Polymers dynamics of the nonfluoro,nano-brush repelling agent with self-stratifying property in water-based coatings

While perfluoroalkyl acids (PFAAs), also known as C8s, are used extensively in textile repellent coatings, concerns have arisen for their carcinogenicity and hazardous effects on the environment. In this study, a novel water-based, nonfluoro, and nanobrush textile repelling agent was prepared by conventional sol–gel chemistry using amorphous fumed silica and n-octyltriethoxysilane as the starting materials. Minimal interaction between the designed repelling agent and marketed water-based resins was confirmed using linear viscosity region (LVR) analysis and asymmetric-flow field-flow fractionation (AF4), suggesting the self-stratification potential of the repelling agent. More specifically, the repelling agent exhibited excellent compatibility and self-stratifying ability with a force-emulsified acrylic-based resin, affording a water contact angle of 104.3° when incorporated at 7% solid content. Performance tests carried out on thermoplastic polyurethane (TPU) revealed excellent adhesion (100/100) of a final formulation, and a significant increase in water contact angle from 80.1° to 103.8° after treatment. In addition, the fouling area after the removal of a submerged sample from a mixture of slurry, polymer, and oil decreased from 48 to 1% when the repelling agent was added. Moreover, the sludge-fouling property remained unchanged after 1000 cycles of abrasion. These findings demonstrate the potential of the described nonfluoro, nanobrush repelling agent as an environmentally safe alternative for use with commercial resins, in turn realizing a fully water-based hydrophobic coating. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 48003.     

Comparative analysis on performance of vertical drain improved clay deposit under vacuum or surcharge loading

This paper presents two well-instrumented large-scale field tests of PVD-improved soft soil with vacuum and surcharge preloading, respectively. The two large-scale field tests were conducted adjacent to each other with the same preload. A comparative analysis was performed to investigate the performance of subsoil (i.e., the ground settlement, the layered settlement, the lateral displacement of subsoil and pore water pressure) under vacuum preloading and equivalent surcharge preloading. Some design methods were verified based on the field data. Cone Penetration Tests (CPT) and Vane Shear Tests (VST) were conducted to assess the improvement effects on subsoil after preloading. The results showed that as compared with surcharge preloading, vacuum preloading mitigated the differential settlement of the ground. The vacuum pressure transmitted into the soil with a minor loss through the PVD length. From a practical point of view, the improvement effects by vacuum preloading and surcharge preloading were similar in terms of influence depth and soil strength based on the in-situ tests.     

葛洲坝水利枢纽泄水建筑物进水口冲磨与修复

葛洲坝水利枢纽工程已运行20余年，近年水下检查中发现泄水建筑物进水口存在不同程度的冲磨，有些已威胁到建筑物安全运行，分析冲磨原因和探讨修复材料和手段是非常重要的，本文就此问题提出一些看法和建议供参考。     

宁夏宁东供水工程主机设备形式参数选择与国际招标

宁东供水工程供水水泵共有卧式和立式离心泵2种方案可供选择,也是工程论证时争论的焦点,经综合比较及主机设备的国际招标,最终确定了奥地利安德里兹公司的卧式双吸中开式离心泵为宁东供水工程的供水水泵。     

恢复邢台百泉泉水流量可行性研究

通过百泉泉区天然状态与超采状态下的水环境对比分析,并对岩溶水补给量和开采量进行计算,阐述恢复邢台百泉泉水流量的可行性,随着“引朱济邢”和“南水北调”供水工程的实施,邢台百泉水生态环境的恢复将变为现实。     

曲沃县水资源开发利用现状及对策

文中对曲沃县水资源开发利用现状进行了认真分析，并从思想观念、管理体制、管理模式上提出了问题，为解决问题提出了相应对策。     

基于投影寻踪的径向基函数网络在参考腾发量预测中的应用

径向基函数网络(RBFN)已广泛应用于参考腾发量预测等领域，但常用的K均值聚类和自组织特征映射等方法在求取径向基函数网络隐层节点中心时存在较大不足。针对这一问题，本文引入投影寻踪方法，在投影降维的基础上实现对大量高维数据的聚类，建立了基于投影寻踪的径向基函数网络模型，并将该模型应用于山西潇河灌区参考腾发量的预测，研究了不同气象因子输入对参考腾发量预测精度的影响。结果表明，基于投影寻踪的径向基函数网络具有较强的适用性，只需使用最高温度、最低温度、日照时数和旬序数作为输入因子，就能以较高的精度预测参考腾发量。     

大同市水资源开发利用状况与承载能力的思考

文中分析了大同市水资源开发利用的状况，并对水资源承载能力的有关问题进行了讨论。     

新安江电站进水口快速闸门动水闭门鉴定试验

本文叙述了应用现代科学方法和实验原型观测技术对新安江水电站进水口快速闸门进行安全检测鉴定，并介绍了水电站快速闸门动水闭门试验程序，对水电站快速闸门试验及相关鉴定有重要参考意义。     

双河油田注入水适应性及注水井酸化解堵研究

考察了双河油田双河联、江河联注入水堵塞地层的因素;膨胀性黏土，悬浮固体颗粒。细菌及悬浮污油。含膨胀性黏土的双河南、双河北及不含膨胀性黏土的双江岩心粉，在注入水中相对于地层水中的体积膨胀度分别为14．5％、11．1％及0．02％；注入100PV不含悬浮颗粒的等体积比地层水、注入水混合水使双河、双江岩心渗透率分别下降7％和4％、9％和7％。注入水中悬浮颗粒引起岩心渗透率下降，粒径越大、颗粒浓度越大、注入量越大，则渗透率越低。在粒径2．1μm或颗粒浓度3mg／L前后下降幅度变化较大。注入水中硫酸盐还原菌引起岩心渗透率下降，含菌量越大则渗透率开始下降时的注水量越小，注入含菌50个／L的水100PV使岩心渗透率下降7％。岩心对注水合油量敏感，注入含油量20mg／L的水50PV使岩心渗透率下降20％。在岩心注水实验中渗透率下降最严重的是双河南岩心，其次是双河北岩心．江河岩心较轻，注入精细过滤水的双河北岩心渗透率下降大大减少．说明悬浮固体是造成注水堵塞的主要因素。为了解除双河油田注水井的堵塞，研制了含黏土稳定剂、缓蚀剂、铁离子稳定剂、互溶剂的土酸液，与南阳油田使用的低伤害酸液一起，用于1口注水井的解堵，效果良好。图7表4参5。