Microwave heating synthesis of HgS and PbS nanocrystals in ethanol solvent

A novel route was developed to prepare PbS and HgS nanocrystals in ethanol solvent in the presence of sodium hydroxide by microwave heating method. PbS and HgS nanocrystals were obtained with an average size of approximately 10 and 6 nm, respectively. In the reaction, mercury acetate and lead acetate were used as mercury and lead source; sulfur powder was employed as chalcogenide source. The products were characterized by X-ray powder analysis (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS) and UV–Vis absorption spectroscopy. The probable mechanism was presented.     

陕北富县探区天然气藏钻井液屏蔽暂堵技术

陕北富县探区上古生界储层属低孔、低渗的致密储层,下古生界主要储集空间为溶蚀孔洞和裂缝,孔洞多为1～3 mm的小孔,裂缝宽度为0.2～7.0 mm,油气主要聚集在裂缝中.优选出了由复合暂堵剂CXD、憎水性屏蔽剂DYC和表面活性剂ABA组成的屏蔽暂堵配方,其中CXD具有架桥作用并对裂缝性储层有独特暂堵效果,DYC有浊点效应、能在井壁上快速形成阻止滤液侵入的油膜,ABA能减少水锁损害.加入暂堵剂后的钻井完井液,抑制性增强,页岩回收率在90%以上;高温高压滤失量降低,滤饼薄而韧、光滑;岩心静态渗透率恢复值大于90%;滤饼摩阻系数降低.富古6井通过使用该完井液,堵塞比和表皮系数都在轻微污染范围内,井径扩大率比其它井有不同程度的降低,表明优选出的屏蔽暂堵钻井完井液,能很好地保护陕北探区天然气藏.     

油罐冒罐事故的原因分析及预防

通过事故实例分析，阐述油罐冒罐事故的原因，并针对原因提出要加强操作人员的责任心教育，完善各项规章制度，不断提高操作人员素质，严格遵守岗位操作规程，及时消除设备缺陷、完善罐区硬件设施和罐区实行现代科学管理等项措施。     

EDA介质快慢横波时差和振幅-方位曲线的实验分析

在含垂直定向裂隙的各向异性（EDA）介质中，地震快、慢横波传播的时差及振幅随裂隙（缝）方位变化曲线能反映裂缝的密度、走向和介质的性质，这对多波地震资料的处理、解释有着重要意义。但受观测条件限制以及噪声的影响，在横波分裂记录上，同相轴往往会出现扭曲、倾斜和不规则抖动等现象，给快、慢横波时差的求取和振幅-方位曲线的绘制带来误差。设计了EDA介质物理模型，并利用岩石超声波测量系统获得了快、慢横波记录；分析记录可知，在相同传播方向的分裂横波具有走时和传播速度不随裂缝方位变化的恒定性特征；以此为基础，提出了利用平均法和瞬时振幅法来计算快、慢横波的走时时差和绘制振幅-方位曲线，以提高精度。利用物理模型实验得到的2个正交横波（S1波与S2波）的快、慢横波记录，分别用平均法和瞬时振幅法计算了快、慢横波走时的平均值、时差和均方差，并绘制了相应的振幅一方位曲线。结果表明，采用上述2种方法，消除了同相轴扭曲、倾斜和不规则抖动等对计算结果的影响，时差的计算是可靠的，振幅一方位曲线的绘制是合理的。     

大电流监测信号提取的光收发及信号处理

近年来,大电流的监测成了人们十分关心的问题,这是由于大电流有强磁、高压、电流大等一系列的直接监测所不能克服的问题。这就需要把高压大电流的强电信号,经过提取后变成能在实验室中直接观测的弱电信号。为此,如何从高压大电流的信号中提取出随实时信号变化而实时变化的小信号就变成了一个关键问题。详细介绍了监测信号提取的光收发电路原理和后续信号处理电路,分析了各部分的作用,给出了必要的分析结果。     

聚合物-蒙脱石纳米复合材料的制备、结构与性能

从结构与性能的观点出发,将聚合物-蒙脱石纳米复合材料划分为插层型、层离型和混合型(插层型+层离型),探讨了影响蒙脱石纳米化的因素,提出了蒙脱石纳米化中值得注意的几个问题.     

Thermophysical Properties of Binary Mixtures of Methyl Methacrylate+Di-Ethers (Ethyl, Isopropyl, and Butyl) at 298.15 and 308.15 K

Experimental data for the densities, dynamic viscosities, sound speeds, and relative permittivities and for three binary systems of methyl methacrylate (MMA)+di-ethers (ethyl, isopropyl, and butyl) at 298.15 and 308.15 K and at atmospheric pressure are reported. The mixture viscosities are correlated by Grunberg–Nissan, McAllister, and Auslander equations over the complete composition range. The sound speeds for the mixtures are also calculated by using free length and collision factor theories, and Nomoto and Junjie equations. From the measured primary properties, deviation functions such as deviations in viscosities, sound speeds, relative permittivities, molar polarizations, excess isentropic compressibilities, and molar electrical susceptibilities were calculated, and the compositional dependence of each of the functions was expressed with a Redlich–Kister type equation. The variation of the Kirkwood correlation factor was determined over the complete composition range.     

方波扫描路径确定声源声功率误差特性分析

改进了矩形测量面方波扫描路径测量声功率的误差模型 ,以单极子、偶极子及四极子声源为例 ,给出了扫描方向、测量面离声源的距离及扫描线的密度的选取对理论误差的分布图形。分析结果表明 :对选定的测量面 ,在扫描线密度小的情况下 ,通过调整声源离测量面的距离 ,可以在声源近处找到一个最优点或较优点 ,使理论误差为零或很小 ;在绝大多数情况下 ,沿测量面长边扫描误差比沿短边扫描小。     

Nonlinear coupled problems in dynamics of shells

The coupled system of three partial differential equations governing a flexible shallow shell dynamics is analysed. No any prior assumptions about the temperature distribution through the shell thickness are applied. The efficiency of the method used here when applied to the solution of integral-differential equations with different dimensions (three-dimensional equations related to the Kirchhoff-Love model) and of different type (heat transfer equations and the hyperbolic equations of shell theory) is demonstrated. Many computational results are reported and discussed.     

圆管流动的二次转捩

利用直接数值模拟方法求解N-S方程来研究空间发展的圆管转捩,计算中雷诺数Re选定为3000。在局部壁面引入的周期性吹吸(PSB)扰动作用下,圆管中首先出现了塞流结构,并向下游迁移,同时有稳定的流向条带结构形成;在塞流结构离开计算域后,随着扰动的不断发展,流向条带结构逐渐破裂失稳,圆管流动出现了第二次转捩,这是一种新的转捩形式,我们称之为“二次转捩”。