稀土掺杂红色长余辉发光材料的研究进展

介绍了稀土掺杂红色长余辉发光材料的研究进展,总结了硫化物、硫氧化物、钛酸盐等基质体系的红色长余辉发光机制。及传统的高温固相法以及溶胶-凝胶法、燃烧法等稀土红色长余辉材料的制备技术,提出了对红色长余辉材料今后发展的看法。     

丙烯腈悬浮床催化水合制备丙烯酰胺的催化剂研究

考察了丙烯腈悬浮床水合制备丙烯酰胺的各种催化剂性能，研究了雷尼铜（Ｒａｎｅｙ Ｃｕ）催化剂的三种影响因素：铜铝成分的比例、冷却成型方式和添加组分的影响及催化剂的再生性能。结果表明：喷雾法制备的雷尼铜［Ａｌ∶Ｃｕ＝５２∶４８（质量比）］催化剂比普通雷尼铜催化剂活性高１０％，强度高２４％，并具有良好的再生性能，适于作为悬浮床催化剂     

WALL AND PARTICLE-SHAPE EFFECTS ON HEAT TRANSFER IN PACKED BEDS

The effective radial thermal conductivity and apparent heat transfer coefficient for a packed bed were experimentally determined for beds of spheres, full cylinders and hollow cylinders, for flow rates giving particle Reynolds numbers in the range 100-1000, and for tube to particle diameter ratios of 5-12. Over these ranges the radial Peclet number Pe_r showed significant dependence on solid conductivity, gas flow rate and particle shape, while the wall Biot number Bi showed significant dependence on tube to particle diameter ratio, gas flow rate and particle shape. These dependencies were predicted well by equations incorporating the effects of these variables into individual gas and solid phase parameters, which were then combined to give the effective or lumped parameters     

PA66阻燃改性研究

通过卤系、氮系、磷系等阻燃体系对尼龙（PA）66进行阻燃改性研究，开发出一种赤磷与无机阻燃剂共用的复配阻燃体系。结果表明，当加入 赤磷10份、无机阻燃剂10份、玻纤30份时，利用该阻燃体系阻燃的PA66，其燃烧性能达FV－0级，拉伸强度大于100MPa，缺口冲击强度大于9kJ/m^2，综合性能优良。     

EXTERNAL FLUID HEATING OF A POROUS ED

This work deals with the thermal analysis of externally heated porous beds of finite length. A one dimensional model was developed that includes conduction and storage in both the fluid and bed, convective exchange between the fluid and bed, and the effect of adsorption/desorption in the bed. This model results in two coupled differential equations for the fluid and bed temperatures as functions of four independent dimensionless parameters. These equations were solved numerically using finite difference approximations. A truncation error analysis was carried out to maintain an accurate solution. The method of normalization is such that the results of this analysis are of use in bed design when the breakthrough characteristics in finite length beds are of interest. A method to measure bed thermal performance is defined and a means to optimize bed thermal performance is presented. An experiment was conducted to validate the numerically obtained results. A comparison of numerical to experimental results is presented     

二氧化氯催化氧化处理活性艳红染料废水催化剂的制备与应用

研究了二氧化氯催化氧化用催化剂的制备条件与催化剂性能。实验结果表明，在工业催化剂载体上负载Cu^2+活性组分的催化剂制备优化条件为：w(Cu²⁺)=6%，焙烧温度500 ℃，焙烧时间4 h。用此催化剂进行二氧化氯催化氧化处理COD为2 700 mg·L^-1的活性艳红染料配制废水时，COD去除率达75%；催化剂寿命与再生实验表明，该方法在技术与经济上都具有较强实用性。     

铁泥氧化制备颜料铁红的研究

以工业废渣铁泥为原料,经拌酸氧化制备铁红颜料,探讨了酸的种类、浓度及用量和氧化温度及时间对产品质量的影响。结果表明,较佳的工艺条件为:硫酸浓度60%,硫酸与铁泥质量比1∶1.2,氧化温度800℃,氧化时间2.0 h,得铁红产品,质量符合油漆、涂料等对铁红颜料的要求。     

氯霉素在聚茜素红薄膜修饰电极上的伏安行为及其测定

研究了聚茜素红薄膜修饰电极(PARE)对氯霉素(Chloramphenicol,CAP)的电催化作用,并应用于对微量CAP的定量检测。实验结果表明:在0.010mol/LHCl+1.0×10-4mol/LCu2++0.10mol/LNaCl测定体系中,CAP的浓度在1.0×10-9mol/L～1.0×10-8mol/L范围内与它的氧化峰电流呈良好的线性关系,线性方程和线性相关系数分别为:ip(μA)=-0.188×10-8CCAP(mol/L)-7.62,γ=0.9997,检出限可达5.0×10-10mol/L。CAP的标准回收率为95.9%~102.9%,八次平行样品测定结果的相对标准偏差3.2%。     

温度影响下压实红粘土持水特性研究

通过渗析法和水汽平衡法研究不同温度控制下干密度1.7 g/cm~3压实红粘土持水特性(SWRC:soil water retention characteristics)。试验结果表明:20℃下干密度1.7 g/cm~3压实红粘土进气值约为110 k Pa;试样控制的温度越高,压实红粘土样持水能力越低,土样进气值随着温度升高而减小,且呈线性关系;Van Genuchten(1980年)土水特征模型能很好的描述干密度1.7 g/cm~3压实红粘土持水特性曲线。     

Bauxite residue (red mud) increases phosphorus retention in sandy soil catchments in Western Australia

The Peel-Harvey estuary on the Swan Coastal Plain, Western Australia has become eutrophic partly because of the leaching of fertiliser phosphorus from sandy soils. The acid, coarse textured sandy soils are predominantly quartz, have a low iron and aluminium content and do not retain phosphorus. Red mud, derived from bauxite, is a by-product of the alumina industry and has the ability to retain phosphorus. Retention of phosphorus is enhanced when the red mud is neutralised with gypsum. Red mud has been suggested as a soil amendment to reduce phosphorus leaching.To investigate the reduction in the leaching of phosphorus from soils amended with red mud, weirs were constructed at the outlets from a pair of catchments to quantify the amount of phosphorus in the streamflow. Both catchments were deep grey Bassendean sand. One of the catchments was treated with 80 t/ha of red mud which had been neutralised with waste gypsum from the phosphate industry. The red mud was applied to the soil surface using conventional fertiliser spreading equipment. The other catchment was untreated.The red mud reduced phosphorus loss by 70% from 13.8 kg/ha on the untreated catchment, to 4.2 kg/ha on the treated catchment. Both catchments were treated with 20.4 kg/ha of phosphorus as superphosphate. The catchment treated with red mud also received a further 41.5 kg/ha of phosphorus from the phosphogypsum that was used to neutralise the red mud.Our results show that red mud reduces phosphorus leaching and is potentially a nutrient management option in sandy soils. Red mud has the potential to reduce the impact of agriculture on the estuarine environment and has implications for the continued expansion and intensification of agriculture in the Peel-Harvey catchment.