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41.
David J. Lawrence Brianna L. Smith Cameron D. Collard Keyton A. Elliott Kyle L. Fakhoury Jeffery D. Mangold Anna N. Soyka 《International Journal of Hydrogen Energy》2021,46(2):1642-1655
Monolithically-integrated tandem photoanodes were fabricated on substrates consisting of epitaxial n-GaAs1-xPx (x ? 0.32) grown on n+-GaAs wafers. A p+-n junction photovoltaic (PV) cell was first formed by zinc diffusion into the n-GaAs0.68P0.32 from a deposited ZnO coating. After diffusion the ZnO serves as a transparent electrical contact to the resulting p+-GaAs0.68P0.32 surface layer. Transparent, conducting SnO2:F provides chemical and mechanical protection for the ZnO and the underlying PV cell, and it electrically connects this cell to a top BiVO4 photocatalyst layer. In some photoanodes, a WO3 thin film was interposed between the SnO2:F and BiVO4. All oxide coatings were produced by ultrasonic spray pyrolysis except WO3, which was spin coated. Unassisted (unbiased) solar water splitting was achieved, with a solar-to-hydrogen efficiency approaching 2%, without addition of any co-catalyst to the BiVO4 surface. This work can provide insights to other researchers regarding scalable, low cost approaches for the planar monolithic integration of oxide photoanode materials with PV cells to create new tandem devices. 相似文献
42.
《International Journal of Hydrogen Energy》2020,45(15):8605-8617
Single phase, crystalline NaFeTiO4 with tunnel structure is prepared by a solid state method and explored as a novel photocatalyst for the first time. Structural, optical and morphological properties of NaFeTiO4 are investigated by various characterization techniques such as X-ray diffraction (XRD), scanning & transmission electron microscopy (SEM & TEM), Energy dispersive X-ray spectroscopy (EDS), N2 adsorption-desorption study (BET), UV-vis, X-ray photoelectron, X-ray absorption (UV-vis DRS, XPS and XANES) and photoluminescence (PL) spectroscopy. The interfacial charge transfer ability of the prepared n-type NaFeTiO4 was also investigated by transient photocurrent response and electrochemical impedence spectroscopy which proved to be an efficient tool for better understanding of electronic properties of NaFeTiO4. The photocatalytic efficiency of NaFeTiO4 is evaluated for decomposition of methylene blue (MB) and Rhodamine B (RhB) dyes as well as for H2 evolution through water splitting reaction under visible light. NaFeTiO4 exhibits efficient charge separation properties, excellent photocatalytic activities and reusability. 相似文献
43.
The analysis of 124 curves obtained in short-term tensile tests demonstrate that they can be described by varying strain hardening and softening characteristics. Different stress–strain curves can be produced at invariable yield strength and ultimate strength and interrelated proportional variations of the above characteristics. To determine some specific stress–strain curve, it is necessary to take account of yield strength and ultimate strength as well as strain corresponding to the latter. The relations between yield strength, ultimate strength and hardening and their practically complete absence between these parameters and softening were statistically established. 相似文献
44.
45.
水力射孔对套管强度的影响研究 总被引:4,自引:2,他引:2
水力射孔技术是一种新型的完井方式,深穿透水力射孔技术辅助定向水力压裂可以实现油气层改造和油气井增产。但是,水力射孔套管会在孔眼处造成应力集中,使得局部应力过大而削弱了套管和水泥环的强度,可能会影响套管的使用寿命。因此,文章利用有限元软件建立了射孔套管的三维有限元模型,分析了水力射孔后套管管体的应力分布,重点研究了水力射孔参数-孔密、孔径、孔深、射孔方位角等对套管强度的影响规律。分析结果表明,沿着最大水平地应力方向深穿透水力射孔,选择合适的孔密、孔径可将射孔对套管的损害降至最小。研究结果为提高水力射孔完井设计水平提供了一定的参数依据。 相似文献
46.
邱文平 《理化检验(物理分册)》2003,39(8):409-410
介绍了一种用三点弯曲试验法测定高性能大尺寸粘接永磁体粘合强度的方法,及利用布氏硬度计的加载系统,实现100%检验粘接质量的方法。 相似文献
47.
Communicating with sensors has long been limited either to wired connections or to proprietary wireless communication protocols. Using a ubiquitous and inexpensive wireless communication technology to create Sensor Area Networks (SANs) will accelerate the extensive deployment of sensor technology. Bluetooth, an emerging, worldwide standard for inexpensive, local wireless communication is a viable choice for SANs because of its inherent support for some of the important requirements – low power, small form factor, low cost and sufficient communication range. In this paper we outline an approach, centered on the Bluetooth technology, to support a sensor network composed of fixed wireless sensors for health monitoring of highways, bridges and other civil infrastructures. We present a topology formation scheme that not only takes into account the traffic generated by different sensors but also the associated link strengths, buffer capacities and energy availability. The algorithm makes no particular assumptions as to the placement of nodes, and not all nodes need to be in radio proximity of each other. The output is a tree shaped scatternet rooted at the sensor hub (data logger) that is balanced in terms of traffic carried on each of the links. We also analyze the scheduling, routing and healing aspects of the resulting sensor-net topology. 相似文献
48.
49.
介绍了堆石料与基岩面的现场直剪试验方法,6个组次的直剪试验结果表明,堆石料与基岩面的抗剪强度指标随基岩面坚硬度的增大而增加,并随基岩面粗糙度的加大而加大。 相似文献
50.
Micro assembly injection moulding 总被引:1,自引:0,他引:1
Injection moulding is established as one of the most common manufacturing processes of thermoplastics due to its high degree of automation and the short cycle times. Micro injection moulding is a rapidly growing technology that allows for the efficient production of very complex micro parts in high series. The “Market Analysis for Microsystems II 2002–2005” of the Nexus Task Force anticipates a yearly growth in the field of micro system technology of about 20% (Wechsung et al. 2002). This study identifies in addition to the continuous miniaturization the growing use of polymers in micro systems (Schneider et al. 2001). No other material group offers this wide range of material properties and permits to choose processing parameters and application properties according to necessities (Gächter 2000). While the production processes of micro technical components are mainly controllable, the assembly of these components to hybrid micro systems is a bottleneck to the industrial large scale production. The assembly itself represents a large fraction of the added product value and gains in importance with growing complexity and miniaturization of the systems. 相似文献