全文获取类型
收费全文 | 44610篇 |
免费 | 3380篇 |
国内免费 | 2143篇 |
专业分类
电工技术 | 2139篇 |
技术理论 | 2篇 |
综合类 | 3301篇 |
化学工业 | 9522篇 |
金属工艺 | 3182篇 |
机械仪表 | 2628篇 |
建筑科学 | 5266篇 |
矿业工程 | 2176篇 |
能源动力 | 1790篇 |
轻工业 | 2865篇 |
水利工程 | 903篇 |
石油天然气 | 1401篇 |
武器工业 | 754篇 |
无线电 | 2275篇 |
一般工业技术 | 7082篇 |
冶金工业 | 3197篇 |
原子能技术 | 477篇 |
自动化技术 | 1173篇 |
出版年
2024年 | 196篇 |
2023年 | 547篇 |
2022年 | 1140篇 |
2021年 | 1417篇 |
2020年 | 1375篇 |
2019年 | 1040篇 |
2018年 | 1017篇 |
2017年 | 1335篇 |
2016年 | 1389篇 |
2015年 | 1334篇 |
2014年 | 2339篇 |
2013年 | 2289篇 |
2012年 | 2763篇 |
2011年 | 3064篇 |
2010年 | 2427篇 |
2009年 | 2701篇 |
2008年 | 2226篇 |
2007年 | 3255篇 |
2006年 | 2917篇 |
2005年 | 2665篇 |
2004年 | 2173篇 |
2003年 | 2019篇 |
2002年 | 1684篇 |
2001年 | 1376篇 |
2000年 | 1174篇 |
1999年 | 932篇 |
1998年 | 702篇 |
1997年 | 573篇 |
1996年 | 491篇 |
1995年 | 392篇 |
1994年 | 347篇 |
1993年 | 244篇 |
1992年 | 144篇 |
1991年 | 106篇 |
1990年 | 79篇 |
1989年 | 80篇 |
1988年 | 57篇 |
1987年 | 22篇 |
1986年 | 13篇 |
1985年 | 16篇 |
1984年 | 6篇 |
1983年 | 9篇 |
1982年 | 7篇 |
1981年 | 5篇 |
1980年 | 5篇 |
1963年 | 3篇 |
1959年 | 4篇 |
1956年 | 3篇 |
1955年 | 4篇 |
1951年 | 6篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
91.
A series of polyurethane microcapsules containing a phase change material (PCM) of n‐octadecane was successfully synthesized by an interfacial polymerization in aqueous styrene‐maleic anhydride (SMA) dispersion with diethylene triamine (DETA) as a chain extender reacting with toluene‐2,4‐diisocyanate (TDI). The average diameter of microPCMs is in the range of 5–10 μm under the stirring speed of 3000–4000 rpm. Optical and SEM morphologies of microPCMs had ensured that the shell was regularly fabricated with the influence of SMA. FTIR results confirmed that the shell material was polyurethane and the SMA chains associated on core material reacted with TDI forming a part of shell material. The shell thickness was decreasing in the range of 0.31–0.55 μm with the molar ratio of DETA/TDI from 0.84 to 1.35 and the weight of core material increasing from 40 to 80% (wt %). By controlling the weight ratio of PCM as 40, 50, 60, 70, and 80% in microPCMs, it was found using DSC that the Tm and Tc of microPCMs were in the range of 29.8–31.0oC and 21.1–22.0°C and an obvious phase change had been achieved nearly the same temperature range of that of PCM. The results from release curves of microPCM samples prepared by 1.4, 1.7, and 2.0 g of SMA indicated the release properties were affected by the amount of the dispersant, which attributed to the emulsion effect and shell polymerization structure. The above results suggest that the shell structure of microPCMs can be controlled and the properties of microPCMs determined by shell will perform proper practical usage. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 4996–5006, 2006 相似文献
92.
93.
Pressure‐sensitive adhesives (PSAs) have long been a problem as sticky contaminants for paper recycling mills. The main problem associated with such stickies is that the PSAs in the waste papers deposit on the felts, press rolls, and drying cylinders of paper machines, and this creates problems with paper formation, reducing the paper quality and paper machine runnability. The annual cost of stickies to the U.S. paper industry is estimated to be about $600,000,000–650,000,000. To solve this problem, a series of cationic water‐soluble/dispersible PSAs have been synthesized by the free‐radical solution polymerization of butyl acrylate and [3‐(methacryloylamino)propyl]trimethylammonium chloride in ethanol. The PSA end‐use properties, repulpability in paper recycling, and the effects on the properties of recycled paper products have been studied. The cationic PSAs can be dissolved or dispersed in water if the cationic charge density in the PSA backbone is controlled, and so they do not deposit as stickies during recycling and papermaking processes. Because the PSAs are cationically charged, they can easily be removed from the papermaking system by adsorption onto the negatively charged fibers and fine surfaces. Furthermore, the adsorbed colloidal or dissolved PSAs have little effect on the final paper properties. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 1624–1630, 2003 相似文献
94.
95.
张万贞 《石油化工腐蚀与防护》2006,23(3):22-25
介绍了在湿H2S环境中金属材料的腐蚀试验标准、方法和手段并重点强调了在H2S试验过程中常遇到的一些问题的处理方法.最后,指出了应加强H2S腐蚀的基础性和系统性研究的研究方向. 相似文献
96.
用屏蔽暂堵技术封堵水平井裂缝性漏层 总被引:1,自引:1,他引:0
克拉玛依油田HW702水平井的大斜度段和水平段,将穿越纵向裂缝发育的二叠系佳木河组储层。为安全钻进和保护油层,用超细碳酸钙和磺化沥青复配后加入复合离子钻井液中成屏蔽暂堵的堵漏钻井液。室内用岩心试验,屏蔽暂堵后渗透率可降为0,暂堵深度小于3cm,可用酸化和射孔解堵。现场使用效果也很好,使HW702水平井顺利完钻,并获得工业油气流。 相似文献
97.
反应烧结法制备MgAlON的合成机理及烧结行为的研究 总被引:2,自引:1,他引:1
通过对以Al2 O3、MgO和AlN为起始原料 ,在氮气气氛中反应烧结合成MgAlON材料合成机理的研究发现 :在 12 0 0℃以前 ,MgO与Al2 O3反应生成镁铝尖晶石 ,此后 ,随着温度的升高 ,Al2O3不断向所形成的尖晶石中固溶 ;在 130 0℃以前 ,AlN基本上不参与反应 ,而在更高的温度下 ,AlN开始向尖晶石中固溶形成MgAlON ,约在 15 5 0℃时形成单一的MgAlON相。用热膨胀仪检测了试样的线变化率随温度和时间的变化 ,用最小二乘法回归分析了试样线变化率的实验数据 ,并根据烧结理论对MgAlON材料烧结初期的动力学进行了探讨。结果表明 ,MgAlON材料烧结初期的烧结机理以体积扩散为主 相似文献
98.
99.
WANG Jiqing 《声学技术》2004,23(Z3)
This paper gives an overview of the research at Institute of Acoustics, Tongji University, on functional absorbers and experience acquired in practical applications over the past three decades. Experiments and analysis of the absorption characteristics of three different geometrical forms of functional absorbers, i.e., panels, cubes and tubes, were conducted with different arrangements. The resulting esthetical effects are illustrated with pictures. Several non-fiber materials are used to compose functional absorbers with advantages both in acoustic properties and in architectural features. Cost effectiveness analysis is also given in order to provide design guidelines. 相似文献
100.
A new interaction integral formulation is developed for evaluating the elastic T-stress for mixed-mode crack problems with
arbitrarily oriented straight or curved cracks in orthotropic nonhomogeneous materials. The development includes both the
Lekhnitskii and Stroh formalisms. The former is physical and relatively simple, and the latter is mathematically elegant.
The gradation of orthotropic material properties is integrated into the element stiffness matrix using a “generalized isoparametric
formulation” and (special) graded elements. The specific types of material gradation considered include exponential and hyperbolic-tangent
functions, but micromechanics models can also be considered within the scope of the present formulation. This paper investigates
several fracture problems to validate the proposed method and also provides numerical solutions, which can be used as benchmark
results (e.g. investigation of fracture specimens). The accuracy of results is verified by comparison with analytical solutions. 相似文献