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31.
32.
Electro-organic synthesis without supporting electrolyte: Possibilities of solid polymer electrolyte technology 总被引:1,自引:0,他引:1
J. Jörissen 《Journal of Applied Electrochemistry》2003,33(10):969-977
The application of ion exchange membranes as solid polymer electrolytes (SPE) in fuel cells is state-of-the-art. This technology needs no supporting electrolyte; consequently it can be applied for electro-organic syntheses in order to save process steps. In this case the process is not predetermined to a maximized energy efficiency so that the selection of the cell design, of the electrode materials and of the operating conditions can be focused on a high selectivity of the electrode reactions. The electro-osmotic stream, which is caused by the solvation shells of the ions during their migration through the membrane, and hence is a typical property of SPE technology, has a significant effect on the electrode reactions. It generates enhanced mass transfer at the electrodes, which is beneficial for reaction selectivity. It can be influenced by the choice of, and possibly by the preparation of, the membrane. An additional remarkable advantage of SPE technology is the exceptional long durability of oxide coated electrodes. By combination of several process engineering methods stable operation of SPE cells has been realized, even for examples of non-aqueous reaction systems. Experiments up to 6000 h duration and in cells of up to 250 cm2 membrane area show the potential for industrial application. 相似文献
33.
Measurement Method of the Thickness Uniformity for Polymer Films 总被引:1,自引:0,他引:1
YANGHong-liang RENQuan FANYun-zheng 《半导体光子学与技术》2003,9(2):128-132
Several methods for investigating the thickness uniformity of polymer thin films are presented as well their measurement principles.A comparison of these experimental methods is given.The cylindrical lightwave feflection method is found to can obtain the thickness distribution along a certain direction.It is simple and suitable method to evaluate the film thickness uniformity. 相似文献
34.
微带型Wilkinson功分器设计与实现 总被引:2,自引:0,他引:2
小型低功耗器件是射频电路设计的研究热点,而微带技术具有小型化低功耗的优点,为此在介绍微带型Wilkin-son功分器工作原理的基础上,使用基于矩量法的ADS软件设计、仿真和优化计算相关数据参数,并制作了一个微带功分器实例,最后对加工的样品进行实测,获得与仿真值吻合较好的预期结果。 相似文献
35.
Finite element piezothermoelasticity analysis and the active control of FGM plates with integrated piezoelectric sensors and actuators 总被引:3,自引:0,他引:3
An efficient finite element model is presented for the static and dynamic piezothermoelastic analysis and control of FGM
plates under temperature gradient environments using integrated piezoelectric sensor/actuator layers. The properties of an FGM plate are functionally graded in the thickness
direction according to a volume fraction power law distribution. A constant displacement-cum-velocity feedback control algorithm that couples the direct and inverse piezoelectric effects is applied to provide active feedback
control of the integrated FGM plate in a closed loop system. Numerical results for the static and dynamic control are presented
for the FGM plate, which consists of zirconia and aluminum. The effects of the constituent volume fractions and the influence
of feedback control gain on the static and dynamic responses of the FGM plates are examined.
Received: 13 March 2002 / Accepted: 5 March 2003
The work described in this paper was supported by a grant awarded by the Research Grants Council of the Hong Kong Special
Administrative Region, China (Project No. CityU 1024/01E). 相似文献
36.
Maenghyo Cho Hee Yuel Roh 《International journal for numerical methods in engineering》2003,56(1):81-115
In the present study first‐order shear deformable shell finite elements based on general curvilinear co‐ordinates are proposed. For the development of the present shell elements, a partial mixed variational functional with independently assumed strains is provided in order to avoid the severe locking troubles known as transverse shear and membrane lockings. Bubble functions are included in the shape function of displacement to improve the performance of the developed element. The proposed assumed strain four‐ and nine‐node elements based on the general tensor shell theory provide an efficient linkage framework for shell surface modelling and finite element analysis. In the several benchmark problems, the present shell elements with exact geometric representations demonstrate their performance compared to previously reported results. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
37.
Lepikhin P. P. Romashchenko V. A. Tarasovskaya S. A. Korbach V. G. 《Strength of Materials》2003,35(1):52-59
The exactness and stability of the Wilkins method in the investigation of the stress-strain state of axisymmetric anisotropic elastic shells, including thick-walled ones, have been studied for different values of artificial viscosity, pulse load rise and fall time, and different deformation process durations. A comparison of numerical calculations, performed by means of an application software package developed by V. A. Romashchenko on the basis of the Wilkins method, with experimental results, known numerical data, and with calculations using the computation kernel LS-DYNA 3D has been carried out. 相似文献
38.
通过对百色等水文站泥沙资料分析 ,并结合广西河流及泥沙特性和社会对泥沙资料的精度要求 ,得出了在广西实行悬移质泥沙简测的可行性。为满足广西国民经济可持续发展需要 ,提出了在广西改革悬移质泥沙测验方式的必要性和紧迫性 相似文献
39.
Preparation and properties of nano-sized SnO2 powder 总被引:2,自引:0,他引:2
1 INTRODUCTIONSnO2isoneofthemainmaterialsusedingassensor.Becauseofthehumidityandgassensingfunction,itattractsmoreandmoreattentions.Butthepresentproblemishowtoimprovethestabilityandsensibilityofgassensor.Researchershavetakenmanymeasurestoresolvethisproble… 相似文献
40.