. The anisotropic change in the crystal structure of alloys can cause the acceleration of pulverization of alloy particles and result in the deterioration of the cyclic stability of alloy electrodes. Misch metals can raise the plateau pressure of hydrogen absorption/desorption. The discharge capacity of alloy ranges from 342.97 to 380.68 mAh g−1 depending on the sort and content of substituting elements. Both cerium and neodymium can obviously reduce the discharge capacity of alloy electrodes. When compared to the La2MgNi9 alloy electrode, mish metals can significantly improve the high rate dischargeability of alloy electrodes. The improvement of the kinetic characteristic of alloy electrodes mainly results from the increase of the hydrogen diffusion rate in alloy bulk. 相似文献
108.
109.
Isothermal storage of NO2 and subsequent reduction with different reducing agents (H2, CO or H2 + CO) in a lean NO
x
trap catalyst was tested by Temperature Programmed Desorption (TPD) and Temperature Programmed Reduction (TPR) experiments
at temperatures representative of automotive “cold-start” conditions (<200 °C) using a commercial NO
x
trap catalyst.
Results from the TPR experiments revealed that no reduction of stored NO2 to N2 was observed at 100–180 °C, and at 200 °C 10% reduction only of NO2 to N2 was measured.
A special affinity of H2 to form NH3 was observed during the reduction of stored NO2. The formation of NH3 increases with increasing amount of stored NO2 and decreases with increasing storage temperature. Direct relation exists between the amount of adsorbed and/or stored NO2 and the formation of H2O and NH3. 相似文献
110.