Agronomical evaluation of phosphate fertilizer as a nutrient source of phosphorus for crops: Isotopic procedure

The agronomic effectiveness of P fertilizers, as sources of phosphorus for crops, was evaluated using the quantities, P_f, of phosphorus taken up byLolium perenne grown on 14 soils during greenhouse experiments in pot cultures. The P_f quantities were determined using³²P-labelled fertilizers. Data were analysed using a new concept: the Isotopic Relative Agronomic Effectiveness (IRAE). The IRAE value was defined as the ratio of the P_f quantity, taken up by a crop, of a tested fertilizer over the P_f quantity, taken up by a crop, of a fertilizer used as standard. In our experiments diammonium phosphate (DAP) was used as standard P fertilizer and two rock phosphates, the North Carolina rock phosphate (NCPR) and a calcium-iron-aluminium phosphate (Phospal), were tested. As a linear relationship between P_f(NCPR) quantities and P_f(DAP) quantities was obtained, with r² = 0.95, when the application rates increased from 15 mgP (kg soil)^–1 to 200 mgP (kg soil)^–1, it is conciuded that IRAE values for a given fertilizer, other than the standard fertilizer, could be determined with a single rate of application. As regards soil pH in the range 4.7 to 8.2 the IRAE_NCPR is related to soil pH by a curvilinear relationship: log IRAE_NCPR = –(0.44) pH + 4.05 with r² = 0.89. The average of IRAE_phospal values was 0.15 with a standard error = 7% irrespective of soil pH. Then a logarithmic relationship was obtained between IRAE values of the two tested fertilizers and their water P-solubility determined at the soil pH where they were applied.     

Application strategies for Sechura phosphate rock use on permanent pasture

At two phosphate (P) responsive sites in hill country the effectiveness of Sechura phosphate rock (SPR) as a direct application P fertilizer for permanent pasture was evaluated. Sechura was applied at two rates, in three different application strategies. The treatments were 16.7 and 50 kgP ha^–1 annually, 25 and 75 kgP ha^–1 biennially, and 50 and 150 kgP ha^–1 triennially giving a total of 50 and 150 kgP ha^–1, respectively, over three years. Single superphosphate (SSP) served as the standard P fertilizer. A comparison was also made between SPR and Chatham Rise phosphorite (CRP), another reactive PR. Total pasture and legume production and P uptake by pasture was measured with all fertilizer treatments over a three year period.In the year of application, SPR was as effective as SSP in stimulating total pasture and legume production and P uptake by pasture. This reflects the very reactive nature of this PR. In the second and third years of measurement, SPR did not show superior residual efffects to SSP. The ability of CRP to stimulate legume growth more than SPR in the second year following application demonstrates the danger of generalizing about the residual effects of reactive PR materials. Of the application strategies evaluated, a biennial appplication of 25 kgP ha^–1 as SPR maintained legume growth at a higher level than a smaller (16.7 kgP ha^–1) annual dressing. The biennial strategy also increased total pasture yield, in addition to legume production to a greater extent in the second and third years than a single (50 kgP ha^–1) triennial application.     

利用钛白废酸制高纯度磷酸一铵试验简介

试验表明,用钛白粉生产中副产的w(H2SO4)≈20%的钛白废酸,经浓缩、净化及再稀释后与磷矿粉反应,在加入净化添加剂的条件下制得纯净的湿法磷酸与氨或碳酸氢铵反应,可代替热法磷酸为原料生产相同质量的高纯度磷酸一铵。分析了该工艺的技术可行性和经济可行性,认为所得的纯净磷酸也可加工成其他高纯度磷化工产品。     

利用测井资料识别碳酸盐岩裂缝的方法

在碳酸盐岩地层中,裂缝是非常常见且十分重要的一类储集空间类型,对油气的运移和聚集有非常重要的作用。因此,裂缝的识别显得特别重要。本文以新疆某油田为例,通过岩芯观察及成像测井资料与常规测井资料进行比对,总结出了不同类型裂缝对常规测井的不同响应特征。通过实际应用,识别效果良好,证明用测井方法识别不同类型的裂缝是可行的。     

利用波形分析技术预测塔河油田碳酸盐岩储层

针对塔河油田盐体覆盖区下奥陶统碳酸盐岩埋深大,储层非均质性强的特征,利用地震波形变化特征半定量识别和预测优质储层分布。波形分析法是根据碳酸盐岩储层裂缝和孔洞结构特有的非均质性,建立地质模型,结合地震波形分析和反射机理研究,确定储层与地震响应之间的对应关系,根据建立的碳酸盐储集层地震识别模式,进而对未知区域作储层预测。     

磁西勘查区主采煤层煤层气赋存特征

据勘探研究磁西勘查区主采煤层既是煤层气源岩,又是其储集层,煤层有机显微组分以镜质组为主,煤的变质程度为中~高变质的烟煤~无烟煤,生气量较高,为高瓦斯矿区。本区以正断层为主,断层使煤层与泥质岩层接触,具有一定的封闭性。煤层埋深较大,主采2号煤层直接顶板为泥岩、粉砂岩,岩性致密,透气性较差,有利于煤层气资源的保存,从而使煤层气含量升高。     

基于Hoek-Brown准则的深部岩体力学参数及其应用

基于Hoek-Brown经验强度准则,采用最小二乘法拟合出岩体力学强度参数,并与H-B_02ed推荐的等面积拟合结果进行对比,结果发现两种拟合方法得出的岩体内摩擦角数值相差很小,但等面积拟合法得出的黏聚力强度远高于最小二乘拟合法。将两种强度参数拟合结果应用于深部矿体开采的数值模拟,发现采用最小二乘拟合法的岩体强度参数其模拟结果更接近工程实际。该方法对深部岩体力学参数的确定具有一定的借鉴意义。     

Particle simulation of the failure process of brittle rock under triaxial compression

In order to investigate the failure process of brittle rock under triaxial compression through both experimental and numerical approaches, the particle simulation method was used in numerical simulations and the simulated results were compared with those of the experiment. The numerical simulation results, such as fracture propagation, microcrack distribution, stress-strain response, and damage patterns, were discussed in detail. The simulated results under various confining pressures (0-60 MPa) are in good...     

Numerical simulation on bolted rock joint shearing performance

A Double Shear Model(DSM)was used in a numerical simulation on bolted rock joint shearing performance.An entire bolt deformed as the letter"U"under a shear load between two joints.Near the bolt-joint intersection,the bolt partly deformed as the letter"Z".There were two critical points along the bolt: one was at the bolt-joint intersection with zero bending moment and the other at the maximum bending moment(plastic hinge)with zero shear stress.The blocks on two sides slid along the bolt as it deformed.A separation area was found between the two joint contact surfaces of the middle rock block and sided block.This area of separation was related to bolt diameter and external forces.We assume that this area is related to the work of external forces.Further research is needed.     

新型半刚性网壳锚喷支护技术在软岩巷道中的适用性研究

通过对钢筋网壳锚喷支护的技术特色、结构特点、支护原理的研究,分析了半刚性网壳支护结构对软岩支护的适应性。并完成了室内整架载荷试验。结合在桃园矿的应用情况,阐述了其支护参数选择和施工工艺,并对其进行现场监测,分析了这种新型支护形式的支护性能。实践证明,空间网壳锚喷支护结构与围岩相互作用的整体性好,具有良好的力学性能与较高的承载能力,是软岩巷道中的一种既经济又安全可靠的支护结构形式。