基于CMIP5的中国西北地区暖湿化演变研究

为了解中国西北地区历史与未来时期的气候演变趋势,以CMFD再分析数据集及CMIP5全球气候模式输出数据为基础,从时空维度详细分析了西北地区历史气候的演变特征并对区域未来气候发展进行了预估。结果表明：1979-2018年西北地区的气温、降水量以及近地面空气比湿均呈现出明显的增加趋势,且未来极有可能继续增加;此外,降水量在年内的分配过程越趋均匀化,且降水结构在2001年左右发生了较大突变。整体来看,西北地区的历史气候演变显示出高度的暖湿化倾向。未来情景下,西北地区的气候将继续朝暖湿化方向发展,同时降水量的年内分配不均匀性也将进一步减小,且在RCP8.5排放情景下表现的更为突出。本研究可为西北地区气候变化的影响评估提供参考,同时也为水利、农业、气象和生态等部门的决策提供科学依据。     

Photovoltaic effect and carrier transport mechanisms in Hg1-Mnxtdiodes

Hg_1-xMn_xTe semiconducting semimagnetic alloy has been examined in the context of its possible applications in infrared detectors. For analysis of detector properties the intrinsic carrier concentration has been calculated as a function of temperature and crystal composition. The starting material was In-doped Hg_1-xMn_xTe grown by the modified Bridgman method. The as-grown crystals with manganese content of 12-19% were p-type with carrier concentration and mobility of 100 cm²/ Vs at 77 K. An-type layer was formed on the surface by the annealing process in saturated Hg-vapour at 270-320° for 2 hrs. Capacitance-voltage curves have C^-3 dependence on applied voltage indicating that the junction is linearly graded. From standard electrical measurements and spectral characteristics the main detector parameters were determined and compared to those of Hg_1-xCd_xTe devices. The influence of material properties on detector parameters was analyzed. In order to estimate the carrier transport mechanisms, differential resistivities and current-voltage curves were measured over a wide range of temperaturesi.e. 25 to 300 K. From the temperature dependence of the R₀A product, it was established that at high temperatures (150-300 K) the carrier transport is dominated by a recombination-generation mechanism. In low temperature region the excess current at forward bias is probably attributed to carrier tunneling via energy states distributed randomly within the forbidden gap. At reverse bias the leakage surface or volume currents dominate in the carrier transport.     

二元稀土系AB5型贮氢电极合金的放电容量与晶胞体积和4f电子浓度的关系

制备了6个系列通式为AαA‘1-αB5的RE(NiCoMnTi)5贮氢电极合金(其中，AαA‘1-α为La，Ce，Pr，Nd4个元素中任意2个的组合)，测定了它们在100次循环中的最大放电容量Cmax及部分合金的晶胞体积Vcell．结果表明：Cmax主要由Vcell决定，Cmax先随Vcell的增大而增加，在Vcell≈85．66x10^-^3。nm^3时达到一极大值，然后又随Vcell的增大而减小；同时，Cmax还与4f电子浓度ne4f／naRE有关，A侧具有相同4f电子浓度的合金其Cmax随4f电子浓度的变化趋势相似．     

Continuous electromagnetic separation of inclusion from aluminum melt using alternating current

A novel scheme about the continuous electromagnetic purification of aluminum melt was put forward based on the utilization of a square separation pipe and a 50 Hz alternating current to produce electromagnetic force. It is experimentally found that with electrical current of 400 A/cm^2, it takes only 10 s to remove 95% inclusion from aluminum melt. Comprehensive numerical simulations were carried out to investigate the dynamics mechanisms behind the process. The results show that the removal of inclusion is attributed to the cooperative effects of electromagnetic buoyancy and the secondary flow induced by the rotational electromagnetic force, and the removal efficient increases with the size of inclusion and the electrical current imposed. Theoretical predictions on the distribution and removal efficiency of inclusion were supported by the experiments.     

从热滤渣中富集提取贵金属

介绍了减压蒸馏脱硫，熔炼富集，高温悬浮氯气浸出处理热滤渣的工艺。其综合利用好，元素硫脱除率〉９２％，贱金属浸出率〉９５％，贵金属回收率〉９９％。贵金属富集物可并入贵金属精炼分离工段处理。     

Cation Effect on the Binary and Ternary Phase Behaviors of Double-Tailed Methanesulfonate Amphiphiles

A series of symmetrical dialkyl methanesulfonate amphiphiles [DiC _n CHSO ₃ ] _m M (n = 6, 7, 8) with different counter cations (M^m+ = H⁺, Li⁺, Na⁺, K⁺, Cu²⁺, Zn²⁺, Mg²⁺, Ca²⁺, Sc³⁺) were synthesized in five steps. Their solubility and critical micelle concentration (CMC) in water were determined highlighting a huge effect of the chain length and the nature of the cation. The hydrophilic–lipophilic balance of the surfactants were assessed with the phase inversion temperature (PIT)-slope method based on the deviation from the PIT of the reference C₁₀E₄/n-octane/0.01 M NaCl_(aq) emulsion through addition of increasing amounts of the dialkyl methanesulfonates. The hydrophilicity of the surfactants was thus ranked in terms of dPIT/dx_sulfonate. A “cation” scan with the [DiC ₆ CHSO ₃ ] _m M /benzene/water systems at f_w = 0.5 was finally performed confirming the hydrophilicity ranking obtained with the PIT-slope method. It revealed that the [DiC ₆ CHSO ₃ ] ₂ Mg behaves as a “Balanced Surfactant” able to form spontaneously a three-phase microemulsion system (Winsor III) just in the presence of water and oil, in the same way as the catalytic surfactant dimethyldioctylammonium molybdate, which has the same PIT-slope.     

Integration of Data from Liquid–Liquid Phase Separation Databases Highlights Concentration and Dosage Sensitivity of LLPS Drivers

Liquid–liquid phase separation (LLPS) is a molecular process that leads to the formation of membraneless organelles, representing functionally specialized liquid-like cellular condensates formed by proteins and nucleic acids. Integrating the data on LLPS-associated proteins from dedicated databases revealed only modest agreement between them and yielded a high-confidence dataset of 89 human LLPS drivers. Analysis of the supporting evidence for our dataset uncovered a systematic and potentially concerning difference between protein concentrations used in a good fraction of the in vitro LLPS experiments, a key parameter that governs the phase behavior, and the proteomics-derived cellular abundance levels of the corresponding proteins. Closer scrutiny of the underlying experimental data enabled us to offer a sound rationale for this systematic difference, which draws on our current understanding of the cellular organization of the proteome and the LLPS process. In support of this rationale, we find that genes coding for our human LLPS drivers tend to be dosage-sensitive, suggesting that their cellular availability is tightly regulated to preserve their functional role in direct or indirect relation to condensate formation. Our analysis offers guideposts for increasing agreement between in vitro and in vivo studies, probing the roles of proteins in LLPS.     

湿法脱硫塔一维传热传质性能模型理论与试验

为预测湿法脱硫系统(wet flue gas desulfurization, WFGD)浆液温度,提出湿烟气绝热饱和温度的概念,推导浆液温度与入口烟气温度及含湿量的函数关系。基于预测的浆液温度,建立脱硫塔内液滴运动、热质传递及压差分布一维耦合数学模型;分析脱硫系统三维不均匀性对于模型准确度的影响;用龙格-库塔法对模型进行迭代求解,探讨脱硫塔内主要运行变量(浆液颗粒直径、烟气入口温度及液气比)对传热传质的影响,获得相关参数的一维分布规律。为验证模型的正确性,分别进行现场测试和物模试验。结果表明,预测的浆液温度与现场实测温度有较好的一致性,最大相对误差为4.56%;浆液颗粒直径是影响传热传质的主要因素;颗粒在下降过程中速度迅速衰减,并趋向于最终不变值;烟气温度沿塔高呈指数规律分布。与模型预测温度及压力相比,物模试验温度分布与压力分布的最大相对误差分别为4.72%和6.46%。模型具有较高的准确度,对脱硫塔的设计、运行及SO₂的传质研究有指导意义。     

Coupling control on pillar stress concentration and surface cracks in shallow multi-seam mining

In order to ensure safe mining and reduce surface damage in shallow multi-seam mining, the failure characteristics of interburden strata with different coal pillars offset distances between pillars in the upper and lower seams, the distribution characteristics of stress concentration in coal pillars, and the development characteristics of stratum cracks and subsidence were investigated by physical and UDEC2 D simulation. Meanwhile, the effect of different coal pillar offset distances on stress concentration of coal pillar and development of stratum cracks were studied. Based on those results, a formula for safe mining and reducing surface damage was established, which provided a theoretical basis for safe and environmentally friendly mining in shallow multi-seam. According to the results, the optimal coal pillar offset distance(the side to side horizontal distance of the upper and lower coal pillars) between the upper and lower coal seams was developed to reduce the stress concentration of coal pillars and surface damage.The results of this study have been applied in Ningtiaota coal mine and have achieved good results in safe and environmentally friendly mining.     

CO2体积分数对燃煤细颗粒物在水汽环境中凝结长大的影响

为研究燃煤烟气中CO₂体积分数对细颗粒物在水汽环境中凝结长大效果的影响,建立了计算模型并搭建了实验平台,分别从理论计算和实验研究两方面探讨了CO₂体积分数对细颗粒物凝结长大效果的影响。结果表明:随着CO₂体积分数升高,混合烟气的热、质扩散系数均降低,生长管内平均过饱和度增加,细颗粒物长大效果明显;管壁温度越高,随着CO₂体积分数的提高,细颗粒物粒径越大。