Particulate organic matter transport in the lower Colorado river,South-Western USA

The lower Colorado River from Laughlin, Nevada, to the border with Mexico is one of the most regulated rivers in North America. An analysis of particulate organic matter (POM) transport through the system was made to determine POM concentrations, composition and point of origin, as well as to determine the effect dams had on this transport. Particulate organic matter concentrations generally increased from upstream to downstream, and were dominated by very fine organic detritus (< 25μm size fraction). Reservoirs released more POM than they received during spring and summer, but less during autumn and winter. Reservoirs recycled POM, taking in organic detritus and discharging small limnoplankton. Backwater complexes functioned as filters during storm events, trapping coarse material and releasing fine material. Agricultural drains made only minor contributions of POM, but provided important nutrients for in-channel production of POM. Water diversions forced POM off-channel, whereas sluicing operations reduced inorganic loads in the canals. Despite the presence of six mainstem dams, the lower reaches support a diverse assemblage of detritivorous fishes, similar to that found in the lowermost reaches of natural, unregulated rivers. The food base for this fishery stems from autochthonous production of POM.     

Enhancement effect of organic solvents on the line intensity of lower power argon ICP-AES：Part I On the nebulization procedure

The procedure of nebulization was studied with the introduction of ethanol into a lower power argon ICE It was found that as ethanol introduced, the physical properties of solutions changed, which results in an improvement on the nebulization efficiency. An empirical relationship between the concentration of the aerosol and the solution properties ( viscosity, density, and surface tension) is presented.     

水土保持工程施工阶段的设计变更

通过对水土保持工程施工阶段设计变更原因的分析，指出水土保持生态工程施工阶段变更的必要性和建设、监理单位对变更管理的重要性。通过对变更设计的程序和原则进行的分析，阐述了变更设计涉及的几个主要问题。     

上海市吴淞工业区大气PM2.5水溶成分的元素分析及细胞毒性研究

通过ICP-MS测定了上海市吴淞地区大气PM2.5水溶成分金属元素含量,通过四唑盐(MTT)测定细胞存活率,通过超氧化歧化酶(SOD)和丙二醛(MDA)两个指标测定细胞氧化损伤,琼脂糖凝胶电泳测定细胞内DNA损伤,流式细胞仪(Flow cytometry)检测细胞凋亡和周期等实验研究了大气PM2.5水溶成分的细胞毒性.实验结果表明:PM2.5可溶成分中Zn元素含量最高,PM2.5在一定浓度范围内能导致细胞死亡,引起细胞的氧化损伤,影响DNA的复制,阻碍细胞增殖,但没有诱导细胞凋亡.PM2.5中可溶金属离子对细胞毒性表现为联合作用.     

Heterogeneous Enzyme Mimics Based on Zeolites and Layered Hydroxides

Careful combination of a metal compound,a ligand and an inorganic support material leads to supramolecular catalysts that mimic the structural, organizational and functional aspects of enzyme activity.After discussing essential features of metalloenzyme-catalyzed reactions and coordination chemistry in inorganic hosts, we present examples of supramolecular materials selected from our own work that eventually resulted in useful catalysts for organic transformations in the liquid phase.     

半空间饱和土中瑞利波特性

通过对饱和土中波的运动方程及连续方程分析，推导了饱和土中瑞利波特征方程，讨论了半空间饱和土中瑞利波波速度的弥散特性，以及位移和孔压分布情况。     

间苯二酚－甲醛有机气凝胶的结构控制研究

以间苯二酚（Ｒｅｓｏｒｃｉｎｏｌ）－甲醛（Ｆｏｒｍａｌｄｅｈｙｄｅ）为原料，用溶胶－凝胶法和超临界干燥工艺制备了纳米多孔ＲＦ有机气凝胶。系统研究了原料配比、催化剂的使用、反应温度及溶剂用量等因素对ＲＦ气凝胶凝结时间和结构的影响，可以实现对该材料的结构进行纳米尺寸上的控制，从而为该材料的应用开发奠定了基础。     

VNS反应合成LLM-116

以1,3-二硝基吡唑为原料,经热重排、氨气中和得到3,5-二硝基吡唑铵盐,然后酸化得到3,5-二硝基吡唑。以三甲基肼碘化物（TMHI）作为异常亲核取代氢（VNS）反应试剂,与3,5-二硝基吡唑在叔丁醇钾为催化剂,利用VNS反应合成4-氨基-3,5-二硝基吡唑（LLM-116）。采用红外分析、核磁共振、元素分析等仪器鉴定了其结构,讨论了VNS反应机理及影响因素。通过实验,得出最佳VNS反应试剂为TMHI,反应时间为4h,反应温度为25℃,收率达到60%。