中国信息服务业空间集聚研究

通过产业集聚的EG指数对中国各省份信息服务业的空间集聚程度进行研究,得出集聚程度比较显著.在此基础上,找到这一服务业的两个相关指标,利用产业集中度CRn判断出信息服务业主要集中于北京、广东等六个地区,然后对两指标数据进行无量纲化处理,加权求和得到新的综合指标,最后对这一新指标进行了系统聚类分析,得知这一产业主要集中在北京和广东两个地区.     

大鼠灌胃中国蜂胶醇提物后血浆中5种酚酸类成分的HPLC测定及其药代动力学

对大鼠灌胃蜂胶乙醇提取物（EEP）后,血浆中5种酚酸类成分的药代动力学特性进行研究.用HPLC-UV法测定血浆中咖啡酸、香豆酸、阿魏酸、异阿魏酸和3,4-二甲氧基肉桂酸的浓度.应用WinNonlin非典型房室模型计算软件计算相应的药代动力学参数.血浆中内源性物质和内标对酚酸类成分测定无干扰,回收率、准确度及日内、日间精密度均符合生物样品测定要求.结果表明,该方法简便、快速、重复性好,适用于咖啡酸等5种蜂胶中酚酸类成分的大鼠血药质量浓度测定及体内药动学研究.     

乙二醇质量浓度对垂直U型地埋管的传热影响的数值模拟

目的研究添加不同质量浓度乙二醇溶液对地埋管换热性能的影响．方法利用gambit和fluent软件建立一个简单垂直U型地埋管热泵机组模型,模拟在不同工况下不同乙二醇的热物性参数对应的机组性能．结果夏季制冷工况下,添加乙二醇与未添加相比冷凝器的出口温度升高,乙二醇质量浓度每升高10％,温度升高1‰左右．冬季制热工况下,添加乙二醇与未添加相比蒸发器的出口温度降低,乙二醇质量浓度每升高10％,温度降低1％左右．结论通过数值模拟,得出在夏季制冷工况下,乙二醇质量浓度变化对地埋管换热的影响不太大．冬季制热时,随着乙二醇质量浓度的升高制热量降低．并得到在制冷和制热的工况下不同质量浓度的乙二醇对应的热泵机组的出口温度随时间的变化规律及模拟出在质量浓度对应的制热量的修正系数．     

四点弯曲U形切口应力集中系数的数值分析

四点弯曲实验是适用陶瓷材料断裂韧性的测试方法和标准,可以研究具有切口脆性材料构件的断裂.借助于ANSYS有限元分析,得到了不同的切口尖锐度(切口深度与切口根部半径的比值a/ρ)和宽度比值(试样宽度和切口深度的比值w/a)下,单边U形切口四点弯曲的应力集中系数.利用Matlab软件拟合不同宽度比值,得到四点弯曲U形切口应力集中系数与切口尖锐度的关系式,为四点弯曲U形切口的断裂分析提供了理论基础.     

压裂泵液力端阀箱内腔结构优化研究

压裂泵液力端阀箱内腔在加工完成后会自然形成相贯线,该相贯线位置存在严重的应力集中问题。这些位置也是液力端阀箱常见的开裂位置,虽然通过相贯线倒圆角的方式可以减小应力集中程度,但是应力减小的幅度不是十分明显。针对此问题,通过有限元仿真对比的方式进行了阀箱内腔优化研究,提出了减小阀箱内腔应力集中程度的技术方案,同时提出了应用该方案时应注意的一些问题。研究结果对于提高压裂泵液力端使用寿命及优化压裂泵液力端设计具有一定的指导意义。     

残余应力集中及其对疲劳极限和短裂纹扩展的影响

缺口根部的残余应力存在应力集中效应,应力集中值不仅取决于缺口几何形状而且和材料的屈服强度有关。残余应力集中系数是一个分布值,其数值甚至可超过理论应力集中系数。软试样喷丸后缺口处的残余应力易于松弛及喷丸时的表面损伤使其对疲劳极限的贡献小。残余压应力使缺口处裂纹闭合力增大甚至可出现非扩展裂纹。     

Microstructure, mechanical and tribological properties of Cr1−xAlxN films deposited by pulsed-closed field unbalanced magnetron sputtering (P-CFUBMS)

Nanocrystallized Cr_1−xAl_xN films with various Al contents (0 to 68 at.%) were deposited by pulsed closed field unbalanced magnetron sputtering (P-CFUBMS). The effects of aluminum content on the microstructure, mechanical and tribological properties of the Cr_1−xAl_xN films have been investigated. It was found that the hardness and elastic modulus of Cr_1−xAl_xN films increased with increasing Al contents in the films and reached the highest value of 36 GPa and 370 GPa, respectively, at an Al content of 58.5 at.%. Addition of Al beyond 64.0 at.% resulted in a change in crystal structure from B1 cubic to B4 hexagonal phase. The wear resistance improved gradually with the increase of Al in the Cr_1−xAl_xN films. A combination of the abrasive and adhesive wear mechanism was proposed based on the SEM and EDS analysis of the wear track. The steady state dry coefficient of friction measured against a WC ball for the Cr_1−xAl_xN films were in the range of 0.36-0.55, and the wear rate was in the 10^− 6 mm³ N^− 1 m^− 1 range.     

流动条件下炔氧甲基季胺盐的缓蚀性能研究

利用交流阻抗(EIS)、线性极化、动电位极化和失重法，研究了炔氧甲基季胺盐对N80在常温CO2饱和的3％NaCl溶液中的电化学行为和缓蚀性能的影响．结果表明：空白溶液中N80的累计失重在4m／s以后急剧增大，即介质的临界流速为4～5m／s．动态下炔氧甲基季胺盐存在与静态下相同的浓度极值现象，流速低于5m／s时缓蚀剂的极值浓度与静态时相同，都为150mg／L，而流速高于5m／s后极值浓度有所增加．     

Thermodynamic properties and mixing thermodynamic parameters of Ba-Al, Mg-Al, Sr-Al and Cu-Al metallic melts

Application of equations of mixing thermodynamic parameters formulated on the basis of the coexistence theory of metallic melts in Ba-Al, Mg-Al, Sr-Al and Cu-Al melts leads to fruitful results that not only the evaluated mass action concentrations agree well with the measured activities, but also the calculated mixing thermodynamic parameters are quite coincident with the experimental values. Moreover, the calculated mass action concentrations strictly obey the mass action law. The evaluated mixing thermodynamic parameters have very fine regularity: the mixing free energy is composed of standard free formation energies of all compounds and chemical potentials of all structural units at equilibrium; the mixing enthalpy consists of standard formation enthalpies of all compounds; the mixing entropy is composed of standard entropies of all compounds and configuration entropies of all structural units at equilibrium. As the equations of mixing thermodynamic parameters formulated are widely applicable to metallic melts involving compound formation, they can be used as the second practical criterion to determine whether thermodynamic models of metallic melts are correctly formulated.     

Pd基大块金属玻璃过冷液相区与键参数的关系

通过计算机对Pd基大块金属玻璃的过冷液相区宽度△Tx的表达式进行回归处理分析，得到Pd基大块金属玻璃过冷液相区△Tx与反映合金混合热变化的3个键参数(电负性差△X、原子尺寸差的百分数δ和电子浓度n)之间存在如下关系：△Tx=29．36909 3602．45898(△x)^2 9992．76758δ^2-3．95897n^2/3，相关系数为97．2％。△Tx随多元合金的电负性差和原子尺寸差的百分数的增加而增加，而随电子浓度的增加而略有降低。