全文获取类型
收费全文 | 11511篇 |
免费 | 943篇 |
国内免费 | 374篇 |
专业分类
电工技术 | 144篇 |
技术理论 | 2篇 |
综合类 | 713篇 |
化学工业 | 5139篇 |
金属工艺 | 404篇 |
机械仪表 | 187篇 |
建筑科学 | 748篇 |
矿业工程 | 289篇 |
能源动力 | 270篇 |
轻工业 | 1712篇 |
水利工程 | 427篇 |
石油天然气 | 657篇 |
武器工业 | 40篇 |
无线电 | 245篇 |
一般工业技术 | 859篇 |
冶金工业 | 658篇 |
原子能技术 | 112篇 |
自动化技术 | 222篇 |
出版年
2024年 | 34篇 |
2023年 | 127篇 |
2022年 | 323篇 |
2021年 | 343篇 |
2020年 | 403篇 |
2019年 | 310篇 |
2018年 | 275篇 |
2017年 | 380篇 |
2016年 | 429篇 |
2015年 | 419篇 |
2014年 | 594篇 |
2013年 | 618篇 |
2012年 | 755篇 |
2011年 | 764篇 |
2010年 | 571篇 |
2009年 | 652篇 |
2008年 | 530篇 |
2007年 | 679篇 |
2006年 | 637篇 |
2005年 | 543篇 |
2004年 | 451篇 |
2003年 | 438篇 |
2002年 | 346篇 |
2001年 | 312篇 |
2000年 | 251篇 |
1999年 | 266篇 |
1998年 | 172篇 |
1997年 | 139篇 |
1996年 | 147篇 |
1995年 | 143篇 |
1994年 | 112篇 |
1993年 | 86篇 |
1992年 | 75篇 |
1991年 | 76篇 |
1990年 | 68篇 |
1989年 | 50篇 |
1988年 | 61篇 |
1987年 | 43篇 |
1986年 | 47篇 |
1985年 | 39篇 |
1984年 | 40篇 |
1983年 | 19篇 |
1982年 | 23篇 |
1981年 | 13篇 |
1980年 | 12篇 |
1978年 | 4篇 |
1975年 | 2篇 |
1973年 | 1篇 |
1962年 | 1篇 |
1951年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 42 毫秒
11.
N. K. Savant P. S. Ongkingco I. V. Zarate F. M. Torrizo P. J. Stangel 《Nutrient Cycling in Agroecosystems》1991,28(3):323-331
A plunger-type, completely hand-operated applicator prototype, made of polyvinyl chloride (PVC), for deep placement of urea briquettes (UB), i.e., pillow-shaped urea supergranules with edges, in line transplanted rice has been developed for use by small-scale rice farmers. The field evaluation of the applicator was conducted in the Philippines during the 1989 dry season. The applicator consistently placed UB at proper depth (7 to 8 cm), which resulted in low concentrations of urea N (<7 ppm) in about 4 cm of floodwater 1 day after placement. These findings indicated that the prototype worked properly. Average work output of the applicator was 0.20 ha workday–1 and may increase with practice. The yields of irrigated transplanted rice in the field trials show that agronomic efficiencies of hand-placed UB and applicator-placed UB were equal and were superior to those of split-applied prilled urea. 相似文献
12.
E. Ya. Davydov I. S. Gaponova T. V. Pokholok G. B. Pariiskii G. E. Zaikov 《应用聚合物科学杂志》2008,108(1):128-133
The features of initiation of free radical reactions in polymers by dimers of nitrogen dioxide are considered. The conversion of planar dimers into nitrosyl nitrate in the presence of amide groups of macromolecules has been revealed. Nitrosyl nitrate initiates radical reactions in oxidative primary process of electron transfer with formation of intermediate radical cations and nitric oxide. As a result of subsequent reactions, nitrogen‐containing radicals are produced. The dimer conversion has been exhibited by estimation of the oxyaminoxyl radical yield in characteristic reaction of p‐benzoquinone with nitrogen dioxide on addition of aromatic polyamide and polyvinylpyrrolidone to reacting system. The isomerization of planar dimers is efficient in their complexes with amide groups, as confirmed by ab initio calculations. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
13.
David C. Whitehead Katherine M. Goulden Roy D. Hartley 《Journal of the science of food and agriculture》1985,36(5):311-318
The distribution of 10 nutrient elements was assessed in three fractions of herbage samples of perennial ryegrass, tall fescue, white clover and lucerne. The cell wall fraction, prepared by mechanical disintegration of undried material, contained the following proportions of the total herbage content of the major elements: N, 2.9–16.4%; P, 3.0–6.9%; S, 3.6–17.2%; Ca, 11.3–51.8%; Mg. 6.4–27.6% and K, 0.1–1.7%. Substantial though more variable proportions of the trace element cations, Fe, Mn, Zn and Cu were also present in the cell wall fraction. The extent to which the elements were soluble in water was assessed by analysis of the water-insoluble fraction prepared from freeze-dried samples of each herbage. The proportions of the total herbage content of the major elements soluble in water were: N, 30–57%; P, 80–92%; S, 35–71%; Ca, 48–69%; Mg. 65–83% and K, 90–96%. With the trace element cations the proportions soluble in water were more variable, though they were generally less than 70% of the total. The extent to which the various elements were soluble in 80% aqueous ethanol was assessed by analysis of the insoluble fraction prepared from freeze-dried materials. With each of the major elements, smaller proportions of the total herbage content were soluble in 80% ethanol than in water, which may reflect in part the lower solubility of proteins and pectin. With the trace element cations, the differences in solubility between 80% ethanol and water were generally small and inconsistent. 相似文献
14.
介绍了马钢A/OO生物脱氮装置的工艺流程、工艺条件及影响因素,探讨了A/OO生物脱氮工艺试运行中存在的问题和解决措施。 相似文献
15.
Large amounts of water containing-ammonium nitrogen(NH4+-N)have attracted increasing attention.Catalytic ozonation technology,involving the generation of hydroxyl radical(OH)with strong oxidation ability,was originally utilized to degrade organic-containing wastewater.In this paper,Ce/MnOx composite metal oxide catalysts prepared with different preparation conditions were used to degrade wastewater containing inorganic pollutant(NH4+-N).The as-prepared catalyst features were characterized using X-ray diffraction(XRD),Brunauer-Emmett-Teller method(BET),scanning electron microscopy(SEM),energy dispersive X-ray spectroscopy(EDS),Fourier transform infrared spectroscopy(FTIR),X-ray photoelectron spectroscopy(XPS)and H2-temperature programmed reduction(H2-TPR)techniques.The results show that the catalyst,prepared by conditions with precipitant Na2CO3 and Ce/Mn molar ratio 1:2 calcined at 400℃for 3 h in pH 11.0,displays the optimal performance,with the removal rate of NH4+-N and selectivity to gaseous nitrogen,88.14 wt%and 53.67 wt%,respectively.The effects of several operating factors including solution pH,initial NH4+-N concentrations and scavengers were evaluated.In addition,XRD patterns of catalyst with the best performance and the comparative study on decontamination of NH4+-N by various processes(O3,catalyst and catalyst/O3)show that the primary metal oxides are CeO2 and MnO2 in Ce/MnOx composite metal oxide catalysts,which have a synergistic effect on the catalytic ozonation of NH4+-N,and the new phase MnO2 plays a great role.After 5 consecutive use cycles,the degradation efficiency is declined slightly,and can still achieve better than 70 wt%over 1 h reaction.Additionally,the application of catalytic ozonation for actual wastewater on the removal rate of NH4+-N was investigated.Possible mechanism and degradation pathway of NH4+-N were also proposed.In a word,the application of CeO2-MnO2 composite metal oxide catalysts in catalytic ozonation can be regarded as an effective,feasible and promising method for the treatment of NH4+-N. 相似文献
16.
Simulation of nitrogen dynamics and biomass production in winter wheat using the Danish simulation model DAISY 总被引:14,自引:0,他引:14
S. Hansen H. E. Jensen N. E. Nielsen H. Svendsen 《Nutrient Cycling in Agroecosystems》1991,27(2-3):245-259
A dynamic simulation model for the soil plant system is described. The model includes a number of main modules, viz., a hydrological model including a submodel for soil water dynamics, a soil temperature model, a soil nitrogen model including a submodel for soil organic matter dynamics, and a crop model including a submodel for nitrogen uptake. The soil part of the model has a one-dimensional vertical structure. The soil profile is divided into layers on the basis of physical and chemical soil characteristics. The simulation model was used to simulate soil nitrogen dynamics and biomass production in winter wheat grown at two locations at various levels of nitrogen fertilization. The simulated results were compared to experimental data including concentration of inorganic nitrogen in soil, crop yield, and nitrogen accumulated in the aboveground part of the crop. Based on this validation it is concluded that the overall performance of the model is satisfactory although some minor adjustments of the model may prove to be necessary. 相似文献
17.
In order to analyse iron phosphate complexes and gel-like phases encountered in the single superphosphate process, experiments were performed with a free-Al, Fe apatite crystal of Durango from Mexico phosphate rock and sulfuric acid. Reaction products were studied by X-ray diffraction and surface analysis methods namely X-ray photoelectron spectroscopy and scanning electron microscopy. Results show that in a free Al, Fe-system, part of the Ca(H2PO4 )2.H2O (MCPM) forms before precipitation of any CaSO4(CS) and gel-like phase such H2SO4.yH3PO4.xH2O is formed. When iron is added, the precipitation rate of (CS) and (MCPM) increases and Fe3(H3O)H8(PO4)6.6H2O is formed. When Fe and Al are added, a gel-like phase is quickly formed with a molar ratio that changes with time and develops into crystalline compounds. The composition of this gel may be represented as a mixture of two phases: H2SO4.yH3PO4.xH2O and a gel containing Al-Fe-Si. 相似文献
18.
The group-contribution method for vapor pressures of hydrocarbons and organic compounds containing nitrogen or sulfur, based on the kinetic theory of fluids, is revised and extended to include new groups containing nitrogen or sulfur. Good representation is obtained for vapor pressure data in the region 1.30-270 kPa. The method may be used to estimate vapor pressures and enthalpies of vaporization for those organic fluids containing nitrogen or sulfur, where no experimental data are available. 相似文献
19.
全国48家化肥催化剂制造厂总能力为57Kt/a,产量近30kt/a,设备利用率不到50%。平均万吨氨耗催化剂10.36t,高于国外5.60t水平。现生产31个品种203个型号的催化剂中有103种经部级鉴定,但经常使用的约50种。目前化肥催化剂工业水平与国外相比还存在四方面差距。 相似文献
20.
针对我国化肥生产企业质检机构的现状 ,结合国家相关政策的要求 ,就如何搞好化肥企业质检机构的管理提出了诸多指导性意见 相似文献