分子动力学模拟铜纳米团簇的结构稳定性

利用分子动力学研究了原子数为13～1 055的铜纳米团簇.结果表明:随着尺寸的减小,铜纳米团簇的结构发生晶体→非晶→晶体→非晶→晶体→非晶的转变.团簇平均原子结合能随着尺寸的减小而减小,且只依赖于短程有序,这说明了团簇平均原子结合能一般不能够作为非晶与密堆结构晶体转变的判据.平均原子间距不但依赖于团簇的尺寸,且对团簇结构的变化敏感,可以作为非晶与密堆结构晶体转变的一个判据.对偶分布函数的研究表明,大尺寸团簇的内部和表层原子结构都表现出晶格收缩效应,且不同于相应块体晶格,这表明了目前文献中关于团簇的块体加表面模型与壳核模型都有待改进.     

化学危险品的安全对策

随着我国化工产业的高速发展，化学危险品事故也日益增多，如何保障化学工业的生产安全，是我们面临的一个课题。本文简述了化学危险品的安全对策。     

Stiffer and super-tough poly(butylene terephthalate) based blends by modification with phenoxy and maleated poly(ethylene-octene) copolymers

New super-tough poly(butylene terephthalate) (PBT) materials were obtained by melt blending PBT with both 20 wt% phenoxy (Ph) and 0-30 wt% maleic anhydride grafted poly(ethylene-octene) (mPEO) copolymers with different grafting levels. Ph was completely miscible in the PBT matrix. The presence of mPEO did not influence either the nature of the PBT-Ph matrix or the crystallization of PBT. The overall decrease in particle size and in interfacial tension upon grafting indicated that compatibilization had taken place. Super-tough (impact strength 23-fold that of the PBT) and stiffer PBT based blends were obtained at mPEO contents equal to or higher than 15%. The dependence of the critical inter-particle distance (τ_c), on both adhesion measured by means of the interfacial tension, and on the relation between the modulus of the matrix and that of the rubbery dispersed phase (E_m/E_d), is proposed.     

基于扩散距离和MDS的非刚性模型相似性分析

在非刚性模型相似性分析方法中, 基于测地距离的等距嵌入方法对模型拓扑变化非常敏感, 对于有局部拓扑变化的完全相似的模型也无法得到正确结果。为了弥补这一不足, 提高非刚性模型相似性分析的准确性, 将扩散距离与多维尺度分析(MDS)相结合, 计算非刚性模型的等距嵌入模型, 再利用迭代最近点(ICP)算法通过计算嵌入模型的相似性来实现原始非刚性模型的相似性分析。实例证明该方法对含有拓扑变化的非刚性模型可以得到理想的相似性分析结果。     

Statistical properties of interparticle/void distance for amorphous plastics toughening

Statistical properties of interparticle/void distance (ID) for various particle/void and dispersion types are studied in relation with toughening of plastics using computer‐generated three‐dimensional models. Particle/void size groups adopted were either of constant diameter or of log‐normal distribution. Particles/voids were dispersed at uniform‐random or flocculated with multiple clusters. It was found that IDs are (a) of approximately Gaussian distribution for particles/voids of either a constant diameter or a log‐normal distribution, when they are dispersed at uniform‐random, but (b) not of Gaussian distribution for particle/void sizes of bimodal log‐normal distribution, nor for flocculated log‐normal distribution of particles/voids dispersed with multiple clusters. It was also found that the degree of ID uniformity for a single group of log‐normally sized particles/voids is not sensitive to standard deviation of particle/void size. Mixing effect on ID properties using two groups of log‐normally distributed particles/voids with similar mean particle/void diameters was simulated. It was found that, when a significant amount (36 vol %) of particles/voids of a small mean and standard deviation of ID was mixed with a group of particles/voids of a large mean and standard deviation of ID, mean and standard deviation of ID for the mixture were not substantially lower than those of the group of particles/voids of the large mean and standard deviation of ID. It was also found that the degree of ID uniformity for the mixture of the two groups was lower than those of individual groups, indicating that the mixing has deleterious effect on toughening. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 4256–4262, 2006     

纹理豪斯多夫距离在人脸识别算法中的应用

很多经典的人脸识别方法难以适应姿势变化及人脸错位的情形。为了解决这一问题,提出一种基于纹理豪斯多夫距离(THD)的人脸识别算法。将人脸图像的空间量及纹理特征相结合,使其在深入的头部转动和人脸错位中都有很高的容错度。在FERET及Yale两大人脸数据库的实验表明,与其他经典的方法相比较,所提出的方法取得了更好的识别效果。     

我国二氧化硫氧化制硫酸的钒催化剂现状和展望

从钒催化剂的生产、市场、开发、质量等方面分析我国二氧化硫氧化制硫酸催化剂的现状，指出我国钒催化剂与国外产品存在的差距和原因，提出发展钒催化剂的对策。     

基于灰度形态重构的颗粒图像分割方法

提出了一种基于距离变换、形态重构和分水岭算法的图像分割算法。将一幅图像通过距离变换得到距离灰度图,与形态重构算法结合,得到颗粒图像的标识点图,用标识点图对距离灰度图进行分割,再用分水岭变换对分割后的距离灰度图进行变换。试验表明,该算法能有效合理地解决粘连或者重叠颗粒等物体的分割。     

水流掺气对明流泄洪洞及挑坎水力特性的影响

水流充分掺气可以避免高流速泄洪设施发生空蚀,但也会改变相关水力特性。通过对某大坝泄洪洞掺气设施水力模型试验及关于水流表面自掺气发生条件的相关分析,提出了在全程流速超过38 m/s,长度达550 m的明流洞内仅布置一级掺气设施的建议,较通常情况减少了两级;并针对泄洪洞出流方向与河道流向交角达60°的特点,研究提出了一种大差动异型鼻坎消能工。水工模型试验成果表明,其挑流水舌沿河道纵向扩散良好,水舌外缘与河道对岸保持了30 m以上的安全距离。该泄洪洞建成后经历了高水头、较长时间的泄洪运行,明流洞和鼻坎消能工均无空蚀发生,但挑坎水舌却冲刷到对岸边坡。     

How social distance shapes human–robot interaction

This paper investigates how social distance can serve as a lens through which we can understand human–robot relationships and develop guidelines for robot design. In two studies, we examine the effects of distance based on physical proximity (proxemic distance), organizational status (power distance), and task structure (task distance) on people׳s experiences with and perceptions of a humanlike robot. In Study 1, participants (n=32) played a card-matching game with a humanlike robot. We manipulated the power distance (supervisor vs. subordinate) and proxemic distance (close vs. distant) between participants and the robot. Participants who interacted with the supervisor robot reported a more positive user experience when the robot was close than when the robot was distant, while interactions with the subordinate robot resulted in a more positive experience when the robot was distant than when the robot was close. In Study 2, participants (n=32) played the game in two different task distances (cooperation vs. competition) and proxemic distances (close vs. distant). Participants who cooperated with the robot reported a more positive experience when the robot was distant than when it was close. In contrast, competing with the robot resulted in a more positive experience when it was close than when the robot was distant. The findings from the two studies highlight the importance of consistency between the status and proxemic behaviors of the robot and of task interdependency in fostering cooperation between the robot and its users. This work also demonstrates how social distance may guide efforts toward a better understanding of human–robot interaction and the development of effective design guidelines.