锰铬不锈钢在化工应用中的风险及对策

对聚丙烯二装置丙烯球罐液位计不锈钢螺栓失效的原因进行了分析,结合锰铬不锈钢(200系列)的性能和国内市场上的现状,分析了锰铬不锈钢在化工生产中应用的风险,提出了应对方法。     

Ennoblement of stainless steel in natural seawater – A new explanation

The ennoblement of corrosion potential (E_corr) of passive metal immersed in seawater was investigated with electrochemical technology and epifluorescence microscopy. The in situ observation showed that the bacteria number increased on the metal surface according to an exponential law which was in the same way with the ennoblement of E_corr. At the same time, the anodic polarization current of high‐Mo stainless steel decreased in the initial days. According to the mix‐potential theory and the characteristics of polarization curves of high‐Mo steel in natural seawater, the ennoblement of corrosion potential may be induced by the decrease of the passive current density.     

Cr对低碳Si-Mn系TRIP钢组织与力学性能的影响

主要研究了Cr对低碳Si-Mn系TRIP钢组织与力学性能的影响。首先利用Formastor-F型膨胀仪测定了含Cr和不含Cr两种低碳钢的连续冷却转变(CCT)曲线,分析指出了Cr对连续退火工艺的潜在影响;然后采用Gleeble-3800热/力模拟试验机对两种钢的薄板试样进行了连续退火模拟实验,并通过拉伸试验测定了力学性能;最后采用金相、扫描电镜、X-射线衍射分析等技术考察分析了两种钢的显微组织。结果表明:含Cr的TRIP钢的组织比较细小,铁素体晶粒近似等轴分布;两种TRIP钢的残余奥氏体含量相近,但含Cr钢的残余奥氏体中的含碳量较高。分析认为这是由于含Cr钢在热轧阶段较易生成细小的组织,而在热处理阶段则抑制贝氏体的生成,最终获得稳定的残余奥氏体。     

S135钻杆钢在钻井液中的氧腐蚀行为

基于系统的理论分析和现场腐蚀产物的XRD分析,揭示了S135钻杆钢在3%NaCl溶液中的氧腐蚀机理。为研究腐蚀因素与腐蚀速率的关系,通过室内高压釜动态模拟实验,分别研究了钻井液中含氧量、钻井液温度、钻井液流速和钻井液盐浓度对S135钻杆钢的氧腐蚀速率影响规律。实验研究结果表明(1)3%NaCl盐水钻井液对S135钻杆钢的腐蚀主要是氧去极化作用所致;(2)钻井液含氧量和钻井液流速的增加会加快钻杆钢的氧腐蚀速率,而钻井液温度和含盐量对钻杆钢的氧腐蚀速率具有双重作用。     

解决废钢短缺是特钢业发展的关键

随着短流程炼钢的迅速兴起，废钢消耗量急剧增加，世界范围内废钢供应已经出现了严重缺口，我国每年须从国际市场进口大量废钢才能满足钢铁生产的供需平衡，在我国废钢已成为紧缺资源，影响着我国特钢业的发展。分析了这一形势，并初步探讨了解决这一问题的方法，建立合理的废钢储备及使用体系，使废钢资源合理化流动，同时积极探寻优质的废钢代用品，以便从根本上解决我国废钢短缺问题。     

便携式全站仪在钻采井架钢结构安装中的应用

文章介绍了一种由便携机和全站仪组成的便携式全站仪 ,阐述了该全站仪在钻采井架钢结构施工安装过程中的测量工作 ,对测点产生的误差采用伪逆自由网平差方法进行处理 ,控制点的精度可达到± 5mm ,该全站仪具有快速、灵活、准确的特点 ,不仅提高了生产效率 ,而且达到了对资料的计算机化管理。     

汽轮机叶片用X20Cr13钢的热处理工艺研究

采用正交试验对汽轮机叶片用X20Cr13钢进行了热处理工艺研究，以获得该钢的最佳热处理工艺，并在回火后以不同的速度冷却，以揭示冷却速度对钢的回火脆性的影响。结果，X20Cr13钢的最佳热处理工艺为900℃油淬或风冷，670℃回火，风冷。     

Use of recycled copper slag for blended cements

Copper slag is a by‐product generated during smelting to extract copper metal from the ore. The copper slag obtained may exhibit pozzolanic activity and may therefore be used in the manufacture of addition‐containing cements. In this paper the effect of the incorporation of the copper slag in cement is measured. Blends of copper slag with Portland cement generally possess properties equivalent to Portland cement containing fly ash, but very different to the silica fume incorporation. Copper slag and fly ash reduce the heat of hydration more effectively than silica fume in mortars. The replacement of 30% cement by copper slag reduces the flexural and compressive strength in a similar way to fly ash; however, after 28 days, the reduction is less than the percentage of substitution. Hydrated calcium aluminate phases were analysed using scanning electron microscopy (SEM) and X‐ray diffraction (XRD) techniques. The pozzolanic activity of copper slag is similar to that of fly ash and higher than silica fume. In the presence of low water/cement ratios, certain pozzolanic materials produce a very compact cement paste that limits the space available for hydration products, a determining factor in the formation of hydrated calcium aluminates. SEM was found to be a useful analytical technique when aluminates are formed and can be clearly detected by XRD. Copyright © 2008 Society of Chemical Industry     

反应器和钢烟囱整体吊装的难点和对策

介绍了在金陵石化炼油厂200万t/a柴油加氢装置建设中,将质量为237t的反应器和高60m的钢烟囱成功进行整体吊装过程中的关键技术.通过此项工程实践得出以下结论象钢烟囱这样细长重物的整体吊装,由两台吊车抬立起后,再由主吊车独立吊装就位的施工方法简单易行,安全可靠,应用范围广;结构复杂细长杆的吊装强度和挠度计算比较复杂,在计算过程中可以忽略部分次要件的质量,分别以两吊点为支点计算上下吊点所受的力,然后再按比例放余量,使两吊点受力之和等于细长杆的重力,计算挠度时,可以适当地把问题夸大化,从而建立近似的力学模型;高压厚壁重型容器的吊装,宜直接设置专门吊盖与大法兰用螺栓把紧起吊;施工现场地基坚实是保证吊车站位和吊装施工的前提条件.     

关于从旋涡炉渣回收铜的研究

介绍了用自然澄清法降低、回收旋涡炉渣中的铜的方法。该方法工艺简单。操作方便，不仅降低冶炼成本，同时提高了经济效益。