用热失重法确定水合粘土水分含量及存在形式

文章以蒙脱土为例，采用热失重法定性定量确定了水合粘土中结合水类型、界限及其相对含量，并与等温吸附法结果进行了对比。结果表明，用该方法得到的水合蒙脱土中各种水分的相对含量及总含水量与等温吸附实验结果相一致。热失重（25~250 ℃）分析结果表明，水合蒙脱土中水分子主要存在自由水、松散吸附结合水、紧密吸附水（强吸附结合水）3种状态，分别对应于25~75 ℃、75~120 ℃、120~230 ℃区间里的失水。从热失重（25~250 ℃）规律来看，仍存在两个明显的转折点p/ps=0.9、0.98，它们为粘土-水体系的两个特征湿度，前者为粘土表面强结合水与松散结合水（渗透结合水）之间的界限，后者为松散结合水与自由水之间的界限，这验证了等温吸附法确定的两个特征湿度及对粘土表面结合水界限划分的正确性。     

Analytic computation of the photocurrent density in a n-6H-SiC/p-Si/n-Si/p-Si0.8Ge0.2 multilayer solar cell

In this work we conceived a model of a multilayer solar cell composed by four layers of opposite conductivities: an n-type 6H-SiC used as a frontal layer to absorb high energy photons (energy gap equals 2.9 eV), a p-type Si layer, an n-type Si layer and a p-type SiGe back layer to absorb low energy photons (Si_0.8Ge_0.2 with an energy gap equal to 0.8 eV). The impurity concentration in every layer of the model is taken equal to 10¹⁷ cm⁻³ to ensure abrupt junctions inside the cell. The optical properties of the separate layers have been fitted and tabulated to be used for thin films devices numerical simulation. We developed the equations giving the minority carrier concentration and the photocurrent density in each abscissa of the model. We used Matlab software to simulate and optimize the layers thicknesses to achieve the maximum photocurrent generated under AM0 solar spectrum. The results of simulation showed that the optimized structure could deliver, assuming 10⁵ cm/s surface recombination velocity, a photocurrent density of more than 53 mA/cm², which represents 88.3% of the ideal photocurrent (59.99 mA/cm²) that can be generated under AM0 solar spectrum.     

Morphology development in polyethylene/polystyrene blends: the influence of processing conditions and interfacial modification

The influence of processing conditions and interfacial modification on the morphology evolution and the composition range within which fully co‐continuous high density polyethylene/polystyrene blend structures can exist during blending in a single screw extruder was studied. Blends ranging from pure A to pure B component, with and without compatibilizer, were prepared under two different shear rates. It was found that high shear rates displaced the breakdown–coalescence balance of the dispersed nodules to the side of coalescence, narrowing the percolation domain and the critical composition for full co‐continuity decreased with increasing shear rates. The addition of a tri‐block compatibilizer induced the percolation threshold of the polystyrene phase to begin at lower percentages of polyethylene but the phase inversion point did not change. The experimental results are discussed in the light of various theoretical models. Copyright © 2005 Society of Chemical Industry     

一种控制盐层段井眼闭合率的钻井液密度新公式

针对钻井过程中钻遇的盐层段井眼蠕变缩径问题,利用弹塑性力学理论,蠕变本构方程采用Heard蠕变方程,在平面应变和均匀地应力假设下,推导出控制井眼收缩的钻井液密度新公式,该公式与前人推导的公式不同。通过理论分析,指出产生差异的根本原因在于蠕变应力差(极坐标下表示的径向应力与切向应力之差)公式的推导上,用有限元法计算结果对理论公式进行检验,证明是可行的。对文中的力学模型采用有限元法建模、求解,利用求解结果对各应力差公式进行验证,得出:根据文中公式计算结果与有限元法计算结果完全一致,而据前人公式计算结果偏离有限元计算值较大,从而间接证明了该钻井液密度新公式的推导更严密,更准确。     

高频MnZn功率铁氧体烧结工艺研究

按照氧化物陶瓷工艺对高频MnZn功率铁氧体烧结工艺条件进行了研究。烧结温度越高，晶粒越大，晶界越薄，电阻率越低，磁芯损耗越大，起始磁导率和烧结密度分别在1240℃和1230℃达到最大值。延长保温时间，可以使晶粒充分生长，晶界变薄，电阻率减小，损耗增大。保温3h后，起始磁导率和烧结密度均可达到最大值。氧分压越低，材料起始磁导率越高，电阻率越小，损耗越大，但氧分压低于5％后烧结密度不再继续增加。     

Estimation of errors of hydrogen standard time scale preservation taking account of systematic frequency changes

Metrological characteristics of active hydrogen frequency standards are investigated on the basis of internal and external comparisons. The stability of random changes and drift of hydrogen frequency standards and also the potential capabilities of time scale preservation with effective consideration of systematic changes in their frequency are demonstrated. __________ Translated from Izmeritel’naya Tekhnika, No. 3. pp. 42–45, March, 2007.     

Preparation,structural elucidation,molecular weight determination,and molecular recognition of first‐ and second‐tier dendrimer molecules

1,3,5‐Triglyceratetriazine [first tier (G₁)] and tri(1,3,5‐triglycerate) triazine [second tier (G₂)] dendrimers were prepared with 1,3,5‐trichlorotriazine and sodium glycerate in a 1 : 3 mass ratio in an ethanolic medium.G₁ and G₂ were amorphous, white, solid substances. Their structures were elucidated with IR, ¹H‐NMR, and ¹³C‐NMR, and their thermal stability was studied with thermogravimetric analysis. The activation energy was calculated with the Freeman–Carroll model. Densities, viscosities, and surface tensions for 0.01–0.08 mol/kg aqueous solutions increased at 0.01 mol/kg for sodium glycerate, 1,3,5‐trichlorotriazine, 1,3,5‐triazine triglycerate chloride, G₁, and G₂. These values were measured at 298.15 K. The apparent molal volume, reduced viscosity, and inherent viscosity were calculated from the densities and viscosities, respectively. The data were regressed for the limiting densities, limiting apparent molal volumes, intrinsic viscosities, limiting inherent viscosities, and limiting surface tensions for solute–solvent interactions. The positive limiting apparent molal volume values were noted in the order of G₂ > 1,3,5‐triazine triglycerate chloride > G₁ > 1,3,5‐trichlorotriazine > sodium glycerate, with weaker hydrophilic intermolecular interactions of G₂. The higher intrinsic viscosity and limiting inherent viscosity values for G₂ implied stronger G₂–H₂O hydrophilic interactions, and the higher limiting apparent molal volume of G₂ indicated slightly higher dynamic conformational changes in comparison with G₁, with stronger structural activities. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Evaluation of improvement of physical and mechanical properties of bamboo fibers due to alkali treatment

Bamboo strips treated with caustic solutions of different concentrations, e.g., 5%, 10%, 15%, 20%, 25%, and 50%, were subjected to mechanical testing giving stresses on tensile strength, percent elongation at break, flexural strength, flexural modulus, and toughness. The change in average density was ?15%, and the weight loss value shows a maximum of 21.94% at 50% alkali treatment. The mechanical properties of bamboo strips increase steadily with increasing concentration of caustic soda, showing a comparable increased value at 15 and 20%, and then exhibiting a gradual fall. The percent elongation at break corroborates these observations showing a continuous decreasing trend. The properties under investigation exhibit a clear transition in between 15 and 20% alkali concentration. The morphology of strips was studied by scanning electron microscope and polarizing light microscope. The crystal structure of both untreated and treated strips was compared by XRD analysis. In both cases, the breakdown of the crystal structures of the cellulose fibers and the recrystallization or reorientation of the degraded chains that are devoid of hemicellulose are quite apparent. However, at a very high concentration (to the extent of 25%) the breakdown of structure predominates much more over the reorientation or recrystallization. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008