基于积分法的热非平衡效应下剪切液膜流的表面波演化模型

当液膜表面同时存在热非平衡效应和切应力作用时,引发液膜流动不稳定的扰动及其影响将更为复杂。基于边界层理论,通过建立气液界面受热非平衡效应和切应力耦合作用的液膜流动的理论模型,采用包含弱非线性项的积分法,推导出热非平衡效应下剪切液膜流的表面波积分演化模型,模型中包括了相变强度、切应力、雷诺数和倾斜角度等不同参数的影响,为分析复杂边界条件下的液膜流的演化特征和稳定性提供了一种可借鉴的理论模型。     

Antioxidizing component,musizin, inrumex japonicus houtt

A substance with antioxidant properties was obtained from the hexane extract of roots ofRumex japonicus Houtt. The active component of the hexane extract was isolated and characterized as 2-acetyl-1,8-dihydroxy-3-methyl naphthalene, trivially named musizin (MUS). The antioxidant activities of MUS in six types of fats and oils were higher than that of butyl hydroxyanisole (BHA) and δ-tocopherol (δ-TOC). Together, TOC and MUS have a synergistic effect, because comparable amounts of either had lower antioxidant activity than various combinations of the two antioxidants. When we studied the antioxidant properties of a mixture of MUS and δ-TOC with methyl linoleate (MeLH), we found that the rates of destruction of the two antioxidants were comparable, but that their destruction occurred sequentially, with MUS first followed by δ-TOC, after which the oxidation of MeLH quickly occurred. Comparison of the antioxidant activity of MUS and its analogs suggests that only one of the two hydroxyl groups in MUS is involved in its antioxidant activit. Intermolecular hydrogen bonding may be involved.     

Loss of Curing Agent During Thin Film (Droplet) Curing of Thermoset Material

Recently, it has been reported by our group and others^1.2 that loss of curing agent is encountered during the curing of small droplets or thin films of amine cured epoxies. In our earlier study³ results were reported on loss of curing agent in small droplets used in conducting the rnicrobond, single fiber test for determination of interfacial shear strength (ISS). It was reported that use of a volatile curing agent (meta-phenylene diamine (m-PDA) with DGEBA resin) resulted in increasing amounts of curing agent being lost (as measured by T₈ of the cured droplets) with decreasing droplet size during the processing procedure. Droplets smaller than 150 micrometers were seen to lose up to 40% of the curing agent leading to alteration of the mechanical properties of the droplet and, therefore, causing measured values of ISS to be exceedingly low. Use of a less volatile curing agent (Jeffamine 700, a polyether diamine, Texaco Specialty Chemicals) in combination with DGEBA resin produced results which indicated that loss of curing agent was not occuring. This study was undertaken to show the relationships between film (or droplet) size and the amount of curing agent lost (during the processing) for three different aminecured epoxy systems.     

A Thermo-Mechanical Study of Some Epoxy Adhesives Subjected to Combined Dynamic and Static Stresses

The object of the present study was to investigate the effect of superimposed dynamic and static stresses on mechanical and thermal properties of some epoxy adhesives. It was found that combinations of shear creep and torsional oscillations, applied simultaneously to adhesive joints at temperatures within the glassy range of the adhesive, led to strengthening of the joints in shear and to an increase in the glass transition temperature of the adhesive. Similar loading stresses applied at temperatures close to the T_g of the adhesive, led to opposite effects on the above mentioned properties of the joints. The width of the glassy-rubbery transition of the adhesives increased, in the whole range of temperatures used in this study and for all epoxy compositions, as a result of subjecting the joints to superimposed dynamic and static stresses. The broadening of the glass transition was interpreted as a result of the stiffening of polymer network during the combined stressing experiments. A linear relationship was found between the area of endothermal peaks in the first DSC scan of specimens subjected prior to test to superimposed dynamic and static stresses at temperatures below T_g, and the shear strength of the joints. In agreement with this observation and with literature data, a linear relationship was revealed also between the glass transition temperature of the resins (measured in the first DSC scan) and the shear strength of the joints. Based on experimental observations and on some literature information, it was suggested that the strengthening of the joint, as well as the changes in thermal properties of the adhesives, are mainly due to physical processes, such as short-range orientation of network chains and an increase in intermolecular interaction between highly polar sites of the network. The possibility that superimposed stressing led to changes in chemical crosslinking was discussed but it seems that no such reactions occurred.     

光化学反应中的磁场效应 Ⅱ.电子转移光敏化1,2-二苯乙烯的顺反异构化反应

前文报道了外加磁场对吸附在硅胶表面上的芳砜光解反应的影响,本文报道外加磁场影响光化学反应的另一个例子——电子转移光敏化1,2-二苯乙烯的异构化。 近年来电子转移光敏化反应引起了有机光化学家们的极大注意。一些异构化、重排、裂解、氧化反应都可以通过电子转移机理敏化。电子转移光敏化的机理可以用(1)描述。图中A和D分别代表电子的受体和给体。     

目标追求的入世和出世对框架效应的影响

采用目标追求的入世、出世量表筛选出入世水平高组(70名)和低组(72)大学生,出世水平高组(68名)和低组(71名)大学生,探讨不同入世、出世水平大学生在奖学金申请、选修课和求职应聘三种决策任务领域上的框架效应及其在性别上的特点。结果发现:(1)不同出入世水平大学生在决策任务上的框架效应特点不同,入世水平高分组和低分组、出世水平高分组和低分组在奖学金申请问题上均出现了经典的框架效应;(2)在奖学金申请问题上,男性被试和女性被试的选择出现了明显的经典的框架效应。     

狭义相对论与钟慢效应关系再认识--纪念狭义相对论创立110周年

从爱因斯坦建立狭义相对论的科学方法与狭义相对论理论的逻辑构成入手,综合运用A· P·弗伦奇在国际著名的改革教材“美国麻州理工学院物理学导论丛书”第二卷《狭义相对论》中的研究观点和闵可夫斯基的四维时空理论,阐明狭义相对论与钟慢效应之间的正确关系。     

High-temperature oxidation of pure titanium in CO2 and Ar-10%CO2 atmospheres

The oxidation behavior of pure titanium has been investigated in the temperature range of 1000 K to 1300 K in CO₂ or Ar-10%CO₂. Optical microscopy, electron probe microanalyses, and X-ray measurements on the oxide scales formed during oxidation indicate that their structures are nearly independent of temperature and the corrosion atmosphere. The scales consisted of two layers, an external one and an internal one, having a rutile (TiO₂) structure. The parabolic rate law was confirmed for growth of the external scale and the permeation depth of oxygen in titanium with apparent activation energies of 266 and 226 kJ/mol, respectively. The rate-determining diffusion species in the oxidation processes are discussed.     

A high-temperature oxidation-resistant Fe-Mn-Al-Si alloy

To develop satisfactory alloys without Cr or Ni for high-temperature application up to 1100C, three alloys based on Fe-10%Al-Si with differing fourth (or fifth) element additions were oxidized in air at 1100°Cfor 24 hr. A low carbon, Fe-30Mn-10Al-Si alloy exhibited excellent high-temperature oxidation resistance. The total weight gain for 24 hr oxidation in air at 1100°C was only 1.03 mg/cm ². After air oxidation for 6 days at 1100°C, no nodule formation or breakthrough oxidation occurred. Post-oxidation SEM and EDAX examination showed that a thin, compact, protective alumina scale formed on the alloy.Visiting Scientist (People's Republic of China).     

Effects of laser beam energy and incident angle on the pulse laser welding of stainless steel thin sheet

This paper reports an experimental study of laser spot welding on stainless steel sheets. A pulsed Nd:YAG laser was used to weld the stainless steel specimen in the range of laser energy 0.6–1.2 J and incident angle 30–75° (the angle of the laser beam incident direction to the sheet surface). Metallography was applied to measure the cross-sectional size and shape of the welded spot. From the experimental results, it is found that as the laser energy increases, the penetration depth, bead length, and bead width of the welded spot increase. As the laser incident angle increases, the penetration depth and the bead width increase while the bead length decreases. The results illustrate that the shape and size of the welded spot depend not only on the laser energy, but also on the incident angle of laser beam.