双阳煤在PKM气化炉试烧总结

介绍了在PKM气化炉中弱粘结性双阳煤的试烧情况,并给出了主要工艺参数控制范围。试烧结果表明:依兰煤中配入50%双阳煤,汽氧比6.0:1时,气化炉工况良好。     

Charge reduction and regeneration in K+, Na+, Mg2+, Ni2+ and Co2+-exchanged Wyoming Bentonite

Controlled calcination of ion-exchanged Wyoming Bentonite in the presence and absence of ammonia leads to layer charge reductions. Detailed chemical analyses of both unexchangeable and exchangeable species lead to the conclusion that in no case is there migration of the original interlamellar cations into the octahedral region of the layers although, in terms of ionic radius alone, Mg²⁺, Ni²⁺ and, possibly Co²⁺, might be expected to do so. The production of unexchangeable Mg, Ni or Co, is identified as resulting from high temperature hydrolysis leading to hydroxide or oxide formation.     

Dynamic deviation reduction‐based concurrent dual‐band digital predistortion

This article introduces the concurrent dual‐band digital predistortion (DPD) architecture with only one upconvertion unit, which is suitable for the linearization of wideband power amplifiers (PAs) excited by concurrent dual‐band signals. By extending the conventional dynamic deviation reduction (DDR) model to the concurrent dual‐band mode, we propose two DDR‐based concurrent dual‐band models, the dual‐band DDR (DB‐DDR) model and the simplified dual‐band DDR (SDB‐DDR) model. The performance of these two models is experimentally assessed with two types of wideband PAs (a GaN Class F PA and a GaN Doherty PA) driven by the concurrent dual‐band signal, and compared with the prior two‐dimensional digital predistortion (2D‐DPD) model and the two‐dimensional modified memory polynomial (2D‐MMP) model. The results prove the good DPD performance and low computational complexity of the proposed models. © 2013 Wiley Periodicals, Inc. Int J RF and Microwave CAE 24:401–411, 2014.     

代数约简的条件信息熵表示及其高效约简算法

给出如何保持正区域不变的语义分析,提出一种修正条件信息熵计算公式,证明保持修正条件信息熵不变与保持正区域不变相互等价。在此基础上,给出代数约简概念的修正条件信息熵表示。给出反例说明修正条件信息熵不具有单调性,导致没法给出自底向上的启发式约简算法,证明了代数协调集中不可删除属性的不可逆性质,提出一种自顶向下直接删除属性的高效约简算法。它从所有条件属性集出发,逐步删除不必要的属性,只需遍历各属性一次,即可保证得到原始决策表的一个代数约简。数值算例和实验验证了该算法的正确性和高效性。     

Chemical Reaction Engineering and Research and development of gas solid systems

A general procedure is proposed for innovative research and development of gas-solid reactor systems, with a brief explanation of the significance of each step in the procedureBased upon the contacting mode between gas and solid phases, as well as the ways of supplying thermal energy to the reacting regions, various types of gas-solid reactor systems are classified by using tables of so called “matrix” form, for thermal cracking and gasification of heavy oils, gasification of coal, gasification of solid waste, calcination of limestone, clinkering of cement and reduction of iron ore.The importance of fundamental concepts is emphasized for successful research and development by presenting several examples; namely, calcination of limestone, thermal cracking of heavy oils and gasification of solid waste materials.In connection with the direction in which fundamental research should be oriented, four primary ways of thinking are proposed, which can be applied to obtain innovative ideas for further research and development in this field.One example of the author's practical experience was selected to show the role of the fundamental research in the course of large scale development. Finally the author outlines the role of chemical reaction engineering to innovate the novel gas-solid reactor systems which may be inevitable for simultaneous solution of the three big E's; namely, Energy, Environment and Economy.     

Effect of incipient removal of hydrogen through palladium membrane on the conversion of methane steam reforming: Experimental and modeling

This paper presents a mathematical model based on the reaction rate expressions to describe the displacement of methane conversion in the steam reforming. The effect of several parameters including weight hourly space velocity (WHSV), load-to-surface ratio, reaction pressure, hydrogen partial pressure in permeate side and reaction temperature were investigated. Simulation and experimental results showed that a conversion higher than 80% could be achieved in a palladium membrane reactor at reaction temperature of 500 °C relative to 850 °C in a conventional fixed bed reactor (FBR). Besides, the yield of CO (<2%) in membrane reactor was much lower than that (>50%) in the FBR, which indicated the significant depression of CO production in use of membrane reactor.     

软弱破碎围岩隧道二衬施作的合理时机判别研究

为了合理判别软弱破碎围岩隧道的二衬施作时机,结合工程实践,通过洞室拱顶沉降和边墙变形收敛的现场监控量测,提出了利用围岩-初支系统变形实测数据判别软弱破碎围岩隧道二衬施作合理时机的考虑支护是否保守的五级速率比值法并研发了相应的软件,并通过工程实例进行了成功验证。研究表明：1研制的软件操作具有界面简洁、友好,以及操作简单易用的特点,具有测点围岩-初支系统位移和收敛的现场监测数据的录入、储存、修改和管理等功能,能方便地进行软弱破碎围岩隧道的二衬合理时机判别;2通过工程实例验证分析表明,提出的方法是可行的,与现行的二衬时机选择的方法本质上是相同的,但更加具有可操作性,研究成果可以为同类型隧道的二衬时机选择提供可资借鉴的方法。     

Comments on the characterisation of oxidation catalysts using TPR/TPO

Temperature programmed reduction (TPR) and oxidation (TPO) are used extensively in catalyst characterisation. In this paper, we examine the use of TPR/TPO cycles for the characterisation of a range of molybdates and single oxides. In particular we observe that the first cycle differs from that of subsequent analyses, even when the maximum temperature is limited to that used in the catalytic reaction. The effect is independent of heating rates and cooling atmospheres and has been demonstrated using different bed configurations. This observation has significance when these oxides are used in periodic flow reactors that involve many cyclical reduction/oxidation.