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71.
UHMWPE/蒙脱土纳米复合材料结构与流动性的关系 总被引:9,自引:0,他引:9
采用甲基丙烯酰氧乙基三甲基氯化铵对微米尺度的蒙脱土进行离子交换,所得有机蒙脱土与少量引发剂和超高分子量聚乙烯(UHMWPE)共混后,在双螺杆挤出机上进行反应挤出,得到了具有一定流动性能的UHM—WPE/蒙脱土纳米复合材料。该纳米复合材料熔体的流动性能较UHMWPE高出许多;用X衍射、透射电子显微镜等表征方法研究了这种纳米复合材料的相结构,通过稳态和动态流变试验研究了其流变性能与蒙脱土含量的关系,分析了UHMWPE熔体大分子解缠结机理。 相似文献
72.
Chlorinated ground rubber tire (Cl‐GRT) particles were used as filler in a plasticized polyvinylchloride (PVC) to develop a melt‐processable rubber composition. Physical properties of the Cl‐GRT‐filled PVC compound showed improvement compared to the nonchlorinated counterpart. Interaction between Cl‐GRT and PVC was examined on the basis of results of stress relaxation, dynamic mechanical thermal analysis, and solvent swelling studies. The Cl‐GRT could be loaded upto 40 parts per hundred parts of PVC, and the composition still retains the elastomeric characteristics. The Cl‐GRT‐filled composite was found to be reprocessable like the unfilled PVC compound. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 84: 622–631, 2002; DOI 10.1002/app.10352 相似文献
73.
Hot melts show many advantages over other adhesives, for instance, their lack of solvent and their very short setting time just by cooling. The weak point of hot melts in comparison to thermosetting resins is their limited thermal resistance. There is no doubt that the high performance hot melts on the basis of polyester and polyamide show a better heat performance than the widely-used rubbery hot melts. Nevertheless, it is true that the thermal resistance is limited by the melting point of the hot melt. To improve the heat performance, without losing the favourable hot melt properties, crosslinkable hot melts have been created. For the example, copolyamide/blocked isocyanate blends, it can be shown that crosslinkable hot melts are achievable in a wide range of reactivities. After curing, which takes place during the bonding process, these hot melts withstand temperatures of over 220°C even if the melting point of the initial hot melt was 100°C. 相似文献
74.
With superimposing a sine vibration of displacement on the extruding direction of a polymer melt, the characterization formula of the shear rate of a polymer melt within a capillary was set up. By making use of the experimental equipment of a constant velocity type dynamic rheometer of capillary (CVDRC) designed by the authors, the calculating steps of the shear rate of the polymer melt at the wall of the capillary under a vibration force field were established. Through measuring and analyzing the instantaneous data of capillary entry pressure, capillary volume rate, and their phase‐difference under the superimposed vibration, the polymer melt's shear rate at the wall of the capillary can thus be calculated. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 95: 1056–1061, 2005 相似文献
75.
针对暗原色先验算法在处理含有大面积明亮区域的有雾图像时,复原图像会产生严重色彩偏移的不足,提出了一种基于像素点的透射率修正方案.在分析暗原色先验去雾原理以及复原图像色彩偏移成因的基础上,对去雾模型进行推导,使用暗通道亮度与大气光数值接近度及像素通道间数值接近度作为明亮区域判定机制,得出更具普适性的透射率求取方法.明亮区域采用容差机制纠正错误估计的透射率,非明亮区域仍采用原透射率求取方式,并首次将改进算法应用到雪天模糊图像清晰化中.实验结果表明,改进算法使去雾图像清晰自然,可有效修正色彩失真. 相似文献
76.
Peter Tatarko Fabrizio Valenza Hakan Ünsal Alexandra Kovalčíková Jaroslav Sedláček Pavol Šajgalík 《Journal of the European Ceramic Society》2021,41(5):3051-3060
The wettability and infiltration of molten ZrSi2 and ZrSi2-Lu2O3 alloys into Cf/SiC and B4C-infiltrated Cf/SiC composites were investigated to understand the interfacial interactions that occur during the development of Cf/SiC-ZrC and Cf/SiC-ZrB2-ZrC-Lu2O3 materials. A significant evaporation of Si from the liquid affected the wetting behaviour of the alloy when tested in a vacuum at 1670 °C. The better wetting and spreading of the alloy over the surface was observed for the composites with lower overall porosity (12 %). On the other hand, the formation of an outer dense layer, followed up by the uniform infiltrated region up to ~ 1 mm was observed for the Cf/SiC with higher porosity (21 %). The infiltrated alloy reacted with SiC matrix to form ZrC or with B4C-infiltrated SiC matrix to form ZrB2-ZrC-SiC. The Lu2O3 particles were not wetted by the melt, and were pushed away of the reaction zone by the solidification front. 相似文献
77.
78.
Electrochemical corrosion measurements have been carried out with Pt-containing and Pt-free Al-diffusion coatings on IN 738 LC in a 90Na2SO4+ 10K2SO4 (mol%) melt at 1173 K. Pt improves the resistance to basic fluxing while there are no significant differences between both coating types in their resistance to acidic fluxing. The corrosion resistance of the Pt-containing coating is also higher in the passive potential region where protective scales rich in Al2O3 are formed. The reason for the different behavior of both coating types appears to be related to the high corrosion resistance of the Pt-rich surface layer of the coating and an increased Al2O3 content in the scale of the Pt-containing type. 相似文献
79.
冷坩埚熔铸技术的研究及开发现状 总被引:1,自引:1,他引:1
综述了冷坩埚技术的原理和特点、目前的研究及开发现状。冷坩埚具有无污染,可熔化高熔点金属,制备的材料组织均匀等优点。冷坩埚技术在以下领域得到广泛的研究和应用:与熔化技术相结合能高纯均匀熔炼活性金属,通过起熔材料能制备陶瓷材料;与连铸技术相结合能进行冷坩埚电磁连铸技术,提高铸锭表面质量,改善内部组织;与定向凝固和连铸技术相结合的冷坩埚定向凝固技术已成功进行钛合金的定向凝固;与多晶硅制备技术相结合能连续制备多晶硅,杂质含量少;与雾化沉积技术相结合的冷坩埚雾化沉积技术具有熔化合金种类多、适用范围广的优点。冷坩埚的自身特点决定了其必将更受重视和广阔发展前景。 相似文献
80.
盒形塑件的几何构型与计算机充模流动模拟 总被引:3,自引:0,他引:3
基于Hele_Shaw流动数学模型 ,给出了构造3D塑件CAD模型并向CAE模型转换的方法和技术 ,通过对塑件进行有限元网格的剖分以及注射成型过程的数值模拟 ,得到了减少塑件充模流动成型缺陷 ,改进熔体充模效果及产品设计的技术方法 相似文献