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81.
Thermochemical analyses of interfacial reactions in titanium, zirconium, and hafnium diboride reinforced oxidematrix composites have been carried out to evaluate the chemical compatibility. The chemical reactivity of these diborides with oxygen and the high volatility of B2 O3 ( l ) at reduced oxygen pressures are concerns during processing and operating conditions. The thermochemical stability and the vaporization behavior of B2 O3 ( l ) are discussed in terms of partial pressures of dominant gaseous species of the boron-oxygen system at 1700 and 2300 K. The TiB2 /ZrO2 and TiB2 /HfO2 systems are thermodynamically stable in a limited oxygen pressure range. The TiB2 /Al2 O3 system is stable, but the reactions in this system may apparently be accompanied by formation of gaseous products (B2 O3 , AlO, Al2 O, and lower boron oxides) in the presence of elemental oxygen. These thermochemical considerations are very useful in evaluating the effectiveness of oxides as diffusion barrier coatings on diboride reinforcements. 相似文献
82.
V Živica 《Bulletin of Materials Science》1995,18(2):115-124
The paper describes a method for the mathematical modelling of steel reinforcement corrosion rate. This method is based exclusively
on experimental results and expression of the influence of significant corrosion factors in the form of functional relations.
The method takes into account the reality of the effects of corrosion factors, their contigency and complexity, and various
circumstances occurring in practice. It represents one way towards the development of methods for the prediction of service
life of reinforced concrete and structures. 相似文献
83.
本文研究了一种Zn-Ti合金新镀层,经盐水浸泡、中性盐雾和大气暴露试验结果试验,其耐蚀明显超过镀Zn层,并与镀Cd层相近,用缺口持久拉伸试验检验氢脆性,拉伸持续时间超过200h,达到原航空部部颁标准(HB5067-85),该镀层适用于高强度钢防护。 相似文献
84.
Electrochemical impedance measurements have been used to characterize zinc selenide films prepared by electrochemical co-deposition at a platinum rotating disk electrode. Estimations of capacitance and polarization resistance of variously prepared electrodeposits have been carried out to determine charge carrier density and corrosion rates. 相似文献
85.
The influence of NaCl and CO2 on the atmospheric corrosion of magnesium alloy AZ91 is studied in the laboratory. Samples were exposed under carefully controlled air and flow conditions; the relative humidity was 95%, the temperature was 22.0°C and the concentration of CO2 was < 1 ppm or 350 ppm. Different amounts of sodium chloride (0–70 μg/cm2) were added before exposure. The corrosion products were analyzed by gravimetry, ion chromatography, X‐ray diffraction and scanning electron microscopy. Mass gain and metal loss results are reported. The combination of high humidity and NaCl is very corrosive towards AZ91. However, the NaCl‐induced corrosion is inhibited by ambient concentrations of CO2. Exposure in the absence of CO2 gives rise to heavy pitting, with brucite, Mg(OH)2, being the dominant corrosion product. In the presence of CO2 a layer of hydrated magnesium hydroxy carbonate, Mg5(CO3)4(OH)2 · 5 H2O forms. A tentative corrosion mechanism is presented that explains the behavior in the two environments. 相似文献
86.
在辽宁省工业城市进行 A3钢大气暴露试验。两年后测出不同地点腐蚀率。依据所记录的各试验点的气象数据和污染数据,讨论了 A3钢的大气腐蚀规律。 相似文献
87.
离子注入对铁及其低合金、铝及其合金耐腐蚀性能的影响 总被引:1,自引:0,他引:1
离子注入对金属腐蚀行为的研究已达30年.研究结果表明离子注入对改变金属表面成分和表面性能是极为有效的技术.本文概述了离子注入对铁及其低合金、铝及其合金的腐蚀电化学行为的影响.涉及的注入离子达十余种。 相似文献
88.
Donghua Zhang 《应用聚合物科学杂志》2006,101(6):4372-4377
Polyaniline (PANI) was synthesized by chemical oxidative polymerization of aniline (ANI) in the presence of alumina (Al2O3) particles. The polymerization of ANI occurred preferentially on the surfaces of the particles, resulting core–shell structured alumina–polyaniline (Al2O3‐PANI) particles. Morphology examination showed that with decreasing of the weight ratio of Al2O3/ANI in the reactants, the thickness of the PANI layer increased and changed from an even surface morphology to a particulate morphology. UV–vis and Fourier transformed infrared (FTIR) spectra indicated that there is no chemical interaction between the PANI layer and the Al2O3 surfaces. The PANI layer adhered well to the particles and can be used as anticorrosive fillers for polymer coatings. Enhanced corrosion protection performance was achieved for the emeraldine base (EB) form of PANI deposited Al2O3 particles (Al2O3‐EB) filled epoxy coating on carbon steel in 3.0 wt % aqueous NaCl solution. The particles demonstrate both excellent corrosion protection performance and lower cost, which will be of great importance in practical applications. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 4372–4377, 2006 相似文献
89.
从加热炉燃料变化情况入手 ,分析了加热炉目前存在的炉管结垢 ,预热器烟气露点腐蚀以及炉体腐蚀等问题。从机理上进行了探讨 ,从而提出了原油脱金属、燃料气脱硫、燃料油优化、化学除垢以及预热器改造等防护措施。 相似文献
90.
Hemanshu Bhatt Kimberly Y. Donaldson D. P. H. Hasselman Kenneth Chyung Mark P. Taylor 《Journal of the American Ceramic Society》1991,74(6):1463-1465
A study concerning the effect of fiber orientation on the thermal conductivity of a uniaxial carbon-fiber-reinforced borosilicate glass was conducted. For thin specimens, and thick specimens with specimen sides cut parallel to the fiber direction, the dependence of thermal conductivity on fiber orientation showed excellent agreement with theoretical behavior predicted for a composite infinite in extent. In contrast, the thermal conductivity data for rectangular thick specimens fell well below the data for the thin and angled specimens. For fiber orientation of 45° and higher, at which the heat was directed toward the side of the specimen rather than across, the thermal conductivity values showed excellent agreement with theoretical behavior predicted for a finite composite strip with insulated sides. 相似文献